A modified antibacterial functional fiber and its preparation method
A functional fiber and modification technology, applied in the field of polyester fiber production, can solve the problems of limited antibacterial time, unsustainable antibacterial effect, and inability to achieve lasting antibacterial, and achieve the effect of increasing surface roughness and not easy to fall off.
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[0027] Such as figure 1 Shown, the present invention proposes a kind of preparation method of modified antibacterial functional fiber, comprises the following steps:
[0028] S10, the PET polyester fiber oxidation treatment step, increases the roughness of the fiber surface, makes the fiber surface form dense pits, and provides space for anchoring hydroxyl groups in the next step. The specific method is as follows: mix the PET polyester fiber and the oxidizing agent in a mass ratio of 1:5, soak for 10-60 minutes at normal temperature, wash with distilled water for 3-5 times, and dry. Wherein, the oxidizing agent includes hydrogen peroxide with a mass fraction of 30%. Preferably, the oxidizing agent can also include FeCl 3 , its mass concentration in the oxidizing agent is 40%, which can achieve better results. More preferably, the oxidizing agent may also include sodium lauryl sulfate, and its mass concentration in the oxidizing agent is 0.5%. Sodium lauryl sulfate is an a...
Embodiment 1
[0041](1) Oxidation treatment of PET polyester fiber: mix PET polyester fiber with oxidant at a mass ratio of 1:5, soak for 10 minutes at room temperature, wash with distilled water for 3 to 5 times, and dry. The oxidizing agent comprises 30% hydrogen peroxide and 40% FeCl in mass fraction 3 And a mass fraction of 0.5% sodium lauryl sulfate.
[0042] (2) Alkali treatment: the oxidized PET polyester fiber is mixed with 5% NaOH solution in a mass ratio of 1:20, soaked at room temperature for 60 minutes, washed with distilled water until neutral, and dried to obtain modified permanent polyester fiber.
[0043] (3) Surface modification of nano-metal oxide antibacterial particles: Mix nano-copper oxide antibacterial particles, water, isopropanol and KH-550 in a mass ratio of 1:80:10:1.2, stir and react at room temperature for 2 to 6 hours, and react After the end, vacuum suction filtration, the filter cake is washed with ethanol for 3 to 5 times, and dried to obtain modified anti...
Embodiment 2
[0046] The difference between embodiment 2 and embodiment 1 lies in: pretreatment is carried out before the polyester fiber is oxidized. The pretreatment method is as follows: after the PET polyester fiber is dried, it is soaked in acetone at normal temperature for 12 hours, and then washed with distilled water for 3 to 5 times, washed with acetone, and dried.
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