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A glass-ceramic made from fly ash

A technology of glass-ceramics and fly ash, which is applied in the field of comprehensive utilization and resource utilization of fly ash, can solve the problems of high production energy consumption, low utilization rate of waste residue, long process flow, etc., and achieve excellent performance, high performance, The effect of efficient comprehensive utilization

Active Publication Date: 2022-03-01
SOUTHWEAT UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] However, the existing mainstream production process of using fly ash to prepare glass-ceramic--integral crystallization method and fusion sintering method has problems such as high production energy consumption, long process flow, and low utilization rate of waste slag. Crystal glass, the utilization rate of its fly ash is also low
[0006] At present, there is no glass-ceramic prepared by one-time high-temperature treatment and efficient utilization of fly ash.

Method used

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  • A glass-ceramic made from fly ash
  • A glass-ceramic made from fly ash
  • A glass-ceramic made from fly ash

Examples

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example 1

[0058] The specific preparation method is as follows:

[0059] 1) Take fly ash from a place in Xinjiang as all raw materials without adding auxiliary materials, dry it at 105°C for 2 hours, and then perform ball mill classification, take fly ash powder with a particle size of 48 μm and add polyvinyl alcohol with a mass percentage of fly ash of 5% After uniform mixing, the glass-ceramic green body powder is obtained;

[0060] 2) The green body powder is flatly spread in the forming abrasive tool, and the glass-ceramic green body is obtained after holding the pressure at 20 MPa for 30 seconds with a green body forming press.

[0061] 3) Put the glass-ceramic body into the tunnel kiln and raise the temperature directly from room temperature to 950°C at a heating rate of 10°C / min and keep it warm for 30 minutes, then raise the temperature to 1180°C at a heating rate of 5°C / min and keep it warm for 60 minutes. After the furnace cools down, the samples are taken out, polished and t...

example 2

[0064] The specific preparation method is as follows:

[0065]1) Take the fly ash in Example 1 as the main raw material, choose waste glass and perlite as the ingredients, dry the fly ash and the ingredients at 105°C for 2 hours, crush and classify by ball milling, and separate the components according to mass percentage 90% of fly ash, 5% of waste glass, and 5% of perlite are weighed and blended, and the powder with a particle size of 37 μm is added to 5% by mass of glycerin and mixed evenly to obtain a glass-ceramic green body powder;

[0066] 2) The green body powder is flatly spread in the forming abrasive tool, and the green body forming press is used to hold the pressure at 30 MPa for 30 seconds to obtain the glass-ceramic green body.

[0067] 3) Put the glass-ceramic body into the tunnel kiln and raise the temperature directly from room temperature to 1160°C for 60 minutes at a rate of 10°C / min. After cooling down with the furnace, take out the sample, polish it, and tr...

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Abstract

The invention provides a glass-ceramic with fly ash as raw material. The glass-ceramic is prepared from raw materials containing fly ash, the mass proportion of fly ash in the raw material is 90% to 100%, and the SiO 2 、Al 2 o 3 and Fe 2 o 3 The sum of the mass percentages is 50% to 70%. The glass-ceramic includes a glass phase and a microcrystalline phase, and the mass fraction of the glass phase is below 6%. The beneficial effects of the invention may include: the comprehensive utilization of fly ash can be realized, and the utilization rate of fly ash is 90-100%; the performance of the glass-ceramic is excellent, and the performance is higher than that of natural stone.

Description

technical field [0001] The invention relates to the field of comprehensive utilization and resource utilization of fly ash, in particular to a glass-ceramic with fly ash as raw material. Background technique [0002] Fly ash is an artificial volcanic mixed material emitted by coal combustion, and is a powdery substance collected by a dust collector after pulverized coal is burned at high temperature in a boiler. However, with the development of the times, more coal is used as power fuel, which will produce more fly ash, which is in urgent need of comprehensive utilization with high added value. [0003] Glass-ceramics is a type of polycrystalline material in which microcrystalline phases and glass phases coexist by controlling the heat treatment system based on glass and ceramic molding technology. Because of its mechanical properties, chemical resistance, thermal stability and insulation properties Good, adjustable coefficient of thermal expansion, etc. and widely used in ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C03C10/06
CPCC03C10/0036
Inventor 孙红娟曾丽彭同江丁文金
Owner SOUTHWEAT UNIV OF SCI & TECH