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A kind of non-magnetic hard alloy and its preparation method and application

A cemented carbide and hard phase technology, applied in the field of non-magnetic cemented carbide and its preparation, can solve the problems of poor toughness, low strength and hardness of non-magnetic cemented carbide, etc., to improve mechanical properties, increase hardness and Strength, the effect of improving toughness

Active Publication Date: 2021-07-20
ZHUZHOU HARD ALLOY GRP CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The technical problem to be solved by the present invention is to provide a kind of adding inhibitor (additive phase) and adopting Ni-Cu continuous solid solution as the shortcoming that the strength and hardness of the non-magnetic cemented carbide in the prior art are all on the low side and the toughness is not good. The non-magnetic hard alloy material of the binder phase, the non-magnetic hard alloy has high hardness and bending strength, and the binder phase uses Cu to replace part of Ni, which reduces the raw material cost of the non-magnetic hard alloy

Method used

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  • A kind of non-magnetic hard alloy and its preparation method and application
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  • A kind of non-magnetic hard alloy and its preparation method and application

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preparation example Construction

[0099] A second aspect of the present invention provides a method for preparing cemented carbide described in the first aspect of the present invention, comprising the following steps:

[0100] 1) WC powder, Ni powder, Cu powder and selected from Cr 3 C 2 powder, VC powder, Mo 2 One or more of the C powder and the TiC powder are mixed and wet-milled to obtain a wet-milled slurry;

[0101] 2) drying the wet-milled slurry to obtain an alloy powder mixture;

[0102] 3) Molding the alloy powder mixture into a compact, and then performing pressure sintering to obtain the hard alloy.

[0103] In some embodiments of the present invention, in step 1), a molding agent is also added during wet grinding, and the amount of the molding agent added is 1-3% of the material after mixing the components; and / or, the molding agent as paraffin and / or PEG.

[0104] In some preferred embodiments of the present invention, in step 1), a molding agent is also added during wet grinding, and the am...

Embodiment 1

[0114] By mass percentage: WC: 89.9%, Ni: 7.2%, Cu: 1.8%, Cr 3 C 2 : 0.6%, Mo 2 C: 0.5%, ingredients 1kg, ball milling medium is alcohol, the amount of alcohol added is 300ml, the weight ratio of ball to material is 3:1, molding agent PEG: 20g, wet mill in ball mill, filter after ball mill for 51h, and spray dry to get alloy powder mixture , and then press the alloy powder mixture, the molding pressure is 140MPa, and finally sintering, the sintering temperature: 1410°C, the sintering furnace pressure is 6MPa, the holding time is 2h, and its metallographic structure is as follows figure 1 and figure 2 As shown, the performance test results are shown in the table below, where K IC is the fracture toughness, which can be measured by the indentation method:

[0115]

[0116]

Embodiment 2

[0118] By mass percentage: WC: 90.4%, Ni: 7.2%, Cu: 1.8%, Cr 3 C 2 : 0.6%, ingredients 1kg, the ball milling medium is alcohol, the amount of alcohol added is 300ml, the weight ratio of the ball to material is 3:1, the molding agent PEG: 20g, wet mill in the ball mill, filter after ball milling for 45h, and spray dry to get the alloy powder mixture, Then the alloy powder mixture is pressed, the molding pressure is 140MPa, and finally sintered, the sintering temperature is 1410°C, the sintering furnace pressure is 6MPa, and the holding time is 2h. The performance test results are shown in the following table:

[0119]

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Abstract

The invention belongs to the technical field of hard alloy material preparation, and in particular relates to a non-magnetic hard alloy using Ni-Cu continuous solid solution as a binder phase, a preparation method and application thereof. The present invention provides a kind of non-magnetic cemented carbide material that adds inhibitor and adopts Ni-Cu continuous solid solution as bonding phase, reduces the magnetism of Ni-Cu bonding phase by adopting non-magnetic Cu on the one hand, on the other hand through Add additive Cr 3 C 2 , VC, Mo 2 One or more of C, TiC, etc., make it dissolve in the binder phase to further reduce the magnetic properties of the Ni-Cu binder phase. The present invention obtains a new type of non-magnetic hard alloy material with high hardness, high strength and high toughness through the joint action of additive phase and binder phase with specific composition and content.

Description

technical field [0001] The invention belongs to the technical field of hard alloy material preparation, and in particular relates to a non-magnetic hard alloy using Ni-Cu continuous solid solution as a binding phase, a preparation method and application thereof. Background technique [0002] Magnetic materials are widely used in many fields, such as permanent magnet materials used as motors, core materials used in transformers, magneto-optical disks used as memories, magnetic recording floppy disks for computers, etc. Magnetic materials are closely related to all aspects of informatization, automation, mechatronics, national defense, and national economy, and have become one of the important basic materials. The production of magnetic materials, especially permanent magnet materials, mainly adopts powder metallurgy technology. In order to make the magnetic moment distribute randomly or along the specified direction, the forming mold needs to be made of non-magnetic materials...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C29/08C22C1/05
CPCC22C1/051C22C29/067C22C29/08
Inventor 孔德方金鹏魏修宇管玉明谢浩
Owner ZHUZHOU HARD ALLOY GRP CO LTD