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Renewable polyurea-urethane based on dynamic covalent crosslinking of stable borate bonds, and preparation method and application thereof

A covalent cross-linking and borate bond technology, applied in polyurea/polyurethane coatings, polyurea/polyurethane adhesives, chemical instruments and methods, etc., can solve the problems of difficult to obtain strong materials and easy damage, etc. Achieve the effect of reducing complexity, increasing productivity, and excellent mechanical properties

Active Publication Date: 2019-06-18
XI AN JIAOTONG UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The condition of dynamic cross-linked polymer repair based on borate bonds is mild, and no catalyst needs to be added during the process, but its disadvantages are also significant
Borate ester structures are too reversible in water or alcohol, they are both easy to form and very easy to destroy, and the resulting materials are often soft materials (such as hydrogels) or non-structural materials, and it is difficult to obtain materials with higher strength

Method used

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  • Renewable polyurea-urethane based on dynamic covalent crosslinking of stable borate bonds, and preparation method and application thereof
  • Renewable polyurea-urethane based on dynamic covalent crosslinking of stable borate bonds, and preparation method and application thereof
  • Renewable polyurea-urethane based on dynamic covalent crosslinking of stable borate bonds, and preparation method and application thereof

Examples

Experimental program
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Effect test

preparation example Construction

[0060] A kind of renewable polyurea-urethane (PUU) preparation method based on stable borate bond of the present invention comprises the following steps: according to the molar ratio of active hydrogen and isocyanate group is 1: (0.8~1.5), nitrogen boron Dissolve the internally coordinated cyclic borate compound (abbreviated as CBC) and isocyanate compound in an organic solvent, stir well until a uniform solution is formed, and react at 40-90°C for 2-10 hours without using a catalyst to obtain PUU resin solution. This method can be called a one-step preparation method.

[0061] Another kind of renewable polyurea-urethane (PUU) preparation method based on stable borate bond of the present invention, comprises the following steps (1), according to the molar ratio of active hydrogen and isocyanate group is (1.2~2.5): 1 , Weigh the CBC and the isocyanate compound and dissolve them in an organic solvent respectively to obtain A solution and B solution. At 40-70°C, slowly add solu...

Embodiment 1

[0079] Synthesis of CBC: Measure 200mL of distilled water into a 500mL beaker, add 15g of hydroxymethylphenylboronic acid and 11g of diethanolamine under magnetic stirring, stir at 50°C until the solution is clear, and keep stirring for 30min. After most of the water was distilled off by a rotary evaporator (temperature 90°C, vacuum degree 0.06MPa), the crude product was obtained by suction filtration with a Buchner funnel and rinsed with IPA several times, and the above crude product was added to a certain amount of DMF. , heated to 100°C to make it fully dissolved, slowly lowered to room temperature, cooled in an ice-water bath for 2h, and then filtered with a Buchner funnel, the resulting product was washed with acetone for 3 times, and vacuum-dried at 80°C for 3h to obtain a white crystal product. The rate is 88%.

[0080] Synthesis of PUU: In a three-necked flask equipped with a stirrer, a thermometer and a condensation device, 9g CBC, 20g HDI triisocyanate (that is, the ...

Embodiment 2

[0089] Synthesis of CBC: Measure 200mL of distilled water into a 500mL beaker, add 20g of p-aminophenylboronic acid and 15g of triethanolamine under magnetic stirring, stir at 60°C until the solution is clear, and keep stirring for 30min. After most of the water was distilled off by a rotary evaporator (temperature 90°C, vacuum degree 0.06MPa), the crude product was obtained by suction filtration with a Buchner funnel and rinsed with IPA several times, and the above crude product was added to a certain amount of DMF. , heated to 100°C to make it fully dissolved, slowly lowered to room temperature, cooled in an ice-water bath for 1.5h, and then filtered with a Buchner funnel. The resulting product was washed with acetone for 3 times, and vacuum-dried at 80°C for 2h to obtain a white crystal product. The yield was 90%.

[0090] Synthesis of PUU: In a three-necked flask equipped with a stirrer, a thermometer and a condensation device, under a nitrogen atmosphere, 21g CBC, 25g TDI...

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Abstract

The invention discloses a renewable polyurea-urethane based on dynamic covalent crosslinking of stable borate bonds, and a preparation method and an application thereof. The preparation method comprises the following steps: dissolving an cyclic borate compound and an isocyanate compound which are coordinated in nitrogen and boron in an organic solvent according to a molar ratio of active hydrogento an isocyanate group: 1:(0.8-1.5), performing sufficient stirring to form a uniform solution, and completely reacting the uniform solution at a preset temperature to prepare a PUU resin gel, whereinthe isocyanate compound is one or a mixture of two or more of difunctional or / and trifunctional isocyanate compounds; the organic solvent is one or a mixture of two or more of strong polar solvents.The PUU of the present invention has the advantages of high strength, excellent mechanical properties, repairability and remoldability, and can be recycled many times.

Description

technical field [0001] The invention belongs to the technical field of new materials, and relates to a renewable polyurea-urethane (PUU) based on a stable borate bond and a preparation method thereof, in particular to a dynamic covalent crosslinking based on a stable borate bond Renewable polyurea-urethanes and their preparation and applications. Background technique [0002] Thermosetting polymers cross-linked by chemical bonds are widely used due to their good mechanical properties, dimensional stability and solvent resistance. However, the stable three-dimensional cross-linked network structure of thermosetting polymers restricts the large-scale relative movement of molecular chains, making them irreproducible and difficult to recycle. The resulting environmental pollution and waste of resources have become the target of the whole society. Endowing traditional thermosetting polymers with remodelability and repairability through chemical structure design is a research fie...

Claims

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Application Information

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IPC IPC(8): C08G18/32C08G18/73C08G18/75C08G18/76C08L75/12C09D175/12C09J175/12C07F5/02
Inventor 井新利张晓婷王淑娟秦娇娇刘晨晶
Owner XI AN JIAOTONG UNIV
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