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A kind of method that rotary hearth furnace prepares titanium nitrogen alloy

A titanium-nitrogen alloy and rotary hearth furnace technology, which is applied in the field of preparing titanium-nitrogen alloys in rotary hearth furnaces, can solve the problems of complex pelletizing stage of raw materials, high nitrogen content of titanium-nitrogen alloys, long process time, etc., and achieves short preparation time, high heat The effect of less loss, increased hardness and strength, and wear resistance

Active Publication Date: 2020-03-20
PANZHIHUA UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

This method prepares titanium-nitrogen alloy with high nitrogen content and low energy consumption, but the process takes a long time and the pelletizing stage of raw materials is relatively complicated

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0037] TiO 2 10kg and 3.75kg of coke were crushed into a powder with a particle size of 160 mesh, stirred evenly, and a polyvinyl alcohol aqueous solution with a mass concentration of 0.5% was used as a binder, and pressed for 8 seconds under a pressure of 10MPa to form a ball to obtain a 200 mesh spherical raw material;

[0038]Put the spherical raw material into the rotary hearth furnace, set the rotation speed of the rotary hearth furnace to 50min / r, enter the low temperature preheating zone of the rotary hearth furnace for low temperature preheating reaction, the temperature of the low temperature preheating zone is 550°C, and the holding time is 10min; then Enter the high-temperature reduction zone for high-temperature reduction-nitridation reaction. The temperature of the high-temperature reduction zone is 1850°C, the holding time is 30 minutes, and the flow rate of nitrogen gas is 1800mL / min; finally enter the cooling zone, and cool down to room temperature (25°C) with t...

Embodiment 2

[0041] TiO 2 10kg and 3.75kg of coke were crushed into a particle size of 200 mesh powder, stirred evenly, with a mass concentration of 0.5% polyvinyl alcohol aqueous solution as a binder, pressed for 8 seconds under a pressure of 10MPa to form a ball, to obtain a 200 mesh spherical raw material;

[0042] Put the spherical raw material into the rotary hearth furnace, set the rotation speed of the rotary hearth furnace to 50min / r, enter the low temperature preheating zone of the rotary hearth furnace for low temperature preheating reaction, the temperature of the low temperature preheating zone is 550°C, and the holding time is 10min Then enter the high-temperature reduction zone for high-temperature reduction-nitridation reaction, the temperature of the high-temperature reduction zone is 1850 ° C, the holding time is 30 minutes, and the feed rate of nitrogen is 2100 mL / min; finally enter the cooling zone, and cool to room temperature with the furnace for 10 minutes ( 25°C) to ...

Embodiment 3

[0045] TiO 2 10kg and 3.75kg of coke were crushed into a particle size of 200 mesh powder, stirred evenly, with a mass concentration of 0.5% polyvinyl alcohol aqueous solution as a binder, pressed for 8 seconds under a pressure of 10MPa to form a ball, to obtain a 200 mesh spherical raw material;

[0046] Put the spherical raw material into the rotary hearth furnace, set the rotation speed of the rotary hearth furnace to 50min / r, enter the low temperature preheating zone of the rotary hearth furnace for low temperature preheating reaction, the temperature of the low temperature preheating zone is 550°C, and the holding time is 10min Then enter the high-temperature reduction zone for high-temperature reduction-nitridation reaction, the temperature of the high-temperature reduction zone is 1900 ° C, the holding time is 30 minutes, and the feed rate of nitrogen gas is 2300 mL / min; finally enter the cooling zone, and cool to room temperature with the furnace for 10 minutes ( 25°C)...

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Abstract

The invention provides a method for preparing a titanium-nitrogen alloy through a rotary hearth furnace and belongs to the technical field of material preparation. The method comprises the steps of mixing titanium dioxide, a carbonaceous reducing agent and a bonding agent and then conducting pelletizing to obtain a spherical raw material; and putting the spherical raw material in the rotary hearthfurnace to be subjected to low-temperature preheating reaction, high-temperature reducing-nitriding reaction to obtain the titanium-nitrogen alloy, wherein high-temperature reducing-nitriding reaction is carried out in a nitrogen atmosphere. Through the method, three operation areas (a low-temperature preheating area, a high-temperature reducing area and a cooling area) of the rotary hearth furnace are made full use of. Compared with a traditional titanium-nitrogen alloy preparation process, the method provided by the invention has the advantages that heat loss is less, and the preparation time is short; there is CO to be formed in the preparation process, the oxygen content of the titanium-nitrogen alloy is reduced, and the hardness, strength and abrasion resistance of the titanium-nitrogen alloy are improved.

Description

technical field [0001] The invention relates to the technical field of material preparation, in particular to a method for preparing a titanium-nitrogen alloy in a rotary hearth furnace. Background technique [0002] Since 1975, low-carbon microalloyed steel has developed rapidly because of its energy-saving and resource-saving properties, as well as its excellent comprehensive properties such as high strength, high toughness and plasticity. At present, industries such as petroleum, chemical industry, automobile, shipbuilding, and building materials have put forward more stringent requirements for materials such as strength, toughness, and welding performance. Coupled with the further development of smelting, processing, and heat treatment, the production of microalloyed steel has become inevitable. trend. [0003] Titanium is the main microalloying element in early microalloyed steels. It is worth paying attention to the role of titanium carbides and nitrides in steelmakin...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C1/00C22C14/00C22B1/244
CPCC22B1/2406C22B1/244C22C1/00C22C14/00
Inventor 杨绍利朴荣勋马兰陈书锐
Owner PANZHIHUA UNIV