a waterproof fabric
A waterproof fabric and fabric technology, applied in synthetic resin layered products, chemical instruments and methods, layered products, etc., can solve the problems that the water repellent effect cannot reach the protective clothing, increase the wet weight of the fabric, etc., and achieve excellent waterproof , Special flexibility, the effect of increasing the silicon content
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Embodiment 1
[0050] A kind of nano SiO 2 Modified polyurethane emulsion, in parts by mass, composed of 26 parts of nano SiO 2 Sol, 96 parts of waterborne polyurethane prepolymer emulsion, 18 parts of vinyl silicone oil, 15 parts of polymerizable silicone monomer (as shown in formula 1), 15 parts of emulsifier, 1 part of initiator, 370 parts of water are prepared by emulsion polymerization to make;
[0051] (H 3 C) 3 Si-O-CH 2 CH 2 NH-CH 2 CH=CH 2 Formula 1
[0052] The preparation method includes the following steps:
[0053] 1. Nano SiO 2 Preparation method of sol
[0054] Combine 25 parts of γ-methacryloxypropyltrimethoxysilane (silane coupling agent KH-570), 3 parts of sodium lauryl sulfate, 4 parts of alkylphenol polyoxyethylene ether (OP-10) Add to 300 parts of water, stir and disperse, then add 9 parts of ammonia under stirring, continue to stir and react for 4 hours to form nano SiO containing C=C bond 2 Sol
[0055] 2. Preparation of waterborne polyurethane prepolymer emulsion:
[0056] In ...
Embodiment 2
[0064] A kind of nano SiO 2 Modified polyurethane emulsion, in parts by mass, composed of 21 parts of nano SiO 2 Sol, 85 parts of waterborne polyurethane prepolymer emulsion, 15 parts of vinyl silicone oil, 12 parts of polymerizable silicone monomer (as shown in formula 1), 13 parts of emulsifier, 0.8 parts of initiator, 340 parts of water are prepared by emulsion polymerization to make;
[0065] (H 3 C) 3 Si-O-CH 2 CH 2 NH-CH 2 CH=CH 2 Formula 1
[0066] The preparation method includes the following steps:
[0067] 1. Nano SiO 2 Preparation method of sol
[0068] Combine 25 parts of γ-methacryloxypropyltrimethoxysilane (silane coupling agent KH-570), 3 parts of sodium lauryl sulfate, 4 parts of alkylphenol polyoxyethylene ether (OP-10) Add to 300 parts of water, stir and disperse, then add 9 parts of ammonia under stirring, continue to stir and react for 4 hours to form nano SiO containing C=C bond 2 Sol
[0069] 2. Preparation of waterborne polyurethane prepolymer emulsion:
[0070] ...
Embodiment 3
[0078] A kind of nano SiO 2 Modified polyurethane emulsion, in parts by mass, composed of 17 parts of nano SiO 2 Sol, 72 parts of waterborne polyurethane prepolymer emulsion, 12 parts of vinyl silicone oil, 9 parts of polymerizable silicone monomer (as shown in formula 1), 9 parts of emulsifier, 0.6 part of initiator, 290 parts of water are prepared by emulsion polymerization to make;
[0079] (H 3 C) 3 Si-O-CH 2 CH 2 NH-CH 2 CH=CH 2 Formula 1
[0080] The preparation method includes the following steps:
[0081] 1. Nano SiO 2 Preparation method of sol
[0082] Combine 25 parts of γ-methacryloxypropyltrimethoxysilane (silane coupling agent KH-570), 3 parts of sodium lauryl sulfate, 4 parts of alkylphenol polyoxyethylene ether (OP-10) Add to 300 parts of water, stir and disperse, then add 9 parts of ammonia under stirring, continue to stir and react for 4 hours to form nano SiO containing C=C bond 2 Sol
[0083] 2. Preparation of waterborne polyurethane prepolymer emulsion:
[0084] In ...
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