Metal water-based polishing oil and preparation method thereof
A water-based, varnish technology, applied in coatings, fire-resistant coatings, etc., can solve the problems of insufficient cooking resistance and wear resistance of varnish on the outside of cans, and achieve improved curing efficiency, good water resistance, and improved machining The effect of performance and wear resistance
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preparation example Construction
[0056] Another embodiment of the present invention provides a method for preparing a metal water-based varnish, comprising the following steps:
[0057] Feeding: In the stirring state, add polyester modified water-based acrylic resin, part of co-solvent, liquid petroleum resin, amino resin, blocked isocyanate and organic acid catalyst to part of the water in sequence, and stir evenly;
[0058] Viscosity adjustment: Take a sample to test the viscosity, add the remaining water and the remaining co-solvent, and adjust the viscosity to 90±10s (T-4# cup, 25°C);
[0059] Get a water-based varnish for metal.
[0060] In the above preparation method, the stirring speed is 600-800 r / min.
[0061] Specifically, in some embodiments, when feeding, under agitation, polyester modified water-based acrylic resin, part of co-solvent, liquid petroleum resin, amino resin, blocked isocyanate, organic acid catalyst, defoamer, fluid The leveling agent and polyfluorowax are added to part of the wa...
Embodiment 1
[0066] This example is used to illustrate the water-based varnish for metal disclosed in the present invention and its preparation method.
[0067] (1) Synthesis of polyester-modified water-based acrylic resin: unsaturated polyester (containing six-membered ring structure, solid content of 70%, glass transition temperature of -15°C, acid value of 15mg KOH / g, degree of unsaturation (expressed by iodine value, in non-volatile matter) is 12.7) 70g, 400g ethylene glycol monobutyl ether and 250g n-butanol are dropped in the reactor, and the control reaction temperature is at 120 ℃; 10g tert-butyl peroxybenzoate Ester (initiator), 100g methyl methacrylate, 80g styrene, 150g butyl acrylate, 300g hydroxyethyl acrylate, and 80g acrylic acid were mixed evenly, and then added dropwise to the reaction kettle, and the dropping time was controlled to be 5 hours. After the monomer and the initiator are dropped, the incubation time is 3 hours. Then cool down naturally, add 700g of deionized ...
Embodiment 2
[0080] Embodiment 2 and embodiment 3 are used to illustrate the water-based varnish for metal disclosed by the present invention and its preparation method, including most of the operation steps in embodiment 1, and its difference is:
[0081] The composition and dosage of the metal water-based varnish adopt the composition and dosage shown in Example 2 and Example 3 in Table 1.
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Abstract
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