Electrolyte for alkali aluminum air cell battery and matched electrolyte box thereof

An electrolyte tank and electrolyte technology, which is applied in the direction of fuel cell half-cells and primary battery half-cells, battery electrodes, circuits, etc., can solve the problem of accumulation of aluminum hydroxide particles, easy accumulation of aluminum hydroxide particles, accelerated and other problems, to achieve good fluidity, low cost, and increase the effect of settling velocity

Inactive Publication Date: 2018-09-07
HARBIN INST OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The purpose of the present invention is to solve the problem that the aluminum hydroxide particles in the inner cavity of the existing aluminum-air battery are easy to accumulate, and to provide an electrolyte for an alkaline aluminum-air battery pack and an electrolyte tank for supporting it. Effectively improve the accumulation of aluminum hydroxide particles in the inner cavity of the single cell when the aluminum-air battery pack is discharged at a high current, and accelerate the settlement of aluminum hydroxide particles generated during the reaction process of the aluminum-air battery pack

Method used

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  • Electrolyte for alkali aluminum air cell battery and matched electrolyte box thereof
  • Electrolyte for alkali aluminum air cell battery and matched electrolyte box thereof
  • Electrolyte for alkali aluminum air cell battery and matched electrolyte box thereof

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specific Embodiment approach 1

[0021] Specific embodiment 1: What this embodiment records is an electrolyte solution for an alkaline aluminum-air battery pack, the electrolyte solution is composed of potassium hydroxide or sodium hydroxide 2~8 mol / L, sodium stannate 0.01~0.15 mol / L, alkaline flocculant 0.5~10 g / L, and the balance is composed of water. The specific preparation method is as follows: adding potassium hydroxide or sodium hydroxide and sodium stannate into distilled water in sequence, stirring thoroughly, adding alkaline flocculant and stirring evenly again.

specific Embodiment approach 2

[0022] Specific embodiment two: a kind of electrolytic solution for alkaline aluminum-air batteries described in specific embodiment one, the described alkaline flocculant is one of anionic polyacrylamide, sodium polyacrylate or polyaluminum chloride or A mixture of several.

specific Embodiment approach 3

[0023] Specific embodiment three: a kind of electrolyte solution for alkaline aluminum-air batteries described in specific embodiment two, the molecular weight of the described anionic polyacrylamide is 200-20 million, and the molecular weight of the described sodium polyacrylate is 400-30 million .

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Abstract

The invention discloses an electrolyte for alkali aluminum air cell battery and a matched electrolyte box thereof, and belongs to the technical field of the aluminum air cell battery. The electrolyteis composed of 2-8mol / L of potassium hydroxide or sodium hydroxide; 0.01-0.15mol / L of sodium stannate, 0.5-10g / L of alkali flocculant, and the balance of water. The lower part in the electrolyte box is partitioned into multiple chambers (6), and the upper sides of the multiple chambers are communicated; an electrolyte inlet is arranged at the upper part of one sidewall of the electrolyte box, andan electrolyte outlet is arranged at the upper part of the other sidewall of the electrolyte box; and an electrolyte inlet and the hydrogen exhaust port are arranged at the upper part of the electrolyte box. The alkali flocculant added in the electrolyte has no influence on the conductivity of the electrolyte, the viscosity and the conductivity and like physical performances of the electrolyte areunchanged after the alkali flocculant is added into the electrolyte to store for a long time; and meanwhile, the alkali flocculant has flocculation effect on the Al(OH)3 particles generated in the discharging process of the aluminum air cell, and the sediment speed of the Al(OH3) particles in the electrolyte box can be greatly improved.

Description

technical field [0001] The invention belongs to the technical field of aluminum-air batteries, and in particular relates to an electrolyte solution for an alkaline aluminum-air battery pack and a supporting electrolyte tank. Background technique [0002] Aluminum-air battery is a new type of chemical power source that uses aluminum and air (oxygen) as electrode active materials. It is an efficient, stable and environmentally friendly energy conversion device. When the aluminum-air battery is working, the aluminum alloy anode is continuously consumed to generate Al(OH) 3 , electrons flow to the cathode through the external circuit, and oxygen captures electrons at the air electrode for a reduction reaction to generate OH - , thereby releasing electrical energy. According to different electrolyte systems, aluminum-air batteries are generally divided into two systems: alkaline and neutral. The electrolyte in the alkaline system is usually NaOH and KOH aqueous solutions, and t...

Claims

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Application Information

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IPC IPC(8): H01M4/485H01M4/62H01M12/06
CPCH01M4/485H01M4/62H01M12/06Y02E60/10
Inventor 程新群许超高云智左朋建杜春雨尹鸽平
Owner HARBIN INST OF TECH
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