Viscoelastic surfactant composition for oil displacement and preparation method and application of viscoelastic surfactant composition
A technology of surfactant and composition, applied in the field of viscoelastic betaine surfactant composition and preparation field for oil displacement, can solve the problems of difficult injection, formation blockage, etc., and achieves reduced repulsion, high interfacial activity, excellent resistance The effect of temperature performance
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Embodiment 1
[0030] 1. Surfactant Preparation
[0031] (1) Erucamide sulfobetaine amphoteric surfactant (R 1 =C 21 , R 2 =C 2 , R 3 \R 4 =C 2 , R 5 =C 3 h 6 O) Preparation
[0032] a) Add methyl erucate and the required amount of amidation reagent N,N-bis(2-hydroxyethyl)ethylenediamine into the reaction kettle, react at 145°C for 7 hours, turn on the vacuum pump, and remove excess N , N-bis(2-hydroxyethyl)ethylenediamine to obtain the erucic acid acyl tertiary amide product, and then heat to 150°C while passing nitrogen into the reactor equipped with a condensation device and a stirring device, after heating for 40 minutes Ethylene oxide (2 moles) was added, and the temperature was maintained at 150° C. and the reaction was stirred for 1 hour. Cool down to 80°C, add barium hydroxide as a catalyst, heat to 140°C, turn on the vacuum system, dehydrate under high vacuum for 1 hour, and then use nitrogen to blow 4 times to remove the air in the system, and then adjust the reaction te...
Embodiment 2
[0042] 1. Surfactant Preparation
[0043] (1) octadecanoic acid amide sultaine surfactant (R 1 =C 17 , R 2 =C 2 , R 3 \R 4 =C 2 , R 5 =C 2 ) preparation
[0044] a) Add methyl octadecanoate and the required amount of amidating reagent N,N-bis(2-hydroxyethyl)ethylenediamine into the reaction kettle, react at 150°C for 8 hours, turn on the vacuum pump, and remove the excess N,N-bis(2-hydroxyethyl)ethylenediamine to obtain the nonanoic acid acyl tertiary amine product, and then heated to 150°C while passing nitrogen into a reactor equipped with a condensing device and a stirring device, and then heated for 40 After 1 minute, ethylene oxide (2 moles) was added, and the temperature was maintained at 150° C. and the reaction was stirred for 1 hour. Cool down to 80°C, add barium hydroxide as a catalyst, heat to 140°C, turn on the vacuum system, dehydrate under high vacuum for 1 hour, and then use nitrogen to blow 4 times to remove the air in the system, and then adjust the ...
Embodiment 3
[0049] 1. Surfactant Preparation
[0050] (1) nonanoic acid amide sultaine surfactant (R 1 =C 7 , R 2 =C 3 , R 3 \R 4 =C 2 , R 5 =C 2 ) preparation
[0051] a) Add methyl nonanoate and N,N-bis(2-hydroxyethyl)propylenediamine into the reactor, react at 150°C for 8 hours, turn on the vacuum pump, and remove the excess N,N-bis(2 -Hydroxyethyl) propylenediamine, obtain nonanoic acid acyl tertiary amine product, then in the reactor that condensing device and stirrer are housed, nitrogen gas limit limit is heated to 150 ℃, adds oxirane after heating 40 minutes ( 2 moles), the temperature was maintained at 150°C and the reaction was stirred for 1 hour. Cool down to 80°C, add barium hydroxide as a catalyst, heat to 140°C, turn on the vacuum system, dehydrate under high vacuum for 1 hour, and then use nitrogen to blow 4 times to remove the air in the system, and then adjust the reaction temperature of the system to Slowly feed ethylene oxide (4 moles) and propylene oxide (2 ...
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