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Green leather preparation method without heavy metal pollution

A heavy metal and leather technology, applied in leather impregnation, leather surface treatment, chemical instruments and methods, etc., can solve the problems of non-elimination, high discharge of chromium-containing solid waste and wastewater in tanning, and low maturity of resource technology Advanced problems, to achieve the effect of reducing COD

Active Publication Date: 2021-01-12
安徽银河皮革有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

In particular, although the environmental pollution of the tanning industry has been improved and reduced to a large extent, it has not been fundamentally resolved.
The outstanding problem is still that pollutants such as lime, sulfide, trivalent chromium, ammonia nitrogen, and chloride ions have not been eliminated, and the problem of high chromium-containing solid waste and wastewater discharge in tanning has not yet been resolved. Resource technology maturity is not high

Method used

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  • Green leather preparation method without heavy metal pollution

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0017] Get the leather and go through primer coating, rolling finish, middle coating, fixed coating and drum treatment in order to get the finished leather product. Add water-based emulsion and 25 parts of anionic polyurethane dispersion to 100 parts of deionized water in turn, raise the temperature to 30°C, stir evenly, roll coat the surface of the skin embryo with a roller coater, bake at 80°C for 20 minutes, and naturally cool down to room temperature. Add 5 parts of nano-photocatalyst and 50 parts of modified acrylic resin under light conditions, spray evenly on the leather surface, and bake at 70°C;

[0018] The modification method of the modified polysiloxane aqueous emulsion is as follows: in parts by weight, 50 parts of epoxy resin, 2 parts of silane coupling agent, 2 parts of auxiliary agent, put into 80 parts of organic solvent and stir at high speed for 0.5h, add 0.2 Part of defoamer, 0.2 part of leveling agent, mix evenly;

[0019] The modified acrylic resin is a ...

Embodiment 2

[0027] Take the leather and go through primer coating, rolling finish, intermediate coating, fixed coating and drum treatment in order to get the finished leather product. Add water-based emulsion and 27 parts of anionic polyurethane dispersion to 110 parts of deionized water in turn, raise the temperature to 35°C, stir evenly, roll coat on the surface of the leather embryo with a roller coater, bake at 85°C for 22min, and cool down to room temperature naturally. Add 13 parts of nano-photocatalyst and 60 parts of modified acrylic resin under light conditions, spray evenly on the leather surface, and bake at 75°C;

[0028] The modification method of the modified polysiloxane water-based emulsion is: in parts by weight, 75 parts of epoxy resin, 6 parts of silane coupling agent, 3 parts of auxiliary agent, put into 90 parts of organic solvent and stir at high speed for 0.5h, add 0.3 1 part defoamer, 0.3 part leveling agent, mix well;

[0029] The modified acrylic resin is a copo...

Embodiment 3

[0037] Get the leather and get the finished leather through primer, rolling, middle coat, fixed coating and drum treatment successively. 1) The primer described in 1) is: in terms of parts by mass, 15 parts of modified polysiloxane Add water-based emulsion and 30 parts of anionic polyurethane dispersion to 120 parts of deionized water in turn, raise the temperature to 40°C, stir evenly, roll coat on the surface of the leather embryo with a roller coater, bake at 90°C for 25 minutes, and cool down to room temperature naturally. Add 20 parts of nano-photocatalyst and 70 parts of modified acrylic resin under light conditions, spray evenly on the leather surface, and bake at 80°C;

[0038] The modification method of the modified polysiloxane water-based emulsion is: in parts by weight, 100 parts of epoxy resin, 10 parts of silane coupling agent, 4 parts of auxiliary agent, put into 100 parts of organic solvent and stir at high speed for 0.5h, add 0.4 Part of defoamer, 0.4 part of ...

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Abstract

The invention discloses a green leather preparation method without heavy metal pollution, which includes the following steps: taking the leather and subjecting it to primer, tumbling, intermediate coating, fixed coating and drum processing in sequence to obtain a finished leather product. 1) The primer is : In terms of parts by mass, add 10-15 parts of modified polysiloxane aqueous emulsion and 25-30 parts of anionic polyurethane dispersion to 100-120 parts of deionized water in sequence at room temperature, raise the temperature to 30-40°C, and stir evenly , use a roller coating machine to apply it on the surface of the leather base, bake it at 80-90°C for 20-25 minutes, let it naturally cool down to room temperature, add 5-20 parts of nano photocatalyst and 50-70 parts of modified acrylic resin under normal temperature light. , evenly sprayed on the leather surface, and baked at 70-80°C; the invention provides a green leather preparation method without heavy metal pollution, has less harmful substance emissions, and has better anti-fouling and waterproof properties.

Description

technical field [0001] The invention relates to the field of leather, in particular to a method for preparing green leather without heavy metal pollution. Background technique [0002] The leather industry is a traditional characteristic and advantageous industry in China, a pillar industry in my country's light industry, and an industry that benefits the people, occupying an indispensable position in the national economy. In particular, after more than 30 years of development since the reform and opening up, my country has become a world-recognized world leather production center, trade center and technology center, and has become a world leather power. [0003] Although our country is a big leather country, it is not yet a leather power. In particular, although the environmental pollution of the tanning industry has been improved and reduced to a greater extent, it has not been fundamentally resolved. The outstanding problem is still that pollutants such as lime, sulfide...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C14C9/00C14C11/00B01J27/24B01J35/00B01J35/02
CPCC14C9/00C14C11/00B01J27/24B01J35/39B01J35/40
Inventor 姜勤勤姜培育杨柳刘小省段云霄任润峰
Owner 安徽银河皮革有限公司
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