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Graphene-based fireproof plastic plate and preparation method thereof

A graphene-based, fire-resistant plastic technology, applied in the direction of fire-resistant coatings, epoxy resin coatings, polyurea/polyurethane coatings, etc., can solve the problems of reducing the mechanical properties of plastics, plastics are flammable, and the flame-retardant effect is poor

Active Publication Date: 2018-09-14
东莞市海洲新材料科技有限公司 +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] PP, PE, ABS and other plastics have good mechanical properties and are widely used in daily life and construction projects. However, such high molecular organic polymers are easy to burn and produce a lot of toxic smoke after burning. Once a fire occurs, if the evacuation is not timely , can easily cause casualties
[0003] In order to solve the problem of flammability of plastics, most of the existing technologies carry out flame retardant modification on the plastic itself, such as adding flame retardants and glass fibers before plastic molding to improve the flame retardant performance of plastics, but flame retardant modification will reduce the plastic Mechanical properties, while the flame retardant effect is poor

Method used

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  • Graphene-based fireproof plastic plate and preparation method thereof
  • Graphene-based fireproof plastic plate and preparation method thereof
  • Graphene-based fireproof plastic plate and preparation method thereof

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preparation example Construction

[0041] The present invention also provides the preparation method of graphene-based fireproof plastic board described in above-mentioned technical scheme, comprises the following steps:

[0042] (1) carrying out surface treatment to plastic base material layer, obtains pretreatment plastic base material layer;

[0043] (2) coating graphene-based fireproof paint on the surface of the pretreated plastic substrate layer obtained in the step (1), forming a graphene-based fireproof layer, obtaining a graphene-based fireproof plastic plate, in the graphene-based fireproof layer Contains intrinsic graphene.

[0044] The invention carries out surface treatment on the plastic base material layer to obtain the pretreated plastic base material layer. In the present invention, the surface treatment is preferably plasma surface treatment or chemical surface treatment. In the present invention, the surface treatment can improve the coating adhesion of the graphene-based fireproof layer. ...

Embodiment 1

[0054] Weigh 30 parts of epoxy resin E51, 2 parts of intrinsic graphene powder, 0.1 part of defoamer BYK-052N, 0.25 parts of leveling agent BYK-3550, 15 parts of dibutyl phthalate and mix with a mechanical stirrer Evenly, the graphene is evenly dispersed; Weigh 20 parts of ammonium polyphosphate, 2 parts of chlorinated paraffin, 6 parts of dicyandiamide, 6 parts of dipentaerythritol, 5 parts of triphenyl phosphate, and 15 parts of barium sulfate, and add them to the obtained slurry in sequence , and stir while adding. After stirring evenly, transfer the slurry to a ball mill, disperse by ball milling, and stop until the slurry fineness is <90 μm, and take it out for later use.

[0055] Weigh 7 parts of T31 curing agent and 5 parts of acetone, and mix them uniformly to obtain component B.

[0056] Choose ABS plastic base material with a thickness of 2.5mm to remove dust and oil.

[0057] Mix A and B components evenly according to the mass ratio of A:B=100:12, and then coat on...

Embodiment 2

[0059] Weigh 30 parts of acrylic resin, 2 parts of intrinsic graphene powder, 0.1 part of defoamer BYK-066N, 0.25 parts of leveling agent BYK-32015 parts of ethyl acetate, and use a mechanical stirrer to mix evenly to disperse the graphene evenly Weigh 20 parts of melamine phosphate, 2 parts of chlorinated paraffin, 6 parts of dicyandiamide, 6 parts of dipentaerythritol, 5 parts of triphenyl phosphate, and 15 parts of talcum powder, and add them to the obtained slurry in turn, stirring while adding. After stirring evenly, transfer the slurry to a ball mill, disperse by ball milling, and stop until the slurry fineness is <90 μm, and take it out for later use.

[0060] Choose ABS plastic base material with a thickness of 2.5mm to remove dust and oil.

[0061] The graphene-based fireproof layer slurry is coated on ABS plastic, one-side coating, one coating 100-250 μm; multiple coatings until the thickness of the fireproof layer is 500 μm and then dried to obtain a graphene-based ...

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Abstract

The invention belongs to the field of fireproof materials and provides a graphene-based fireproof plastic plate. The graphene-based fireproof plastic plate comprises a graphene-based fireproof layer and a plastic base material layer, and the graphene-based fireproof layer comprises intrinsic graphene. Flame retardation and heat insulation effects of the fireproof layer can be improved by intrinsicgraphene, the plastic base material layer can be effectively protected in fire accidents, and burning and toxic gas releasing time of the plastic base material layer is delayed to buy time for evacuation and rescue. Further, stretch resistance and flexibility of the fireproof layer can be improved by intrinsic graphene, and the fireproof layer deforms correspondingly in deformation of the plasticbase material layer so as to keep high adhesion to the plastic base material layer; strength of an expansion carbon layer is improved, and less proneness to shedding after heat deformation of the plastic base material layer is realized. Owing to excellent insulation and hydrophobic performances of intrinsic graphene, water resistance of the fireproof layer can be remarkably improved, and the service life of the fireproof plastic plate is prolonged. In addition, the graphene-based fireproof plastic plate is low in density.

Description

technical field [0001] The invention relates to the technical field of fireproof materials, in particular to a graphene-based fireproof plastic board and a preparation method thereof. Background technique [0002] PP, PE, ABS and other plastics have good mechanical properties and are widely used in daily life and construction projects. However, such high molecular organic polymers are easy to burn and produce a lot of toxic smoke after burning. Once a fire occurs, if the evacuation is not timely , can easily cause casualties. [0003] In order to solve the problem of flammability of plastics, most of the existing technologies carry out flame retardant modification on the plastic itself, such as adding flame retardants and glass fibers before plastic molding to improve the flame retardant performance of plastics, but flame retardant modification will reduce the plastic Mechanical properties, while the flame retardant effect is poor. Contents of the invention [0004] In v...

Claims

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Application Information

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IPC IPC(8): C08J7/04C08L55/02C08L23/12C09D163/00C09D5/18C09D7/63C09D7/61C09D133/00C09D175/02
CPCC08J7/042C08J2323/12C08J2355/02C08J2433/00C08J2463/00C08J2475/02C08K2003/3045C08K2003/323C08L2201/02C09D5/18C09D133/00C09D163/00C09D175/02C09D7/61C09D7/63C08L91/06C08K13/02C08K3/042C08K5/12C08K3/32C08K5/053C08K5/523C08K3/30C08K3/34
Inventor 谭崇军李召平马强肖峰
Owner 东莞市海洲新材料科技有限公司
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