Wear-resisting and high-rigidity polycarbonate lens

Abstract

The invention discloses a wear-resisting and high-rigidity polycarbonate lens. The wear-resisting and high-rigidity polycarbonate lens comprises a polycarbonate substrate and a coating which covers the surface of the polycarbonate substrate, wherein the coating is prepared from the following raw materials: a silicon resin pre-polymer, polyurethane, epoxy resin, hydroxyethyl methylacrylate, polyester polyol, aluminum acetylacetonate, dibutyltin dilaurate, tetrabutylammonium hydroxide, methylhexahydrophthalic anhydride, 2-methylimidazole, bicyclic amidine, a solvent, a silane coupling agent andan auxiliary agent. The wear-resisting and high-rigidity polycarbonate lens provided by the invention has good wear resistance, high surface rigidity, excellent heat-resisting performance and long service life.

Description

technical field

[0001] The invention relates to the technical field of lenses, in particular to a wear-resistant high-hardness polycarbonate lens. Background technique

[0002] Polycarbonate is a thermoplastic resin with a carbonate bond structure in its main molecular chain. It has the advantages of light weight, high transparency, good impact resistance, heat resistance, cold resistance, stable size, high light transmittance, and easy processing and molding. It has been widely used as a material for optical lenses, lenses, etc., but compared with optical glass, polycarbonate has low surface hardness and poor wear resistance, and the lenses made of it are easily damaged during use, which seriously affects its use value. Contents of the invention

[0003] Based on the technical problems in the background technology, the present invention proposes a wear-resistant and high-hardness polycarbonate lens, which has good wear resistance, high surface hardness, excellent heat res...

Examples

Embodiment 1

[0016] A kind of abrasion-resistant high-hardness polycarbonate lens that the present invention proposes, comprises polycarbonate substrate and the coating that is coated on polycarbonate substrate surface; Its raw material of described coating comprises by weight: silicone resin prepolymerized 100 parts of polyester, 3 parts of polyurethane, 5 parts of epoxy resin, 0.12 parts of hydroxyethyl methacrylate, 1 part of polyester polyol, 0.1 part of aluminum acetylacetonate, 0.12 parts of dibutyltin dilaurate, 0.05 parts of tetrabutylammonium hydroxide , 0.85 parts of methylhexahydrophthalic anhydride, 0.01 parts of 2-methylimidazole, 0.5 parts of bicyclic amidine, 13 parts of solvent, 1.8 parts of silane coupling agent, and 0.1 part of auxiliary agent.

Embodiment 2

[0018] A kind of abrasion-resistant high-hardness polycarbonate lens that the present invention proposes, comprises polycarbonate substrate and the coating that is coated on polycarbonate substrate surface; Its raw material of described coating comprises by weight: silicone resin prepolymerized 80 parts, 11 parts of polyurethane, 1 part of epoxy resin, 0.25 parts of hydroxyethyl methacrylate, 0.2 parts of polyester polyol, 0.2 parts of aluminum acetylacetonate, 0.05 parts of dibutyltin dilaurate, 0.25 parts of tetrabutylammonium hydroxide , 0.2 part of methylhexahydrophthalic anhydride, 0.1 part of 2-methylimidazole, 0.1 part of bicyclic amidine, 30 parts of solvent, 0.5 part of silane coupling agent, and 0.3 part of auxiliary agent.

Embodiment 3

[0020] A kind of abrasion-resistant high-hardness polycarbonate lens that the present invention proposes, comprises polycarbonate substrate and the coating that is coated on polycarbonate substrate surface; Its raw material of described coating comprises by weight: silicone resin prepolymerized 95 parts, 6 parts of polyurethane, 4.3 parts of epoxy resin, 0.18 parts of hydroxyethyl methacrylate, 0.79 parts of polyester polyol, 0.12 parts of aluminum acetylacetonate, 0.1 parts of dibutyltin dilaurate, 0.09 parts of tetrabutylammonium hydroxide , 0.8 parts of methylhexahydrophthalic anhydride, 0.03 parts of 2-methylimidazole, 0.43 parts of bicyclic amidine, 18 parts of solvent, 1.6 parts of silane coupling agent, and 0.15 parts of auxiliary agent;

