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Preparation of carbon fiber/graphene oxide/epoxy resin prepreg and carbon fiber composite material

A technology of epoxy resin and composite materials, which is applied in the field of preparation of composite materials, can solve the problems of high brittleness of materials, poor bonding between cured products and carbon fibers, and achieve the effect of simple methods

Inactive Publication Date: 2019-04-12
BEIJING UNIV OF CHEM TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Epoxy resin, as the most widely used matrix of carbon fiber composite materials, has excellent adhesion, corrosion resistance and chemical stability, but due to its own structure, when the epoxy resin is cured, the combination of its cured product and carbon fiber Poor, the material is more brittle

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0026] Weigh 1.5g of NaNO3 solid and dissolve it in 69ml of concentrated sulfuric acid with a concentration of 98%. Put the mixed solution in an ice-water bath and stir it magnetically to fully dissolve the NaNO3 solid; weigh 3g of natural graphite and add it to the mixed solution and stir for 15 minutes Weigh 9g of potassium permanganate, slowly add it to the mixed solution in 5 minutes, stir for 20 minutes, keep the temperature below 20°C in this process, and gradually increase the temperature in the last 10 minutes; raise the temperature to 35°C, add Plastic wrap, continue to stir for 1 hour; add 138ml of deionized water to raise the temperature to above 95°C, and continue to react for 15 minutes; continue to add 420ml of deionized water preheated to 50°C in advance, and then add 30ml of hydrogen peroxide to terminate the reaction, and the solution turns bright yellow Then the hot slurry is centrifuged and filtered, and washed with 5% dilute hydrochloric acid solution, and c...

Embodiment 2

[0032] Weigh 1.5g of NaNO3 solid and dissolve it in 69ml of concentrated sulfuric acid with a concentration of 98%. Put the mixed solution in an ice-water bath and stir it magnetically to fully dissolve the NaNO3 solid; weigh 3g of natural graphite and add it to the mixed solution and stir for 15 minutes ; Weigh potassium permanganate, slowly add it to the mixture for 5 minutes, stir for 20 minutes, keep the temperature below 20°C during this process, and gradually increase the temperature in the last 10 minutes; raise the temperature to 35°C, add fresh-keeping film, continue to stir and react for 1 hour; add deionized water to raise the temperature to above 95°C, and continue to react for 15 minutes; continue to add deionized water preheated to 50°C in advance, and then add hydrogen peroxide to terminate the reaction, and the solution turns bright yellow; then heat The slurry was centrifugally filtered, washed with 5% dilute hydrochloric acid solution, and centrifuged to obtai...

Embodiment 3

[0038] Weigh 1.5g of NaNO3 solid and dissolve it in 69ml of concentrated sulfuric acid with a concentration of 98%. Put the mixed solution in an ice-water bath and stir it magnetically to fully dissolve the NaNO3 solid; weigh 3g of natural graphite and add it to the mixed solution and stir for 15 minutes ; Weigh potassium permanganate, slowly add it to the mixture for 5 minutes, stir for 20 minutes, keep the temperature below 20°C during this process, and gradually increase the temperature in the last 10 minutes; raise the temperature to 35°C, add fresh-keeping film, continue to stir and react for 1 hour; add deionized water to raise the temperature to above 95°C, and continue to react for 15 minutes; continue to add deionized water preheated to 50°C in advance, and then add hydrogen peroxide to terminate the reaction, and the solution turns bright yellow; then heat The slurry was centrifugally filtered, washed with 5% dilute hydrochloric acid solution, and centrifuged to obtai...

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Abstract

The invention relates to preparation of a carbon fiber / graphene oxide / epoxy resin prepreg and a carbon fiber composite material, and relates to the technical field of composite materials. According tothe preparation provided by the invention, graphene oxide is prepared by an improved Hummers method, then the graphene oxide is transferred from an aqueous solution to epoxy resin, so that dispersibility of the graphene oxide in the epoxy resin is improved, the interfacial adhesion between the epoxy resin and carbon fibers is enhanced, and the mechanical properties of the epoxy resin-based carbonfiber composite material are improved; the carbon fiber / graphene oxide / epoxy resin composite material prepared by the preparation has bending strength of 1422.26 MPa when an addition amount is 0.5 wt%, and the bending strength is improved by 20.05% compared with that of a carbon fiber reinforced epoxy resin composite material; and when the addition amount is 0.3 wt%, the interlaminar shear strength reaches 84.67 MPa and is improved by 16.74% compared with that of the carbon fiber reinforced epoxy resin composite material.

Description

technical field [0001] The invention relates to the preparation of a composite material, in particular to the preparation of a unidirectional carbon fiber / graphene oxide / epoxy resin prepreg and a carbon fiber composite material. Background technique [0002] Due to their excellent physical and chemical properties, mechanical properties and thermal properties, carbon fiber composite materials have attracted more and more attention, and are widely used in communication vehicles, sports equipment, aerospace, national defense and military industries. Epoxy resin, as the most widely used matrix of carbon fiber composite materials, has excellent adhesion, corrosion resistance and chemical stability, but due to its own structure, when the epoxy resin is cured, the combination of its cured product and carbon fiber Poor, the material is more brittle. [0003] The combination of composite reinforcement and matrix interface and the dispersion of reinforcement in the matrix are importa...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08J5/04C08J5/10C08L63/00C08K3/04C08K7/06C08J3/215
CPCC08J3/215C08J5/042C08J5/10C08J2363/00C08K3/042C08K7/06
Inventor 赵东林蒲浩胡涛孟闻捷杨会先吴亚倩杨宇
Owner BEIJING UNIV OF CHEM TECH