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Corrugated SCR (Selective Catalytic Reduction) denitration catalyst for gas turbine set and preparation method of denitration catalyst

A denitration catalyst, corrugated technology, applied in catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc., can solve the problems of monopoly of sources and high prices, and achieve high porosity, large specific surface area, and denitration efficiency. high effect

Active Publication Date: 2018-10-09
QIYUAN XIAN DAE YOUNG ENVIRONMENTAL PROTECTION TECH CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The proportion of natural gas power generation in my country's power structure is less than 5%, which is far behind developed countries. With the completion of the "West-to-East Gas Transmission" project and the gradual maturity of the overall coal gasification technology, for a long time in the future, my country will A large number of gas-fired units are built in developed areas with conditions. It is expected that all gas-fired units will implement SCR denitrification devices simultaneously in the future. However, the current gas denitrification catalysts are mainly imported, with high prices and monopolized sources.
[0005] The corrugated denitrification catalyst uses glass fiber felt as the skeleton material, and the corrugated plate with a certain size and multiple diameters is manufactured through a unique molding process, assembled into a unit, and intensively impregnated, and then soaked in the active powder solution. The active ingredients can be evenly adsorbed on the substrate. At present, there is no precedent for the application of this type of catalyst in China.

Method used

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  • Corrugated SCR (Selective Catalytic Reduction) denitration catalyst for gas turbine set and preparation method of denitration catalyst
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preparation example Construction

[0030] The preparation method of corrugated SCR denitrification catalyst for gas-fired unit of the present invention comprises the following steps:

[0031] Step 1: Select a certain specification of glass fiber felt as the skeleton material, manufacture it into a corrugated plate through a molding process, and then stack it with a flat plate of a certain size to form a unit. %~80% methanol, 2%~20% silica sol, 4%~25% water.

[0032] The forming process includes: firstly, preparing a certain proportion of forming liquid for use; secondly, setting the temperature of the drying furnace and forming roller of the forming machine, and feeding the material when the temperature reaches the set value. The second stage is 200°C, the upper forming roll is 300°C, and the lower forming roll is 180°C; again, the glass fiber mat sample is first immersed in the forming liquid, and then fed to the forming counter-pressing roll after drying at a high temperature of 300°C. Corrugated; finally, t...

Embodiment 1

[0038] The preparation method of the corrugated SCR denitration catalyst for the gas unit of the present embodiment comprises the following steps:

[0039] Step 1: Select a certain specification of glass fiber felt as the skeleton material, manufacture it into a corrugated plate through a molding process, and then stack it with a flat plate of a certain size to form a unit. % methanol, 20% silica sol, and 20% water.

[0040]The forming process includes: firstly, preparing a certain proportion of forming liquid for use; secondly, setting the temperature of the drying furnace and forming roller of the forming machine, and feeding the material when the temperature reaches the set value. The second stage is 200°C, the upper forming roll is 300°C, and the lower forming roll is 180°C; again, the glass fiber mat sample is first immersed in the forming liquid, and then fed to the forming counter-pressing roll after drying at a high temperature of 300°C. Corrugated; finally, the corru...

Embodiment 2

[0045] The preparation method of the corrugated SCR denitration catalyst for the gas unit of the present embodiment comprises the following steps:

[0046] Step 1: Select a certain specification of glass fiber felt as the skeleton material, manufacture it into a corrugated plate through a molding process, and then stack it with a flat plate of a certain size to form a unit. % methanol, 16% silica sol, and 4% water.

[0047] The forming process includes: firstly, preparing a certain proportion of forming liquid for use; secondly, setting the temperature of the drying furnace and forming roller of the forming machine, and feeding the material when the temperature reaches the set value. The second stage is 200°C, the upper forming roll is 300°C, and the lower forming roll is 180°C; again, the glass fiber mat sample is first immersed in the forming liquid, and then fed to the forming counter-pressing roll after drying at a high temperature of 300°C. Corrugated; finally, the corru...

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Abstract

The invention discloses a corrugated SCR (Selective Catalytic Reduction) denitration catalyst for a gas turbine set and a preparation method of the denitration catalyst. The catalyst is prepared by the steps: taking a glass fiber mat as a corrugated skeleton, stacking the corrugated skeleton and a flat plate into a denitration catalyst unit, and sequentially performing impregnation liquid enhancedimpregnation, catalyst activity powder solution impregnation and sinter hardening treatment, thereby obtaining the corrugated SCR denitration catalyst. The corrugated SCR denitration catalyst has geometric specific surface area of 771-1034 m<2> / m<3> and the porosity of 72.0-80.8%. The specific surface area of the corrugated catalyst SCR denitration catalyst can be increased by 69.45-94.66% compared with that of a coal fired corrugated catalyst, the geometric specific surface area is increased by 14.2-17.98% compared with that of the traditional honeycomb denitration catalyst, the porosity isincreased by 17.95-21.58%, and the flue gas denitration service requirement of a gas fired boiler is met.

Description

technical field [0001] The invention belongs to the technical field of flue gas denitration catalysts, and relates to a denitration catalyst, in particular to a corrugated SCR denitration catalyst for a gas unit and a preparation method thereof. Background technique [0002] With the rapid development of the economy, the emission of nitrogen oxides (NOx) has increased rapidly. Studies have shown that NOx is an important reason for the formation of haze weather and has become one of the factors restricting social and economic development. At present, SCR denitrification has been widely used in coal-fired units due to mature technology at home and abroad, but it is not widely used in gas-fired units. [0003] Compared with coal-fired boilers, gas-fired boilers have the advantages of high combustion efficiency and low pollutant emission concentrations, which are of great significance for CO2 and TSP emission reduction. However, gas boilers also produce a small amount of nitrog...

Claims

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Application Information

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IPC IPC(8): B01D53/86B01D53/56B01J35/10B01J37/08B01J37/02
CPCB01D53/8628B01J37/0205B01J37/08B01D2258/0283B01J35/60B01J35/618B01J35/617
Inventor 刘炜肖雷薛璐李韦权文亮张蓓张磊杨莎莎冯艳婷赵刚蒋宗安姜群
Owner QIYUAN XIAN DAE YOUNG ENVIRONMENTAL PROTECTION TECH CO LTD