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Electrolyte-resistant solvent type acrylate pressure-sensitive adhesive and method for preparing same

A technology of acrylate and butyl acrylate, applied in the field of pressure-sensitive adhesives, can solve the problems of large difference in adhesion performance of adherends, poor temperature resistance, poor electrolyte resistance, etc., and achieves convenient operation and time-consuming. short, simple effects

Inactive Publication Date: 2019-04-05
广东安利华新材料科技有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0003] However, acrylate pressure-sensitive adhesives also have disadvantages, such as poor temperature resistance, poor electrolyte resistance, and large differences in bonding performance to different types of adherends. It is necessary to introduce other materials to modify pressure-sensitive adhesives. improve its performance
Aluminum shell and polypropylene film are two different types of materials. Acrylic pressure-sensitive adhesives currently on the market cannot achieve high adhesion to aluminum and polypropylene film at the same time, and have good electrolyte resistance

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0019] An electrolyte-resistant solvent-type acrylate pressure-sensitive adhesive, comprising the following raw materials in parts by weight: 15 parts of isooctyl acrylate, 5 parts of butyl acrylate, 2 parts of acrylic acid, 7 parts of methyl acrylate, 4 parts of natural rubber, C9 3 parts of tackifying resin, 50 parts of solvent, 0.3 parts of initiator, and 0.3 parts of crosslinking agent.

[0020] The solvent is a mixture of acetone, ethyl ester and xylene in a weight ratio of 10:25:15.

[0021] The initiator is benzoyl peroxide.

[0022] The crosslinking agent is an aziridine crosslinking agent.

[0023] A method for preparing an electrolyte-resistant solvent-type acrylate pressure-sensitive adhesive as described above, comprising the following steps: A, taking the raw materials in parts by weight of the formula for later use, B, mixing all isooctyl acrylate, butyl acrylate, acrylic acid , methyl acrylate, natural rubber, C9 tackifying resin, and 65% solvent are placed in...

Embodiment 2

[0026] An electrolyte-resistant solvent-type acrylate pressure-sensitive adhesive, comprising the following raw materials in parts by weight: 15.5 parts of isooctyl acrylate, 5.5 parts of butyl acrylate, 2.5 parts of acrylic acid, and 7.5 parts of methyl acrylate , 4.5 parts of natural rubber, 3.5 parts of C9 tackifying resin, 75 parts of solvent, 0.4 part of initiator, and 0.35 part of crosslinking agent.

[0027] The solvent is a mixture of acetone, ethyl ester and xylene in a weight ratio of 11:28:17.

[0028] The initiator is benzoyl peroxide.

[0029] The crosslinking agent is an aziridine crosslinking agent.

[0030] A method for preparing an electrolyte-resistant solvent-type acrylate pressure-sensitive adhesive as described above, comprising the following steps: A, taking the raw materials in parts by weight of the formula for later use, B, mixing all isooctyl acrylate, butyl acrylate, acrylic acid , methyl acrylate, natural rubber, C9 tackifying resin, and 65% solve...

Embodiment 3

[0033] An electrolyte-resistant solvent-type acrylate pressure-sensitive adhesive, comprising the following raw materials in parts by weight: 16 parts of isooctyl acrylate, 6 parts of butyl acrylate, 3 parts of acrylic acid, and 8 parts of methyl acrylate , 5 parts of natural rubber, 4 parts of C9 tackifying resin, 100 parts of solvent, 0.45 part of initiator, and 0.4 part of crosslinking agent.

[0034] The solvent is a mixture of acetone, ethyl ester and xylene in a weight ratio of 11:27:16.

[0035] The initiator is benzoyl peroxide.

[0036] The crosslinking agent is an aziridine crosslinking agent.

[0037] A method for preparing an electrolyte-resistant solvent-type acrylate pressure-sensitive adhesive as described above, comprising the following steps: A, taking the raw materials in parts by weight of the formula for later use, B, mixing all isooctyl acrylate, butyl acrylate, acrylic acid , methyl acrylate, natural rubber, C9 tackifying resin, and 65% solvent are plac...

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PUM

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Abstract

The invention relates to the technical field of pressure-sensitive adhesive, in particular to electrolyte-resistant solvent type acrylate pressure-sensitive adhesive and a method for preparing the same. The electrolyte-resistant solvent type acrylate pressure-sensitive adhesive comprises, by weight, 15-18 parts of iso-octyl acrylate, 5-7 parts of butyl acrylate, 2-4 parts of acrylic acid, 7-10 parts of methyl acrylate, 4-6 parts of natural rubber, 3-5 parts of C9 tackifying resin, 50-150 parts of solvents, 0.3-0.6 part of initiators and 0.3-0.5 part of cross-linking agents. The electrolyte-resistant solvent type acrylate pressure-sensitive adhesive and the method have the advantages that acrylate monomers, the natural rubber with double bonds and the tackifying resin with double bonds areused as main bodies of the electrolyte-resistant solvent type acrylate pressure-sensitive adhesive, the ester, ketone and aromatic solvents are used as dispersion of the electrolyte-resistant solventtype acrylate pressure-sensitive adhesive, appropriate quantities of initiators and cross-linking agents are added into the dispersion and the main bodies, and accordingly the electrolyte-resistant solvent type acrylate pressure-sensitive adhesive which is high in adhesion property for aluminum materials and polypropylene films and is excellent in electrolyte resistance can be prepared by the aidof the method.

Description

technical field [0001] The invention relates to the technical field of pressure-sensitive adhesives, in particular to an electrolyte-resistant solvent-type acrylate pressure-sensitive adhesive and a preparation method thereof. Background technique [0002] Acrylic pressure-sensitive adhesives are a type of adhesives that are widely used and are developing very rapidly. Solvent-type acrylate pressure-sensitive adhesive is an important branch of resin-type pressure-sensitive adhesives. Solvent-type acrylate pressure-sensitive adhesive has a low average relative molecular weight, and has excellent pressure sensitivity, adhesion, oxidation resistance, light resistance and Due to its aging resistance and other advantages, it has been widely used in the production of medical tapes, pressure-sensitive adhesive labels, BOPP packaging tapes, double-sided tapes, explosion-proof tapes, etc. [0003] However, acrylate pressure-sensitive adhesives also have disadvantages, such as poor t...

Claims

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Application Information

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IPC IPC(8): C09J133/08C09J107/00C09J157/02C09J11/06
CPCC08L2205/03C09J11/06C09J133/064C08L7/00C08L57/02C08K5/3412
Inventor 张涛辉徐智超叶启亮
Owner 广东安利华新材料科技有限公司
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