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Epoxy resin and preparation method thereof, curing agent and preparation method thereof, cured epoxy resin and preparation method thereof

A technology of epoxy resin and curing agent, which is applied in the fields of epoxy resin and its preparation, cured epoxy resin and its preparation, can solve the problems that cycloaliphatic epoxy resin is difficult to apply, and achieve good strength and toughness, Good toughness, good insulation effect

Active Publication Date: 2022-01-28
BEIJING GUODIAN FUTONG SCI & TECH DEV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] The invention provides an epoxy resin and a preparation method thereof, aiming at solving the problem that the cycloaliphatic epoxy resin is difficult to be used as an insulating material in the electric power industry due to its brittleness.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0034] The preparation method of the epoxy resin provided by the present invention comprises mixing the primary mixed raw materials, the second mixed raw materials and the third mixed raw materials, in parts by weight, the primary mixed raw materials include 350-420 parts of glycidyl hexahydrophthalate and poly 390-400 parts of propylene glycol diglycidyl ether, 5-15 parts of silane coupling agent as the second-mix raw material, 250-300 parts of quartz powder and 160-180 parts of the first flame retardant.

[0035] Optionally, the silane coupling agent includes γ-glycidyltrimethoxysilane. Optionally, the first flame retardant includes aluminum hydroxide.

[0036] Specifically, the following processes are included:

[0037] S1. Put the initial mixed raw materials in a stirring device and mix them at a speed of 50-200r / min for 10-30min and mix them evenly to obtain a resin initial mixture.

[0038]Specifically, glycidyl hexahydrophthalate and polypropylene glycol diglycidyl et...

Embodiment 1

[0068] This embodiment provides an epoxy resin and a preparation method thereof, a curing agent for curing the above epoxy resin and a preparation method thereof, and a cured epoxy resin and a preparation method thereof.

[0069] The preparation method of the epoxy resin provided by the present embodiment comprises:

[0070] Put 400 g of glycidyl hexahydrophthalate and 400 g of polypropylene glycol diglycidyl ether in a planetary stirring device, stir at a low speed of 200 r / min for 10 min, mix and disperse evenly, and obtain a resin primary mixture.

[0071] γ-epoxypropyltrimethoxysilane 10g, hydroxyl-terminated polydimethylsiloxane 40g, nitrile rubber core-shell particles 120g, octamethylcyclotetrasiloxane 12g, cyclopolydimethylsiloxane Add 40 g of alkane, 48 g of linear polydimethylsiloxane, and 4 g of non-ionic polymeric fluorine-containing surfactant into the resin primary mixture, and stir and disperse at a high speed in a planetary stirring device at a speed of 1500 r / m...

Embodiment 2

[0081] This embodiment provides an epoxy resin and a preparation method thereof, a curing agent for curing the above epoxy resin and a preparation method thereof, and a cured epoxy resin and a preparation method thereof.

[0082] The preparation method of the epoxy resin provided by the present embodiment comprises:

[0083] Put 350 g of glycidyl hexahydrophthalate and 390 g of polypropylene glycol diglycidyl ether in a planetary stirring device, stir at a low speed of 50 r / min for 30 min, mix and disperse evenly, and obtain a resin primary mixture.

[0084] 5g of γ-epoxypropyltrimethoxysilane, 45g of hydroxyl-terminated polydimethylsiloxane, 80g of nitrile rubber core-shell particles, 5g of octamethylcyclotetrasiloxane, and cyclopolydimethylsiloxane Add 20 g of alkane, 80 g of linear polydimethylsiloxane, and 15 g of non-ionic polymeric fluorine-containing surfactant into the resin primary mixture, and stir and disperse at a high speed in a planetary stirring device at a spee...

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Abstract

The invention relates to the field of insulating materials in the electric power industry, and provides an epoxy resin. The raw materials for preparing the epoxy resin include in parts by weight: 350-420 parts of hexahydrophthalic acid glycidyl ester and 390-400 parts of polypropylene glycol diglycidyl ether , 250~300 parts of quartz powder, 160~180 parts of first flame retardant, 5~15 parts of silane coupling agent. A preparation method of epoxy resin, comprising mixing the above-mentioned raw materials. A curing agent is used for curing the above epoxy resin, and its preparation raw materials include hexahydrophthalic anhydride, methylhexahydrophthalic anhydride, quartz powder and a second flame retardant. The preparation method of the above-mentioned curing agent includes mixing the above-mentioned various raw materials. A cured epoxy resin, comprising using the above-mentioned curing agent to cure the above-mentioned epoxy resin. The cured epoxy resin has good insulation, electrical resistance, strength and toughness.

Description

technical field [0001] The invention relates to the field of insulating materials in the electric power industry, in particular, to an epoxy resin and a preparation method thereof, a curing agent and a preparation method thereof, and a cured epoxy resin and a preparation method thereof. Background technique [0002] Epoxy resins are oligomers containing two or more epoxy groups and taking organic compounds such as aliphatic, alicyclic or aromatic compounds as the skeleton. Due to the active epoxy groups in the molecular structure, they can cross-link with various types of curing agents to form insoluble, infusible thermosetting plastics with a three-way network structure. Epoxy resin has excellent physical and mechanical properties, electrical insulation properties, chemical resistance and bonding properties, and is widely used in various fields. Due to its excellent properties, epoxy resin is a kind of thermosetting resin widely used in various fields. Because the alicycl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G59/20C08G59/22C08G59/42C08K3/36C08K5/54
Inventor 赵悦菊刘杨滕济林杜婧张孝阿王建辉郑永立卢路
Owner BEIJING GUODIAN FUTONG SCI & TECH DEV