A kind of treatment method of phosphorus-containing pesticide wastewater
A treatment method and phosphorus pesticide technology, applied in the field of water treatment, can solve the problems of unsatisfactory inorganic phosphorus removal effect, high treatment cost, complicated operation steps, etc., and achieve the effects of excellent micro-electrolysis efficiency and ideal pretreatment effect.
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Embodiment 1
[0016] After analysis of the phosphorus-containing pesticide wastewater to be treated, the COD in the raw water is 3250mg / L, and the total phosphorus is 620mg / L; micro-electrolysis treatment: adjust the pH value of the phosphorus-containing pesticide wastewater to 7.5, and perform micro-electrolysis treatment under alkaline conditions. Copper powder is loaded on carbon rods, titanium dioxide powder is loaded on diatomaceous earth as the cathode, and the waste water treated by micro-electrolysis is sent to the contact oxidation tank for treatment. Oxygen is 3mg / L; after contact oxidation treatment, the wastewater enters the UASB reactor from the bottom of the UASB reactor for anaerobic treatment, the water temperature is adjusted to 30°C, the pH value is 7.5, and the hydraulic retention time is 20 hours; The coagulation and sedimentation treatment is carried out in the coagulation sedimentation tank. The flocculants added are PAC and PAM, and the stirring and sedimentation is ca...
Embodiment 2
[0018] The same phosphorus-containing pesticide wastewater as in Example 1 was used to carry out the test.
[0019] Micro-electrolysis treatment: adjust the pH value of phosphorus-containing pesticide wastewater to 8, and carry out micro-electrolysis treatment under alkaline conditions. The anode uses carbon rods to load copper powder, and the cathode uses diatomaceous earth to load titanium dioxide powder. The wastewater treated by micro-electrolysis is sent to contact oxidation Treatment in the pool, during the reaction process, the pH is 8.0, the water temperature is adjusted to 25°C, the contact residence time is controlled at 4 hours, and the dissolved oxygen is 4mg / L; after contact oxidation treatment, the wastewater enters the UASB reactor from the bottom of the UASB reactor for anaerobic treatment. For treatment, the water temperature is adjusted to 30°C, the pH value is 7.5, and the hydraulic retention time is 20 hours; the effluent after UASB treatment enters the coag...
Embodiment 3
[0021] The phosphorus-containing pesticide wastewater to be treated is analyzed, and the COD in the raw water is 4045mg / L, and the total phosphorus is 735mg / L; micro-electrolysis treatment: adjust the pH value of the organic phosphorus pesticide wastewater to 7.5, and perform micro-electrolysis treatment under alkaline conditions. Copper powder is loaded on carbon rods, titanium dioxide powder is loaded on diatomaceous earth as the cathode, and the waste water treated by micro-electrolysis is sent to the contact oxidation tank for treatment. Oxygen is 3mg / L; after contact oxidation treatment, the wastewater enters the UASB reactor from the bottom of the UASB reactor for anaerobic treatment, the water temperature is adjusted to 30°C, the pH value is 7.5, and the hydraulic retention time is 20 hours; The coagulation and sedimentation treatment is carried out in the coagulation sedimentation tank. The flocculants added are PAC and PAM, and the stirring and sedimentation is carried...
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