Conducive polyacrylonitrile fiber and preparation method thereof

A technology of polyacrylonitrile fiber and acrylonitrile, applied in the fiber field, can solve problems such as high cost, bad hand feeling, and easy falling off of carbon black, and achieve the effect of improving surface activity and improving electrical conductivity

Inactive Publication Date: 2018-09-28
芜湖天科生物科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Based on ordinary fiber, the fiber surface is coated with carbon black by coating method, the carbon black is easy to fall off, the hand feel is not good, and the carbon black is not easy to distribute evenly on the fiber surface
Conductive metal compound fiber, with sulfide, iodide or oxide of copper, silver, nickel and cadmium as conductive material, made by mixed spinning method, adsorption method or chemical reaction method, with good fastness, among which copper, silver The compound also has certain additional functions, such as antibacterial and deodorizing, but the cost of silver is high, while the conductive fibers of copper, nickel and cadmium sulfide and iodide are worse than carbon black fibers, and the electromagnetic shielding performance is average. antistatic

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] A kind of conductive polyacrylonitrile fiber, it is made up of the raw material of following weight part:

[0020] Acrylonitrile 110, dibenzoyl peroxide 4, acetylene carbon black 2, alkenyl succinic anhydride 17, polysorbate 0.1, calcium stearate 0.7, diphenylimidazoline 0.4, pentaerythritol 3, ammonium persulfate 0.5.

[0021] A preparation method for conductive polyacrylonitrile fibers, comprising the following steps:

[0022] (1) get dibenzoyl peroxide, join in the dehydrated alcohol of its weight 14 times, stir, obtain initiator solution;

[0023] (2) Get ammonium persulfate, join in the deionized water of 25 times of its weight, stir;

[0024] (3) Mix acetylene carbon black and calcium stearate, heat and stir at 55°C for 1 hour, mix with alkenyl succinic anhydride, add to deionized water 13 times the weight of the mixture, stir evenly, and send it to the reaction kettle In the process, nitrogen gas was introduced to adjust the temperature of the reaction kettle t...

Embodiment 2

[0030] A kind of conductive polyacrylonitrile fiber, it is made up of the raw material of following weight part:

[0031] Acrylonitrile 130, dibenzoyl peroxide 6, acetylene carbon black 3, alkenyl succinic anhydride 20, polysorbate 0.2, calcium stearate 1, diphenyl imidazoline 1, pentaerythritol 4, ammonium persulfate 0.6.

[0032] A preparation method for conductive polyacrylonitrile fibers, comprising the following steps:

[0033] (1) get dibenzoyl peroxide, join in the dehydrated alcohol of its weight 20 times, stir, obtain initiator solution;

[0034] (2) Get ammonium persulfate, join it in the deionized water of 30 times of its weight, stir;

[0035] (3) Mix acetylene carbon black and calcium stearate, heat and stir at 60°C for 2 hours, mix with alkenyl succinic anhydride, add to deionized water 20 times the weight of the mixture, stir evenly, and send it to the reaction kettle In the middle, feed nitrogen gas, adjust the temperature of the reaction kettle to 75°C, add ...

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PUM

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Abstract

The invention discloses conducive polyacrylonitrile fiber, which is prepared from the following raw materials in parts by weight: 110 to 130 parts of acrylonitrile, 4 to 6 parts of dibenzoyl peroxide,2 to 3 parts of acetylene black, 17 to 20 parts of alkenyl succinic anhydride, 0.1 to 0.2 part of polysorbate, 0.7 to 1 part of calcium stearate, 0.4 to 1 part of diphenyl imidazoline, 3 to 4 parts of pentaerythritol and 0.5 to 0.6 part of ammonium persulfate. The acrylonitrile is used as monomers to be polymerized under the effect of initiators, so that the carbon black doped polyacrylonitrile is obtained. The conduction performance of the finished product fiber can be effectively improved; the toughening effect is also achieved.

Description

technical field [0001] The invention belongs to the field of fibers, and in particular relates to a conductive polyacrylonitrile fiber and a preparation method thereof. Background technique [0002] According to the conductive components, there are four main types of conductive fibers: metal fibers, carbon black fibers, conductive metal compound fibers and conductive polymer fibers. Metal fibers have good electrical conductivity, heat resistance, and chemical corrosion resistance. However, for textiles, metal fibers have small cohesion, poor spinning performance, and limited finished color. They are mostly used in carpets and work clothes fabrics. expensive. Carbon black fiber is a conductive fiber made by mixing carbon black with fiber-forming substances and using sheath-core spinning method. In addition to maintaining the original mechanical properties of the fiber, it also obtains certain electrical conductivity, but the color is single, usually black. Or gray and black...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): D01F6/54D01F1/09D01F1/10C08F120/44C08F2/44
CPCC08F2/44C08F120/44D01F1/09D01F1/10D01F6/54
Inventor 段国凡
Owner 芜湖天科生物科技有限公司
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