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A kind of anti-yellowing weak solvent spray paint and preparation method thereof

A weak solvent, anti-yellowing technology, applied in the direction of coating, etc., can solve the problems of increasing lamination process and production cost, limited amount of anti-aging agent, thick and heavy materials, etc., to achieve vivid and vivid colors of inkjet printing, and prolong anti-aging The effect of uniform performance and whiteness

Active Publication Date: 2020-06-19
HUIZHOU YIDU IMAGE TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The middle of the PVC light box cloth is mesh cloth, and both sides are PVC. The material is thick and inconvenient to install. In order to meet the requirements of inkjet printing accuracy, the amount of anti-aging agent added to the material is limited. The PVC surface will crack, become brittle, and turn yellow when used outdoors for a long time
The PVC body can be pasted on the aging resistance by attaching a layer of cold lamination film on the surface. Although the weather resistance of the picture and materials is improved, the lamination process and production cost are increased.
Most of the existing weak solvent paint formulations add low-priced styrene-acrylic emulsions, which can reduce costs, but yellowing is prone to occur. In addition, whitening agents with sulfonated aromatic chromophores are added, which must be combined with hydroxyl-containing PVA Or the whitening effect can be stable and non-fading after CMC forms a complex, but the addition of PVA and CMC affects the water resistance and ink absorption of the coating, and outdoor use is limited. Usually, the proportion of PVA or CMC added is very small, resulting in the product only Adapt to the whiteness effect of short-term coatings, and the problem of fading and yellowing will appear after 3 days of outdoor use
There is also a combination of fluorescent whitening on the substrate and no whitening of the weak solvent coating on the market. The color of the coating does not change much without brightening, but the weak solvent coating does not have whitening, and the overall color of the product is yellowish. Yellowing will be slower

Method used

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  • A kind of anti-yellowing weak solvent spray paint and preparation method thereof
  • A kind of anti-yellowing weak solvent spray paint and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0029] Anti-yellowing weak solvent spray paint, its raw materials are: 33.4 parts of acrylic acid emulsion, 13.5 parts of polyvinyl alcohol solution (prepared from 11 parts of polyvinyl alcohol and 2.5 parts of deionized water), 9.4 parts of silicon dioxide, 0.5 parts of nano titanium dioxide Sol, 0.17 parts of whitening agent, 0.063 parts of dispersing agent, 0.0017 parts of phthalocyanine blue, 0.0023 parts of permanent violet, 43 parts of deionized water.

[0030] Prepare as follows:

[0031] 1. Prepare polyvinyl alcohol solution: weigh the polyvinyl alcohol granules, add deionized water to the reaction pot, start stirring at a speed of 400r / min, slowly add the polyvinyl alcohol granules, be careful not to form agglomerates, start to heat up after adding, After the temperature reaches 90°C, keep it warm for 1 hour, start cooling to 45°C, filter through a 200-mesh filter, and let it stand for 24 hours for defoaming before use.

[0032] 2. Prepare whitening solution: weigh p...

Embodiment 2

[0035] Anti-yellowing weak solvent spray paint, its raw materials are: 31 parts of acrylic acid emulsion, 15 parts of polyvinyl alcohol solution (prepared from 12 parts of polyvinyl alcohol and 3 parts of deionized water), 8 parts of silicon dioxide, 0.3 parts of nano-titanium dioxide Sol, 0.12 parts of whitening agent, 0.066 parts of dispersing agent, 0.0012 parts of phthalocyanine blue, 0.0033 parts of permanent violet, 40 parts of deionized water.

[0036] Prepare as follows:

[0037] 1. Prepare polyvinyl alcohol solution: weigh the polyvinyl alcohol granules, add deionized water to the reaction pot, start stirring at a speed of 400r / min, slowly add the polyvinyl alcohol granules, be careful not to form agglomerates, start to heat up after adding, After the temperature reaches 90°C, keep it warm for 1 hour, start cooling to 45°C, filter through a 200-mesh filter, and let it stand for 24 hours for defoaming before use.

[0038] 2. Prepare whitening solution: weigh polyvinyl...

Embodiment 3

[0041] Anti-yellowing weak solvent spray paint, its raw materials are: 38 parts of acrylic emulsion, 12 parts of polyvinyl alcohol solution (prepared from 9.5 parts of polyvinyl alcohol and 2.5 parts of deionized water), 12 parts of silicon dioxide, 1 part of nano-titanium dioxide Sol, 0.34 parts of whitening agent, 0.078 parts of dispersant, 0.003 parts of phthalocyanine blue, 0.0025 parts of permanent violet, 50 parts of deionized water.

[0042] Prepare as follows:

[0043] 1. Prepare polyvinyl alcohol solution: weigh the polyvinyl alcohol granules, add deionized water to the reaction pot, start stirring at a speed of 400r / min, slowly add the polyvinyl alcohol granules, be careful not to form agglomerates, start to heat up after adding, After the temperature reaches 90°C, keep it warm for 1 hour, start cooling to 45°C, filter through a 200-mesh filter, and let it stand for 24 hours for defoaming before use.

[0044] 2. Prepare whitening solution: weigh polyvinyl alcohol so...

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Abstract

The invention belongs to the field of coatings, and discloses a yellowing-resistant weak solvent inkjet coating which comprises the following raw materials in parts by weight: 30-40 parts of acrylic emulsion, 10-15 parts of a polyvinyl alcohol solution, 8-12 parts of silicon dioxide, 0.3-1 part of nano titanium dioxide sol, 0.1-0.4 part of a whitening agent, 0.05-0.08 part of a dispersing agent, 0.001-0.003 part of phthalo blue, 0.002-0.005 part of permanent violet and 40-50 parts of deionized water. The invention further discloses a preparation method of the inkjet coating. The preparation method comprises the steps of preparation of the polyvinyl alcohol solution, preparation of a whitening liquid, preparation of the inkjet coating and other steps. The inkjet coating provided by the invention is capable of adapting to different substrates, and has the advantages of high whiteness and yellowing resistance.

Description

technical field [0001] The invention belongs to the field of coatings, in particular to an anti-yellowing weak solvent inkjet coating and a preparation method thereof. Background technique [0002] Outdoor advertising has rich visual impact and a high rate of communication. It has developed rapidly in recent years. Inkjet outdoor photo has the characteristics of personalization, waterproof materials, high printing accuracy and wide application, and is more and more popular among people. However, when advertising materials are used outdoors, they are more affected by external unstable factors than indoor materials. The ultraviolet rays in the environment will cause the color of the spray painting to fade, the surface fluorescent whitening effect will decline, and the coating will turn yellow. The thermal oxygen aging effect of the coating exacerbates the yellowing problem of the coating, and directly appears the embarrassing phenomenon that the advertising paintings, especial...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09D133/04C09D129/04C09D7/61C09D7/65C09D7/63
CPCC08K2003/2241C08K2201/011C08L2201/08C08L2205/02C08L2205/03C09D7/61C09D7/63C09D7/65C09D133/04C08L29/04C08L33/02C08K13/02C08K3/36C08K3/22
Inventor 罗晓琪卢家荣
Owner HUIZHOU YIDU IMAGE TECH
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