High polymer-based cigarette filter material with excellent temperature control effect and preparation method thereof
A polymer material and polymer-based technology, which is applied in the field of polymer-based cigarette filter materials and its preparation, can solve the problems of poor filter interception effect, poor sensory quality of cigarettes, and poor biodegradability, etc., and achieve excellent biodegradation properties, high latent heat of phase change, and stable performance
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Embodiment 1
[0031] 1. Preparation of microcapsule phase change material: Take 50mL of toluene solution, add 14.3g of PEG-2000 and acrylonitrile monomer (mass ratio 1:1), heat and stir, the amount of additive Span-80 accounts for the amount of PEG 10%, the emulsification temperature is 50°C, under the assistance of ultrasound, fully stir and disperse into very fine particles. After that, 2 g of initiator azobisisobutyronitrile was added, the temperature was controlled at about 50° C., and the reaction was kept for 4 hours. After the reaction, wash the microcapsules with alcohol and distilled water for 2-3 times respectively, then filter with suction and dry in vacuum to obtain the microcapsules PEG-2000.
[0032] 2. Preparation of modified BN: Take 1.0g BN, disperse it in 500mL water, and ultrasonicate it for 8-10h. Then add 1.0gPEI-10000 and continue to sonicate for 4h. After the reaction, the unstripped BN was removed by centrifugation at 4000 rpm. The filtrate was suction filtered an...
Embodiment 2
[0038] 1. Preparation of microcapsule phase change material: Take 50mL of toluene solution, add 14.3g of PEG-6000 and acrylonitrile monomer (mass ratio: 1:1), heat and stir, the amount of additive Span-80 accounts for the amount of PEG 8%, the emulsification temperature is 50°C, under the assistance of ultrasound, fully stir and disperse into very fine particles. After that, 5 g of initiator azobisisobutyronitrile was added, the temperature was controlled at about 50° C., and the reaction was kept for 6 hours. After the reaction is finished, the microcapsules are washed with alcohol and distilled water for 2-3 times, then filtered with suction and vacuum-dried to obtain PEG-6000 microcapsules.
[0039] 2. Preparation of modified BN: Take 1.0g BN, disperse it in 500mL water, and ultrasonicate it for 8-10h. Then add 2.0gPEI-12000 and continue to sonicate for 4h. After the reaction, the unstripped BN was removed by centrifugation at 4000 rpm. The filtrate was suction filtered ...
Embodiment 3
[0045] 1. Preparation of microcapsule phase change materials: Take 50mL of toluene solution, add 14.3g of PEG-4000 and acrylonitrile monomer (mass ratio: 1:2), heat and stir, the amount of additive Span-80 accounts for the amount of PEG 10%, the emulsification temperature is 60°C, under the assistance of ultrasonic, fully stir and disperse into very fine particles. After that, 2 g of initiator azobisisobutyronitrile was added, the temperature was controlled at about 50° C., and the reaction was kept for 4 hours. After the reaction, wash the microcapsules with alcohol and distilled water for 2-3 times, then filter with suction and dry in vacuum to obtain the microcapsules PEG-4000.
[0046] 2. Preparation of modified AlN: Take 1.0g of AlN, disperse it in 500mL of ethanol, and treat it ultrasonically for 6-8h. After that, 1.0 g of vinyltriethoxysilane was added, and ultrasonication was continued for 4 h. After the reaction was finished, unstripped AlN was removed by centrifuga...
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