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Manufacturing method of carbon fiber bundle

A manufacturing method and technology of carbon fiber bundles, applied in the direction of carbon fiber, fiber type, fiber treatment, etc., can solve the problems of fiber bundles such as difficulty in fiber opening, difficult to disperse uniformly, instability, etc., and achieve excellent mechanical properties, good fiber opening performance, and excellent affinity effect

Pending Publication Date: 2019-07-23
ZHENJIANG COLLEGE
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  • Abstract
  • Description
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  • Application Information

AI Technical Summary

Problems solved by technology

If the fiber opening and dispersion uniformity are not good, the performance of the final composite material will be low and unstable
In order to improve this phenomenon, a technology similar to glass fiber is adopted, that is, the chopped carbon fiber is dispersed in a solvent and then compounded with the resin substrate; in terms of safety and cost, the solvent used here is generally water, but The surface of carbon fiber does not have a good affinity with water, so it is difficult to disperse uniformly in water
[0004] After research, we found that one of the important reasons for the above problems is the sizing agent used by carbon fiber with epoxy resin as the main component. Because epoxy resin has a high viscosity and is a thermosetting resin, it is difficult to open the fiber bundle after sizing , and the affinity between epoxy resin and water is poor, which makes it difficult to disperse fibers in water

Method used

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Embodiment Construction

[0017] The method for manufacturing the carbon fiber bundle of the present invention will be further described in detail below in combination with specific embodiments.

[0018] In the method for producing carbon fiber bundles of the present invention, after immersing unsized carbon fibers in a bath of thermoplastic sizing agent with a concentration of 1.0-5.0%, they are subjected to dry heat treatment at 200-240°C. Preliminary drying treatment is carried out in the range of ~200°C to reduce the water content to below 2.0%. During the drying and heat treatment process, the mass reduction rate of thermoplastic sizing agent is between 30 and 70%, and the final product containing thermoplastic sizing agent 0.3 ~2.5% of carbon fiber bundles is necessary in order to enable the carbon fiber bundles to have good dispersibility in water, thereby obtaining chopped carbon fiber materials with excellent dispersibility in water, and at the same time showing good resistance to the thermopla...

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Abstract

The invention discloses a manufacturing method of a carbon fiber bundle. After non-sized carbon fibers are soaked in a thermoplastic sizing agent bath with the concentration of 1.0-5.0%, the carbon fibers are subjected to drying and heat treatment at the temperature of 200-240 DEG C, in the drying and heat treatment process, the mass reduction rate of the thermoplastic sizing agent is within 30%-70%, and finally the carbon fiber bundle containing 0.3-2.5% of the thermoplastic sizing agent is obtained. The manufacturing method has the advantages that in the molding and compounding process, thethermoplastic sizing agent is attached to the surface layers of the fibers, then by means of specific heat treatment, the fibers show excellent dispersion performance in water, meanwhile, the affinityof the fibers and a thermoplastic resin matrix is also greatly improved, the abrasion resistance and the splitting performance of the fibers are good, the fibers and resin have excellent affinity, ahigh-performance carbon fiber reinforced thermoplastic resin material can be prepared, and the manufacturing method is especially suitable for the fields such as automobile manufacturing and electronic product shells.

Description

technical field [0001] The invention relates to a method for manufacturing reinforced materials of composite materials, in particular to a method for manufacturing carbon fiber bundles. Background technique [0002] As a reinforcing material for advanced composite materials, carbon fiber has been widely used in the fields of aerospace and high-end sporting goods. In recent years, with the continuous decline of its cost, its application in energy, automobile manufacturing and electronics industries is also rapidly expand. In traditional application fields such as aerospace, carbon fiber is mainly compounded with thermosetting resin in the form of continuous fiber, so the sizing agent used is mostly an aqueous emulsion of epoxy resin. However, in many industrial fields such as automobile manufacturing, not only low cost is required, but also the molding shape is complicated. Therefore, carbon fibers are generally in the form of chopped fibers and compounded with thermoplastic...

Claims

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Application Information

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IPC IPC(8): D06M15/568C08G18/76C08G18/66C08G18/48C08G18/32C08J5/06C08L101/00C08K9/04C08K7/06D06M101/40
CPCD06M15/568C08G18/7614C08G18/66C08G18/4833C08G18/3215C08J5/06D06M2101/40D06M2200/40C08K9/08C08K7/06C08J2300/22
Inventor 刘福杰王国喜
Owner ZHENJIANG COLLEGE
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