Technology method used for producing poly aluminium chloride and calcium aluminate

A technology of polyaluminum chloride and process method, which is applied in the preparation of aluminum chloride, calcium aluminate, alkaline earth metal aluminate/aluminum oxide/aluminum hydroxide, etc., and can solve the problems of incomplete harmless treatment and fluoride Problems such as untreated gas and innocuousness have not been achieved, and the effect of realizing resource reuse, avoiding further innocuous treatment, and efficient recovery

Active Publication Date: 2019-09-03
XINJIANG JOINWORLD CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, this invention has disadvantages: on the one hand, the mixed salt obtained after solid-liquid separation has not been rationally utilized as a resource; Gases containing fluoride are produced in the
A new problem has arisen: this process method is incomplete in the harmless treatment of the secondary aluminum ash recycling, and the secondary pollution that may be caused in the process of producing the refining agent calcium aluminate has not been controlled, although the cost has been reduced However, it is not ideal in terms of the integrity of the process method and the harmless treatment of aluminum ash
[0006] However, this invention has disad

Method used

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  • Technology method used for producing poly aluminium chloride and calcium aluminate

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Experimental program
Comparison scheme
Effect test

Embodiment 1

[0047] The specific operation steps are as follows, and the process flow chart is as follows: figure 1 Shown:

[0048] (1) The aluminum ash is processed by frying ash sieving method, and metal aluminum is recovered to obtain secondary aluminum ash.

[0049] (2) Deamination treatment: the secondary aluminum ash is added in the deamination tank, and water and catalyst (sodium carbonate) are added simultaneously, the consumption of water is 10% of the secondary aluminum ash consumption, and the consumption of the catalyst is the secondary aluminum ash consumption 0.3% of 0.3%, stir evenly, carry out deamination treatment 24h, obtain the aluminum ash slurry after deamination;

[0050] The ammonia gas produced in the deamination process is collected and sent to the ammonia absorption tower, washed and absorbed by water circulation, and sent to the power plant for denitrification when the concentration of circulating liquid ammonia is greater than 5%.

[0051] (3) Defluorination t...

Embodiment 2

[0059] The specific operation steps are as follows, and the process flow chart is as follows: figure 1 Shown:

[0060] (1) The aluminum ash is processed by frying ash sieving method, and metal aluminum is recovered to obtain secondary aluminum ash.

[0061] (2) Deamination treatment: the secondary aluminum ash is added in the deamination tank, and water and catalyst (sodium carbonate) are added simultaneously, the consumption of water is 10% of the secondary aluminum ash consumption, and the consumption of the catalyst is the secondary aluminum ash consumption 0.3% of 0.3%, stir evenly, carry out deamination treatment 24h, obtain the aluminum ash slurry after deamination;

[0062] The ammonia gas produced in the deamination process is collected and sent to the ammonia absorption tower, washed and absorbed by water circulation, and sent to the power plant for denitrification when the concentration of circulating liquid ammonia is greater than 5%.

[0063] (3) Defluorination t...

Embodiment 3

[0069] The specific operation steps are as follows, and the process flow chart is as follows: figure 1 Shown:

[0070] (1) The aluminum ash is processed by frying ash sieving method, and metal aluminum is recovered to obtain secondary aluminum ash.

[0071] (2) Deamination treatment: the secondary aluminum ash is added in the deamination tank, and water and catalyst (sodium carbonate) are added simultaneously, the consumption of water is 10% of the secondary aluminum ash consumption, and the consumption of the catalyst is the secondary aluminum ash consumption 0.3% of 0.3%, stir evenly, carry out deamination treatment 24h, obtain the aluminum ash slurry after deamination;

[0072] The ammonia gas produced in the deamination process is collected and sent to the ammonia absorption tower, washed and absorbed by water circulation, and sent to the power plant for denitrification when the concentration of circulating liquid ammonia is greater than 5%.

[0073] (3) defluorination t...

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Abstract

The invention discloses a technology method used for producing poly aluminium chloride and calcium aluminate. The technology method comprises following steps: 1, ash stir frying is carried out, and metal aluminum is recycled so as to obtain secondary aluminum ash; 2, the secondary aluminum ash is subjected to deamination processing so as to obtain a deaminated aluminum ash slurry; 3, the deaminated aluminum ash slurry is subjected to defluorination processing so as to obtain a defluorinated aluminum ash slurry; 4, the defluorinated aluminum ash slurry is filtered so as to obtain a filtrate anda filtration residue, wherein the filtrate is a poly aluminium chloride solution; and 5, the filtration residue is washed until the pH value is 7, is uniformly mixed with a calcium based auxiliary material, drying and high temperature reaction are carried out, after reaction, cooling, crushing, and grinding processing are carried out so as to obtain calcium aluminate. According to the technologymethod used for producing poly aluminium chloride and calcium aluminate, secondary aluminum ash is subjected to complete harmless processing, so that high efficiency resource utilization of secondaryaluminum ash is realized, and the produced products possess better economical benefit.

Description

technical field [0001] The invention specifically relates to a process for producing polyaluminum chloride and calcium aluminate by utilizing aluminum ash. Background technique [0002] Aluminum ash produced during aluminum electrolysis is an industrial waste with large output and serious pollution. The main source of aluminum ash: aluminum ash produced in the process of electrolytic production of alumina molten salt, aluminum ash in the process of aluminum electrolytic smelting, aluminum ash in the process of aluminum melting and casting, aluminum ash in the process of secondary aluminum processing, simultaneous operation and measurement A certain amount of aluminum ash will also be generated from the carrying of appliances, anode replacement, aluminum tapping, ingot casting, and overhaul of electrolytic cells. The newly released aluminum ash and aluminum slag contain a large amount of metallic aluminum, of which only part of the aluminum can be recycled, and the remaining...

Claims

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Application Information

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IPC IPC(8): C01F7/16C01F7/58
CPCC01F7/164C01F7/58
Inventor 昌振利曹新乐赵霞李海珍陈润冬随文强
Owner XINJIANG JOINWORLD CO LTD
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