A kind of purification method of lactoperoxidase in milk
A technology of lactoperoxidase and purification method, applied in the directions of oxidoreductase, biochemical equipment and methods, enzymes, etc., can solve the problems of cumbersome operation method, complicated operation and high cost
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[0057] The preparation method of the present invention will be further described in detail in conjunction with specific examples below. It should be understood that the following examples are only for illustrating and explaining the present invention, and should not be construed as limiting the protection scope of the present invention. All technologies realized based on the above contents of the present invention are covered within the scope of protection intended by the present invention.
[0058] The experimental methods used in the following examples are conventional methods unless otherwise specified; the reagents and materials used in the following examples can be obtained from commercial sources unless otherwise specified.
[0059] Instrument and reagent used in the embodiment:
[0060] Instruments: AKTA Pure Protein Purifier (GE Healthcare), Magnetic Stirrer (SCILOGEX), Peristaltic Pump (Langer), Discover12m-PES 0.2μm Hollow Fiber Column (WaterSep), Discover12m-PES 30...
Embodiment 1
[0065] Example 1: Selection of hydrophobic chromatography prepacked column conditions
[0066] (1) Sample pretreatment
[0067] Prepare skim milk: centrifuge 1 L of whole fresh milk at 2500 rpm and 25° C. for 15 min in a 500 mL centrifuge bottle. The upper separation layer containing the cream was discarded, and the skim milk was poured into a 1 L beaker.
[0068] Preparation of whey: Dissolve 1 g of rennet in 5 mL of ultrapure water to prepare a rennet solution with a concentration of 0.2 g / mL. Add 400 μL of rennet solution to 1 L of skim milk and mix well. Heat at 30°C for 60min to coagulate and precipitate the casein, and centrifuge at 4000rpm and 25°C for 15min in a 500mL centrifuge bottle. Finally, pour the whey into a clean 2L beaker for later use, and discard the precipitated coagulated casein.
[0069] (2) Ammonium sulfate precipitates miscellaneous proteins
[0070] Take 1L of deionized water and dissolve 750g of ammonium sulfate to prepare a saturated ammonium s...
Embodiment 2
[0086] Embodiment 2: the purification method of lactoperoxidase in cow's milk
[0087] According to the same conditions of (1) sample pretreatment and (2) ammonium sulfate precipitation of miscellaneous proteins in Example 1, sample pretreatment and ammonium sulfate precipitation of miscellaneous proteins were carried out.
[0088] (3) Preparation of starting buffer and elution buffer
[0089] Starting buffer: 50mM NaH 2 PO 4 ,50% (NH 4 ) 2 SO 4 ,2mM CaCl 2 ,pH 7.0;
[0090] Elution buffer: 50mM NaH 2 PO 4 ,2mM CaCl 2 ,pH 7.0;
[0091] (4) Purified lactoperoxidase
[0092] A hydrophobic chromatography prepacked column Octyl Sepharose 4FF (purchased from GE, codenamed GE HiTrapOctyl FF) was used as the purification filler, and the purification process was as follows:
[0093] A.5 column volume ultrapure water washes the chromatography column;
[0094] B. 5 column volumes of 100% starting buffer equilibrate the chromatographic column;
[0095] C. the clarified ammo...
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