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Processing method of high-stability nano superlattice electrothermal material

An electrothermal material and high-stability technology, applied in the field of material processing, can solve problems that affect stability and life, are not suitable for large-scale applications, and reduce market competitiveness, so as to improve bonding strength, enhance surface reactivity and ability, the effect of improving electrical performance

Inactive Publication Date: 2019-03-19
含山县领创新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] For a long time, alloy thermoelectric materials with high ZT value have been widely used, such as Bi 2 Ti 3 , PbTe, etc.; however, alloy materials have problems such as toxicity, lack of raw materials, and poor thermochemical stability, which are not suitable for large-scale applications; in view of this, in recent years, oxide materials have begun to attract the attention and attention of thermoelectric materials researchers.
[0004] At present, people have carried out a lot of experimental research on oxide thermoelectric materials. Although various types of materials have been made, when they are attached and formed into films, they often show poor bonding strength with the substrate, which will affect the use. Stability and longevity, which reduces the competitiveness of the market

Method used

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  • Processing method of high-stability nano superlattice electrothermal material

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Experimental program
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Effect test

Embodiment 1

[0029] A method for processing a high-stability nano-superlattice electrothermal material, comprising the steps of:

[0030] (1) Preparation of compound additives:

[0031] a. Mix potassium sodium niobate powder and hydrochloric acid solution into a three-necked flask, and keep stirring for 6 minutes to obtain mixed solution A for later use;

[0032] b. Mix pyrrole and hydrochloric acid solution together and put them into a three-necked flask, and keep stirring for 8 minutes to obtain the mixed solution B for later use;

[0033] c. Mix ammonium peroxodisulfate and hydrochloric acid solution and put them into a three-necked flask, and keep stirring for 10 minutes to obtain mixed solution C for later use;

[0034] d. Graphene, sodium pyrophosphate, dodecyltrimethylammonium bromide, disodium edetate, and deionized water are mixed and stirred according to the weight ratio of 14:4:2:0.5:75, constantly After stirring for 1 h, the mixed solution D was obtained for subsequent use; ...

Embodiment 2

[0048] A method for processing a high-stability nano-superlattice electrothermal material, comprising the steps of:

[0049] (1) Preparation of compound additives:

[0050] a. The potassium sodium niobate powder and the hydrochloric acid solution are mixed and put into a three-neck flask, and the mixed solution A is obtained after continuous stirring for 7 minutes;

[0051] b. Pyrrole and hydrochloric acid solution were mixed together and dropped into a three-necked flask, and the mixed solution B was obtained after continuous stirring for 9 minutes;

[0052] c. Mix ammonium peroxodisulfate and hydrochloric acid solution together and put them into a three-necked flask, and keep stirring for 11 minutes to obtain mixed solution C for later use;

[0053] d. Graphene, sodium pyrophosphate, dodecyltrimethylammonium bromide, disodium edetate, and deionized water are mixed and stirred according to the weight ratio of 16:6:4:0.8:77, constantly After stirring for 1.3 hours, the mixed s...

Embodiment 3

[0067] A method for processing a high-stability nano-superlattice electrothermal material, comprising the steps of:

[0068] (1) Preparation of compound additives:

[0069] a. Mix potassium sodium niobate powder and hydrochloric acid solution into a three-necked flask, and keep stirring for 8 minutes to obtain mixed solution A for later use;

[0070] b. Mix pyrrole and hydrochloric acid solution together and put them into a three-necked flask, and keep stirring for 10 minutes to obtain the mixed solution B for later use;

[0071] c. Mix ammonium peroxodisulfate and hydrochloric acid solution together and put them into a three-necked flask, and keep stirring for 12 minutes to obtain mixed solution C for subsequent use;

[0072] d. Graphene, sodium pyrophosphate, dodecyltrimethylammonium bromide, disodium edetate, and deionized water are mixed and stirred according to the weight ratio of 18:7:5:1:80, constantly After stirring for 1.5 hours, the mixed solution D was obtained fo...

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Abstract

The invention discloses a processing method of a high-stability nano superlattice electrothermal material. The processing method includes following steps: (1), preparing a composite adding material; (2), preparing a premixture; (3), preparing the electrothermal material. The processing method is simple in process, reasonable in step matching and convenient for popularization and application; the electrothermal material prepared by the method is good in thermoelectric performance, high in using stability, long in service life and extremely high in market competitiveness.

Description

technical field [0001] The invention belongs to the technical field of material processing, and in particular relates to a processing method of a high-stability nano superlattice electrothermal material. Background technique [0002] Fossil energy is currently the main source of energy, the energy crisis caused by its non-renewability and the greenhouse effect caused by the emission of carbon dioxide during use have attracted more and more attention. According to statistics, about two-thirds of the energy of fossil energy is wasted in the form of waste heat in use; if this part of waste heat can be recovered, it is obviously of great significance to alleviate the energy crisis and solve the greenhouse effect; in In this context, thermoelectric materials, as functional materials that can directly convert thermal energy and electrical energy, have received more and more attention in recent years. [0003] For a long time, alloy thermoelectric materials with high ZT value have...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C04B35/50C04B35/462C04B35/622C04B35/63C04B35/632C04B35/634
CPCC04B35/462C04B35/50C04B35/622C04B35/6303C04B35/632C04B35/63444C04B2235/3203C04B2235/3224C04B2235/3232
Inventor 郭平
Owner 含山县领创新材料科技有限公司
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