Ionic conductive separator plate, production method thereof, and electrodialysis reversal device
A technology of inverted electrodialysis and ion conduction, applied in the field of inverted electrodialysis devices
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specific Embodiment approach 1
[0054] In some embodiments, the polymeric coatings of the present invention can include sulfonated block copolymers. The sulfonated block copolymer includes sulfonic acid groups in one block in a sufficient amount to form a macroscopically continuous microphase.
[0055] Examples of such sulfonated block copolymers may include, for example, but are not limited to, sulfonated poly(styrene-b-ethylene-r-butylene-b-styrene) (sulfonated poly(styrene-b-ethylene- r-butylene-b-styrene), S-SEBS) triblock copolymer, polystyrene poly(styrene-b-isobutylene-b-styrene) (polystyrene poly(styrene-b-isobutylene-b-styrene) , S-SIBS), poly((dicyclopentadieneethylstyrene-s-styrene)-b-(n-propyl-p-styrenesulfonate)) (poly((norbornenyethylstyrene-s-styrene )-b-(n-propyl-p-styrenesulfonate)), PNS-PSSP), or poly(t-butylstyrene-b-hydrogenated isoprene-b-sulfonated styrene-b-hydrogenated isoprene Diene-b-t-butylstyrene) (poly(t-butylstyrene-b-hydrogenated disoprene-b-sulfonated styrene-b-hydrogenated ...
example 1
[0056] Example 1: Sulfonated Pentablock Copolymer Coating
[0057] A sulfonated pentablock copolymer supplied by Kraton Polymers LLC, poly(t-butylstyrene-b-hydrogenated isoprene-b-sulfonated styrene-b-hydrogenated isoprene Diene-b-t-butylstyrene) was dissolved in the solvent. The solvent used was a mixture of cyclohexane and heptane. Therefore, a sulfonated pentablock copolymer solution was prepared and then coated onto a PP web. The coated separator is called Kraton coated PP separator.
[0058] Please refer to Journal of Membrane Science (Journal of Membrane Science) 2012, 169-174, 394-395, J.H.Choi, C.L.Willis and K.I.Winey studied the self-assembled morphology of this pentablock copolymer thin film. When the IEC is 2.0meq / g polymer, the middle segment of sulfonated styrene forms a bicontinuous phase, but when the IEC decreases, the microphase structure of the sulfonated polymer becomes discontinuous. When this pentablock copolymer was coated onto PP mesh, it was obse...
specific Embodiment approach 2
[0064] In some embodiments, the polymeric coatings of the present invention may include fluorinated polymers having sulfonic acid groups in the side chains.
[0065]Fluorinated polymers can include, for example, but are not limited to, copolymers of tetrafluoroethylene and perfluoro(alkyl vinyl ether) with sulfonyl fluoride, or α,β,β-trifluoroethylene Sulfonated polymer of fluorostyrene.
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