A kind of product prepared by photocuring rapid prototyping process and its preparation method
A molding process and light-curing technology, which is applied in the field of 3D printing materials, can solve the problems that the performance cannot meet the development and demand of the market, the types of photosensitive resins are few, and the reaction is complicated. The effect of high physical strength
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Embodiment 1
[0056] Preparation of vinyl-containing polycarbosilane: Add dropwise a mixed solution of 5.67 g of chloromethyltriethoxysilane and 8 mL of tetrahydrofuran to 8.0 g of magnesium chips and 20 mL of tetrahydrofuran, and continue to drop 80.28 g of methyl chloride after triggering the Grignard reaction A mixed solution of triethoxysilane and 450mL tetrahydrofuran was incubated at 30°C for 6h. Continue to drop 98.58g of vinylmagnesium bromide in methyl tetrahydrofuran solution, keep the reaction at 30°C for 2h, then add 10.8g of lithium aluminum hydride, and continue to react at 30°C for 10h. After the reaction, the reaction solution was gradually added to a 3.0mol / L hydrochloric acid solution, stirred for 0.5 to 2 hours, then extracted with 200mL of hexane, the organic phase was separated and dried by adding anhydrous magnesium sulfate, filtered and rotary evaporated to obtain polycarbosilane. The polycarbosilane has a number average molecular weight of 670 g / mol, a weight averag...
Embodiment 2
[0060] Preparation of allyl-containing polycarbosilane: Add dropwise a mixed solution of 7.35 g of chloromethyltrimethoxysilane and 11 mL of tetrahydrofuran to 10.2 g of magnesium chips and 24 mL of tetrahydrofuran, and continue to drop 97.0 g of methyl chloride after triggering the Grignard reaction A mixed solution of trimethoxysilane and 500mL tetrahydrofuran was incubated at 45°C for 8h. Continue to add 135.87g of allylmagnesium bromide in methyl tetrahydrofuran solution dropwise, keep the reaction at 45°C for 6h, then add 19.5g of lithium aluminum hydride, and continue to react at 45°C for 10h. After the reaction, the reaction solution was gradually added to a 3.0mol / L hydrochloric acid solution, stirred for 0.5 to 2 hours, then extracted with 240mL of hexane, the organic phase was separated and dried by adding anhydrous magnesium sulfate, filtered and rotary evaporated to obtain based polycarbosilane. The polycarbosilane has a number average molecular weight of 490 g / mo...
Embodiment 3
[0064] Preparation of isopropenyl-containing polycarbosilane: Add dropwise a mixed solution of 12.66 g of chloromethyltriethoxysilane and 20 mL of tetrahydrofuran to 17.5 g of magnesium chips and 42 mL of tetrahydrofuran, and continue to drop 186.0 g of chlorine after the Grignard reaction is initiated. A mixed solution of methyltriethoxysilane and 700mL tetrahydrofuran was incubated at 45°C for 9h. Continue to add 256.0g of isopropenylmagnesium bromide in methyl tetrahydrofuran solution dropwise, keep the reaction at 45°C for 6.5h, then add 35.8g of lithium aluminum hydride, and continue to react at 45°C for 13h. After the reaction, the reaction solution was gradually added to a 3.0mol / L hydrochloric acid solution, stirred for 0.5 to 2 hours, then extracted by adding 430mL of hexane, the organic phase was separated and dried by adding anhydrous magnesium sulfate, filtered and rotary evaporated to obtain based polycarbosilane. The polycarbosilane has a number average molecula...
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