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In-situ remediation method for soil contaminated by heavy metal chromium ions

A technology for in-situ remediation and polluted soil, applied in the field of soil remediation, can solve problems such as pollution, and achieve the effects of improving soil purification effect, improving use efficiency, and improving adsorption selectivity

Inactive Publication Date: 2020-07-17
NORTHEAST GASOLINEEUM UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0011] The purpose of the present invention is to solve the problem of in-situ remediation of soil heavy metal chromium ion pollution, synthesize a magnetic core adsorbent with selective adsorption of heavy metal chromium ions, and do not affect the content of other ions in the soil at the same time. In-situ remediation technology can improve the use efficiency of adsorbents, improve the effect of soil purification, and at the same time, use heavy metal ions as resources for waste utilization

Method used

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  • In-situ remediation method for soil contaminated by heavy metal chromium ions
  • In-situ remediation method for soil contaminated by heavy metal chromium ions
  • In-situ remediation method for soil contaminated by heavy metal chromium ions

Examples

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Effect test

Embodiment 1

[0034] Reference figure 1 with figure 2 , An in-situ remediation method for heavy metal chromium ion contaminated soil, the remediation method includes the following steps:

[0035] The first step is to prepare magnetic nuclear adsorbent, including the following steps:

[0036] (1), spherical γ-Al 2 O 3 Activation of

[0037] Weigh 200ml of deionized water in a beaker, mix with 2% ammonia water as the activator, and then weigh 3 grams of spherical γ-Al 2 O 3 Put it into ammonia water, place it in a 40℃ oven for surface activation for 12 hours, then pour off the ammonia water and remove the spherical γ-Al 2 O 3 Put it in an oven at 40℃ to dry for 4 hours;

[0038] (2) The introduction of ferric nitrate

[0039] Prepare 200ml of 5% ferric nitrate aqueous solution in a beaker, and then combine the spherical γ-Al obtained in step (1) 2 O 3 Put it in a beaker and immerse it at 40°C for 12 hours to obtain spherical γ-Al adsorbing 5% ferric nitrate aqueous solution 2 O 3 , Then put it in an o...

Embodiment 2

[0051] Reference figure 1 with figure 2 , An in-situ remediation method for heavy metal chromium ion contaminated soil, the remediation method includes the following steps:

[0052] The first step is to prepare magnetic nuclear adsorbent, including the following steps:

[0053] (1), spherical γ-Al 2 O 3 Activation of

[0054] Weigh 200ml of deionized water in a beaker, mix with 5% ammonia water as the activator, and then weigh 4.5g of spherical γ-Al 2 O 3 Put it into ammonia water, place it in a 60℃ oven for surface activation for 30 hours, then pour off the ammonia water, and remove the spherical γ-Al 2 O 3 Dry for 8 hours in an oven at 70℃;

[0055] (2) The introduction of ferric nitrate

[0056] Prepare 200ml of 15% ferric nitrate aqueous solution in a beaker, and then combine the spherical γ-Al obtained in step (1) 2 O 3 Put it in a beaker and immerse it at 60°C for 18 hours to obtain spherical γ-Al adsorbing 15% ferric nitrate aqueous solution 2 O 3 , And then place it in an oven ...

Embodiment 3

[0068] Reference figure 1 with figure 2 , An in-situ remediation method for heavy metal chromium ion contaminated soil, the remediation method includes the following steps:

[0069] The first step is to prepare magnetic nuclear adsorbent, including the following steps:

[0070] (1), spherical γ-Al 2 O 3 Activation of

[0071] Weigh 200ml of deionized water in a beaker, mix with 8% ammonia water as the activator, and then weigh 6 grams of spherical γ-Al 2 O 3 Put it in ammonia water, place it in a 80℃ oven for surface activation for 48 hours, then pour off the ammonia water, and remove the spherical γ-Al 2 O 3 Put it in an oven at 100℃ to dry for 12 hours;

[0072] (2) The introduction of ferric nitrate

[0073] Prepare 200ml of 25% ferric nitrate aqueous solution in a beaker, and then combine the spherical γ-Al obtained in step (1) 2 O 3 Put it in a beaker and immerse it at 80°C for 24 hours to obtain spherical γ-Al adsorbing 25% ferric nitrate aqueous solution 2 O 3 , And then dry it ...

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Abstract

The invention relates to a soil remediation technology, in particular to an in-situ remediation method for soil contaminated by heavy metal chromium ions, comprising the following steps: 1. preparing a magnetic core adsorbent, the steps are (1), spherical γ-Al 2 o 3 (2), introduction of ferric nitrate; (3), solution drive; (4), hydrogen reduction; (5), preparation of 3‑aminopropyltriethoxysilane (APTES) solution; step (6), Synthesis of magnetic nuclear adsorbent; the second step, the adsorption test of magnetic nuclear adsorbent to adsorb heavy metal chromium ions in soil. The remediation technology solves the problem of in-situ remediation of soil heavy metal chromium ion pollution, synthesizes a magnetic core adsorbent that selectively adsorbs heavy metal chromium ions, and does not affect the content of other ions in the soil, and proposes a magnetic core adsorbent for in-situ remediation of soil The technical process can improve the use efficiency of the adsorbent, improve the soil purification effect, and at the same time, use heavy metal ions as resources for waste utilization.

Description

Technical field [0001] The invention relates to a soil remediation technology, in particular to an in-situ remediation method for soil contaminated by heavy metal chromium ions. Background technique [0002] Soil heavy metal pollution is one of the main problems affecting human health and environmental quality. It not only affects crop production, but also affects the quality of the atmosphere and water environment, and even endangers human health through the food chain. Soil heavy metal pollution in my country is mainly caused by the "three wastes" produced by industries such as mining, smelting, electroplating, and chemical industries, as well as agricultural measures such as sewage irrigation and unreasonable application of pesticides and fertilizers [Pantsar-Kallio M, Reiniainen SP, Oksanen M. Interactions of soil components and their effects on speciation of chromium in soils[J].Analytica Chimica Acta. 2001, 439(1): 9-17.]. Heilongjiang Province is an important commercial gr...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B09C1/08
CPCB09C1/08
Inventor 张健王以臣施伟光陈彦广宋华胡云峰
Owner NORTHEAST GASOLINEEUM UNIV