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Outdoor silver powder coating and preparation method thereof

A powder coating and silver-colored technology, applied in powder coatings, polyester coatings, coatings, etc., can solve problems such as the influence of non-floating aluminum powder dispersion, blackening and darkening of the paint film, and loss of luster in the floating silver layer , to achieve good outdoor weather resistance, high gloss, good appearance effect

Active Publication Date: 2019-04-16
东莞市爱粤金属粉末有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, since aluminum is a metal with strong metallic properties, it is easy to oxidize. When it is corroded by water and oxygen, the formed silver floating layer is easily oxidized and loses its original luster.
Therefore, some researchers currently use non-leafing aluminum powder to replace floating silver. During the curing process of powder coatings, non-floating aluminum powder can be distributed in the paint film to form a flashing effect. However, the use of outdoor silver powder coatings needs to reach a certain level. High hardness and mechanical properties are usually added with high content of fillers and pigments. Regardless of the preparation process, if the fillers and pigments are not uniformly dispersed in the resin, the dispersibility of the non-floating aluminum powder will be greatly affected. This leads to poor mirror effect, which makes the cured paint film dark and glossy.

Method used

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  • Outdoor silver powder coating and preparation method thereof
  • Outdoor silver powder coating and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0043] A kind of outdoor silver powder paint, its preparation raw material is made up of following components:

[0044] Base powder:

[0045] Carboxylated polyester resin 60%, curing agent 5%, leveling agent 1.2%, wax powder 0.8%, high-gloss barium sulfate 13%, titanium white 19%, the glass transition temperature of carboxylated polyester resin is 55 ℃, and the acid value is 35mgKOH / g, the cone-plate viscosity at 200°C is 3000mPa.s, the curing agent is triglycidyl isocyanurate, and the leveling agent is ethylene bisstearamide;

[0046] Non-leafing aluminum powder:

[0047] 1%, flaky, and the particle size is 8um.

[0048] The preparation method of above-mentioned outdoor silver powder coating is:

[0049] (1) Preparation of base powder

[0050] Mix carboxyl polyester resin, curing agent, leveling agent, wax powder, high-gloss barium sulfate and white pigment in a high-speed mixer to obtain a mixture, and the rotation speed of the mixer is 1200r / min;

[0051] The mixture i...

Embodiment 2

[0056] A kind of outdoor silver powder paint, its preparation raw material is made up of following components:

[0057] Base powder:

[0058] Carboxyl polyester resin 65%, curing agent 4.5%, leveling agent 1.0%, wax powder 0.5%, high-gloss barium sulfate 10%, titanium dioxide 17.5%, carboxy polyester resin glass transition temperature is 57 ℃, acid value It is 37mgKOH / g, the cone-plate viscosity at 200°C is 3800mPa.s, the curing agent is triglycidyl isocyanurate, and the leveling agent is ethylene bisstearamide;

[0059] Non-leafing aluminum powder:

[0060] 1.5%, flaky, and the particle size is 8um.

[0061] The preparation method of the above-mentioned outdoor silver powder coating is the same as the preparation method of the outdoor silver powder coating in Example 1.

Embodiment 3

[0063] A kind of outdoor silver powder paint, its preparation raw material is made up of following components:

[0064] Base powder:

[0065] Carboxylated polyester resin 60%, curing agent 5%, leveling agent 1.2%, wax powder 0.8%, high-gloss barium sulfate 13%, lithopone 19%, glass transition temperature of carboxylated polyester resin is 55 ℃, acid value The viscosity is 35mgKOH / g, the cone-plate viscosity at 200°C is 3000mPa.s, the curing agent is triglycidyl isocyanurate, and the leveling agent is ethylene bisstearamide;

[0066] Non-leafing aluminum powder:

[0067] 1%, flaky, and the particle size is 8um.

[0068] The preparation method of the above-mentioned outdoor silver powder coating is the same as the preparation method of the outdoor silver powder coating in Example 1.

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Abstract

The invention provides an outdoor silver powder coating which is prepared by non-floating aluminum powder and bottom powder by a bonding process. The bottom powder in preparation raw materials contains, by weight, the following components: 55-65% of carboxyl polyester resin, 4.5-5.5% of a curing agent, 0.8-1.5% of a flatting agent, 0.5-1% of wax powder, 10-20% of high-gloss barium sulfate and 15-25% of a white pigment, wherein the glass transition temperature of the carboxyl polyester resin is 55 DEG C or above, an acid value is 32-37 mg of KOH per g, the viscosity of a conical plate is 2800-3800 mPa.s at 200 DEG C, the curing agent is triglycidyl isocyanurate, the flatting agent is NN'-ethylene bis-stearamide, and the non-floating aluminum powder accounts for 0.05-2% of the preparation raw materials. The adopted wax powder, high-gloss barium sulfate and the NN'-ethylene bis-stearamide can make the white pigment uniformly dispersed in the resin, so that it can be avoided that the whitepigment in the bottom powder is dispersed ununiformly to interfere the bonding of the non-floating aluminum powder, and the non-floating aluminum powder is uniformly adhered to the surface of the bottom powder particles in the bonding process. Therefore, the non-floating aluminum powder is uniformly dispersed in paint film, and a better appearance effect and high gloss are obtained.

Description

technical field [0001] The invention relates to the technical field of powder coatings, in particular to an outdoor silver powder coating and a preparation method thereof. Background technique [0002] Powder coating is a powdery solid coating that does not contain organic solvents or water. Its coating is also sprayed on the surface of the object to be coated in powder form, and is melted, leveled, and solidified to form a film. Compared with traditional solvent-based coatings, powder coatings can effectively reduce the pollution caused by solvent emissions, and their corrosion resistance, scratch resistance, and impact resistance can be further improved. With the improvement of people's living standards, the requirements for the quality of life are also increasing. People are more pursuing aesthetic effects on the objects to be painted, such as outdoor walls, billboards, etc., all hope to produce a certain degree of gloss and have a A certain color sensory effect, so ther...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D167/00C09D7/61C09D5/03C09D7/47
CPCC08K2003/0812C08K2003/2227C08K2003/2241C08K2003/3036C08K2003/3045C08K2201/011C09D5/033C09D167/00C08K3/36C08K3/08C08K3/22C08K5/20C08K3/30
Inventor 严耀耀周理银
Owner 东莞市爱粤金属粉末有限公司
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