[0021] Wherein, the silicone resin prepolymer is based on tetraethyl orthosilicate, methyltrimethoxysilane, γ-(2,3-epoxypropoxy)propyltrimethoxysilane, γ-chloropropyltrimethyl Silicone resin prepolymer prepared from oxysiloxane monome...

technical field

[0001] The invention relates to the technical field of lenses, in particular to a wear-resistant high-hardness polycarbonate lens. Background technique

[0002] Polycarbonate is a thermoplastic resin with a carbonate bond structure in its main molecular chain. It has the advantages of light weight, high transparency, good impact resistance, heat resistance, cold resistance, stable size, high light transmittance, and easy processing and molding. It has been widely used as a material for optical lenses, lenses, etc., but compared with optical glass, polycarbonate has low surface hardness and poor wear resistance, and the lenses made of it are easily damaged during use, which seriously affects its use value. Contents of the invention

[0003] Based on the technical problems in the background technology, the present invention proposes a wear-resistant and high-hardness polycarbonate lens, which has good wear resistance, high surface hardness, excellent heat res...

Examples

Embodiment 1

[0016] A kind of abrasion-resistant high-hardness polycarbonate lens that the present invention proposes, comprises polycarbonate substrate and the coating that is coated on polycarbonate substrate surface; Its raw material of described coating comprises by weight: silicone resin prepolymerized 100 parts of polyester, 3 parts of polyurethane, 5 parts of epoxy resin, 0.12 parts of hydroxyethyl methacrylate, 1 part of polyester polyol, 0.1 part of aluminum acetylacetonate, 0.12 parts of dibutyltin dilaurate, 0.05 parts of tetrabutylammonium hydroxide , 0.85 parts of methylhexahydrophthalic anhydride, 0.01 parts of 2-methylimidazole, 0.5 parts of bicyclic amidine, 13 parts of solvent, 1.8 parts of silane coupling agent, and 0.1 part of auxiliary agent.

Embodiment 2

[0018] A kind of abrasion-resistant high-hardness polycarbonate lens that the present invention proposes, comprises polycarbonate substrate and the coating that is coated on polycarbonate substrate surface; Its raw material of described coating comprises by weight: silicone resin prepolymerized 80 parts, 11 parts of polyurethane, 1 part of epoxy resin, 0.25 parts of hydroxyethyl methacrylate, 0.2 parts of polyester polyol, 0.2 parts of aluminum acetylacetonate, 0.05 parts of dibutyltin dilaurate, 0.25 parts of tetrabutylammonium hydroxide , 0.2 part of methylhexahydrophthalic anhydride, 0.1 part of 2-methylimidazole, 0.1 part of bicyclic amidine, 30 parts of solvent, 0.5 part of silane coupling agent, and 0.3 part of auxiliary agent.

Embodiment 3

[0020] A kind of abrasion-resistant high-hardness polycarbonate lens that the present invention proposes, comprises polycarbonate substrate and the coating that is coated on polycarbonate substrate surface; Its raw material of described coating comprises by weight: silicone resin prepolymerized 95 parts, 6 parts of polyurethane, 4.3 parts of epoxy resin, 0.18 parts of hydroxyethyl methacrylate, 0.79 parts of polyester polyol, 0.12 parts of aluminum acetylacetonate, 0.1 parts of dibutyltin dilaurate, 0.09 parts of tetrabutylammonium hydroxide , 0.8 parts of methylhexahydrophthalic anhydride, 0.03 parts of 2-methylimidazole, 0.43 parts of bicyclic amidine, 18 parts of solvent, 1.6 parts of silane coupling agent, and 0.15 parts of auxiliary agent;

[0021] Wherein, the silicone resin prepolymer is based on tetraethyl orthosilicate, methyltrimethoxysilane, γ-(2,3-epoxypropoxy)propyltrimethoxysilane, γ-chloropropyltrimethyl Silicone resin prepolymer prepared from oxysiloxane monome...