Green leather preparation method without heavy metal pollution
A heavy metal and leather technology, applied in leather impregnation, leather surface treatment, chemical instruments and methods, etc., can solve the problems of non-elimination, high discharge of chromium-containing solid waste and wastewater in tanning, and low maturity of resource technology Advanced problems, to achieve the effect of reducing COD
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Embodiment 1
[0017] Get the leather and go through primer coating, rolling finish, middle coating, fixed coating and drum treatment in order to get the finished leather product. Add water-based emulsion and 25 parts of anionic polyurethane dispersion to 100 parts of deionized water in turn, raise the temperature to 30°C, stir evenly, roll coat the surface of the skin embryo with a roller coater, bake at 80°C for 20 minutes, and naturally cool down to room temperature. Add 5 parts of nano-photocatalyst and 50 parts of modified acrylic resin under light conditions, spray evenly on the leather surface, and bake at 70°C;
[0018] The modification method of the modified polysiloxane aqueous emulsion is as follows: in parts by weight, 50 parts of epoxy resin, 2 parts of silane coupling agent, 2 parts of auxiliary agent, put into 80 parts of organic solvent and stir at high speed for 0.5h, add 0.2 Part of defoamer, 0.2 part of leveling agent, mix evenly;
[0019] The modified acrylic resin is a ...
Embodiment 2
[0027] Take the leather and go through primer coating, rolling finish, intermediate coating, fixed coating and drum treatment in order to get the finished leather product. Add water-based emulsion and 27 parts of anionic polyurethane dispersion to 110 parts of deionized water in turn, raise the temperature to 35°C, stir evenly, roll coat on the surface of the leather embryo with a roller coater, bake at 85°C for 22min, and cool down to room temperature naturally. Add 13 parts of nano-photocatalyst and 60 parts of modified acrylic resin under light conditions, spray evenly on the leather surface, and bake at 75°C;
[0028] The modification method of the modified polysiloxane water-based emulsion is: in parts by weight, 75 parts of epoxy resin, 6 parts of silane coupling agent, 3 parts of auxiliary agent, put into 90 parts of organic solvent and stir at high speed for 0.5h, add 0.3 1 part defoamer, 0.3 part leveling agent, mix well;
[0029] The modified acrylic resin is a copo...
Embodiment 3
[0037] Get the leather and get the finished leather through primer, rolling, middle coat, fixed coating and drum treatment successively. 1) The primer described in 1) is: in terms of parts by mass, 15 parts of modified polysiloxane Add water-based emulsion and 30 parts of anionic polyurethane dispersion to 120 parts of deionized water in turn, raise the temperature to 40°C, stir evenly, roll coat on the surface of the leather embryo with a roller coater, bake at 90°C for 25 minutes, and cool down to room temperature naturally. Add 20 parts of nano-photocatalyst and 70 parts of modified acrylic resin under light conditions, spray evenly on the leather surface, and bake at 80°C;
[0038] The modification method of the modified polysiloxane water-based emulsion is: in parts by weight, 100 parts of epoxy resin, 10 parts of silane coupling agent, 4 parts of auxiliary agent, put into 100 parts of organic solvent and stir at high speed for 0.5h, add 0.4 Part of defoamer, 0.4 part of ...
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