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A kind of high temperature resistant carrier adhesive film and preparation method thereof

A high temperature resistant, carrier technology, applied in chemical instruments and methods, adhesives, synthetic resin layered products, etc., can solve the problems of performance degradation, insufficient temperature resistance, unable to form interface matching and good bonding, etc., to alleviate the relative Movement, the effect of increasing bond strength

Active Publication Date: 2019-11-22
AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Due to the insufficient temperature resistance level of the traditional epoxy adhesive film, the adhesive film has been carbonized and decomposed when the high temperature resistant composite material is cured or the performance has dropped sharply. At the same time, effective interface matching and good bonding cannot be formed during the curing and cooling process.
[0004] Therefore, there is an urgent need for a carrier adhesive film that can be applied to composite materials and metal structures to solve the problems of interface matching between high-temperature curing resin-based composite materials and metal structures, and bonding and laying process.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0036] Add 100 parts of YH-550 polyimide and 20 parts of Vespel thermoplastic polyimide to 250 parts of N,N-dimethylacetamide (DMAC) (boiling point 166°C), stir at 115°C for 3 hours, and wait to mix After uniform and complete dissolution, then add 1 part of polystyrene oligomer (thermal decomposition temperature 325°C) and ultrasonically mix evenly to prepare a surface density of 30g / m 2 Chopped carbon fiber mat, use the solution method to coat the prepared glue on the chopped carbon fiber mat according to the predetermined thickness on both sides, heat it at 60℃h for 0.5h, attach the isolation film, and make a film with a thickness of 0.1mm . Use this adhesive film to bond 45# steel sheet, press 240°C / 2h+370°C / 3h, hot press curing under 3MPa pressure conditions, according to GB / T 7122-1996 peel strength test method and GB / T 7124-1986 shear The strength test method is to test the peel strength and shear strength at room temperature and 400°C respectively. The shear strength a...

Embodiment 2

[0038] Add 100 parts of 5428 bismaleimide (BMI) and 20 parts of thermoplastic polyethersulfone to 250 parts of dioxane (boiling point 101.5°C), stir at 55°C for 3 hours, wait until the mixture is uniform and completely dissolved, then add 5 parts of polyethylene oligomer (thermal decomposition temperature 142°C) are ultrasonically mixed uniformly, and the prepared area density is 30g / m 2 For chopped carbon fiber felt, the prepared glue solution is coated on the fiber carrier according to the predetermined thickness by the solution method, baked at 60°C for 0.5h, and the isolation film is attached to make an interface layer with a thickness of 0.1mm. Use this adhesive film to bond 45# steel sheet, press 180°C / 2h+200°C / 3h, hot press curing under 3MPa pressure conditions, according to GB / T7122-1996 peel strength test method and GB / T 7124-1986 shear strength The test method is to test the peel strength and shear strength at room temperature and 250°C respectively. The shear streng...

Embodiment 3

[0040] Add 100 parts of Novolac type cyanate ester and 20 parts of thermoplastic polyether ether ketone into 250 parts of dimethylformamide (DMF) (boiling point 152°C), stir at 110°C for 3 hours, wait until the mixture is uniform and completely dissolved, then add 1 part of polypropylene oxide oligomer (thermal decomposition temperature 200°C) is ultrasonically mixed, and the prepared area density is 30g / m 2 Chopped carbon fiber felt, using the solution method to coat the prepared glue solution on the fiber carrier according to the predetermined thickness, heat it at 60°C for 0.5h, attach the isolation film, and make a glue film with a thickness of 0.1mm. Use this adhesive film to bond 45# steel sheet, press 240°C / 2h+300°C / 3h, hot press curing under 3MPa pressure conditions, according to GB / T 7122-1996 peel strength test method and GB / T 7124-1986 shear The strength test method is to test the peel strength and shear strength at room temperature and 300°C respectively. The shear...

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PUM

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Abstract

The invention provides a high-temperature resistant carrier adhesive film and a preparing method thereof. The adhesive film is prepared from a mixed adhesive solution by adopting a solution process ona fiber carrier. The adhesive film is characterized in that: the mixed adhesive solution includes high-temperature resistant thermosetting resin, a flexibilizer, thermally unstable oligomers and a solvent having a high boiling point, and the fiber carrier is short cut fibrofelt. The adhesive film is designed based on double functions of adhesive bonding and thermal stress buffer, in-situ foamingis realized under high solidification temperature by the adhesive film, the good adhesive bonding of a metal structure and a composite material can be realized by the high toughness of the adhesive film, the peeling strength is improved, and the potential corrosion can be avoided at the same time.

Description

technical field [0001] The invention relates to a high-temperature-resistant carrier adhesive film and a preparation method thereof, belonging to the technical field of composite materials. Background technique [0002] With the rapid development of aerospace technology, the flight speed of missiles and aircraft is getting faster and faster, and the requirements for the weight and temperature resistance of structural materials are also getting higher and higher. At present, resin-based composite materials have the characteristics of high specific modulus, high specific strength, strong designability, good fatigue resistance and corrosion resistance, and have been widely used in primary load-bearing and secondary load-bearing components. Due to the increasingly high service environment temperature of aircraft structures, high temperature resistant resin-based composite materials are widely used in aircraft wings, rudder surfaces, structural cabins, radomes and other structure...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B32B27/00
CPCC09J179/04C09J179/08C09J179/085C09J2461/00C09J2479/08C09J2481/00C08L79/08C08L25/06C08L81/06C08L23/06C08L61/16C08L71/02
Inventor 柯红军许亚洪王国勇
Owner AEROSPACE INST OF ADVANCED MATERIALS & PROCESSING TECH