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Preparation method of composite material with negative dielectric constant and negative permeability metamaterial performance

A technology of composite materials and metamaterials, which is applied in the field of preparation of carbon nanotube/polyolefin elastomer composite materials, can solve the problems of limited application, matching of negative permittivity and magnetic permeability, etc., and achieves simple and convenient preparation methods and expanded The effect of application range

Inactive Publication Date: 2019-10-15
TONGJI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Another situation is that a large number of conductive loops are formed in the system, which will generate an induced current under the applied electromagnetic field, which in turn leads to the generation of negative magnetic permeability
At present, most researches use magnetic particles or metal materials to prepare double-negative metamaterials. The negative value of the dielectric constant of the prepared material cannot match the magnetic permeability, which greatly limits its application.

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  • Preparation method of composite material with negative dielectric constant and negative permeability metamaterial performance

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preparation example Construction

[0028] A method for preparing a composite material with double negative metamaterial properties, the following method steps can be used:

[0029] 1. Swelling polyolefin elastomer (POE): weigh POE 0.1-0.5g, weigh a certain amount of organic solvent, you can choose one of toluene, acetone, and n-hexane, and the mass ratio of POE to organic solvent is 1:3 , Grind the two uniformly and let stand at 25°C for 10-40min to make POE swell.

[0030] 2. Preparation of carbon nanotube (CNT) / polyolefin elastomer composite material: Weigh 0.01-0.1g CNT, fully grind it with swollen POE, and then dry it in an oven at 30-40°C to remove the solvent.

[0031] 3. Preparation of carbon nanotube / polyolefin elastomer metamaterial block: Weigh 0.5-1.5g of conductive silver glue, mix with powdered CNT / POE composite material particles, and then under 1.0-10.0MPa in PTFE Curing in an vinyl mold for 2-18 hours to prepare a composite material with double-negative metamaterial properties.

[0032] The fo...

Embodiment 1

[0034] This embodiment is a method for preparing a carbon nanotube / polyolefin elastomer composite material with metamaterial properties, which is carried out according to the following steps:

[0035] Swelling polyolefin elastomer (POE): Weigh 0.288g of POE, weigh toluene as an organic solvent, the mass ratio of POE to organic solvent is 1:3, grind both uniformly and let stand at 25°C for 10min to make POE swell .

[0036] Preparation of carbon nanotube (CNT) / polyolefin elastomer composite material: Weigh 0.012g of CNT, fully grind it with swollen POE, and then dry it in an oven at 30°C to remove the solvent.

[0037] Preparation of carbon nanotube / polyolefin elastomer metamaterial block: Weigh 1.5g of conductive silver glue, mix it with powdered CNT / POE composite material particles, and then solidify and form it in a polytetrafluoroethylene mold under a certain pressure.

[0038] In the present invention, CNT is evenly attached to the POE surface in a swelling manner, and a ...

Embodiment 2

[0041] This embodiment is a method for preparing a carbon nanotube / polyolefin elastomer composite material with metamaterial properties, which is carried out according to the following steps:

[0042] Swelling polyolefin elastomer (POE): Weigh 0.282g of POE, weigh acetone as an organic solvent, and the mass ratio of POE to organic solvent is 1:3. Grind both uniformly and let stand at 25°C for 20 minutes to make POE swell .

[0043] Preparation of carbon nanotube (CNT) / polyolefin elastomer composite material: Weigh 0.018g of CNT, fully grind it with swollen POE, and then dry it in an oven at 40°C to remove the solvent.

[0044]Preparation of carbon nanotube / polyolefin elastomer metamaterial block: Weigh 1.5g of conductive silver glue, mix it with powdered CNT / POE composite material particles, and then solidify and form it in a polytetrafluoroethylene mold under a certain pressure.

[0045] In the present invention, CNT is evenly attached to the POE surface in a swelling manner...

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Abstract

The invention relates to a preparation method of a composite material with negative dielectric constant and negative permeability metamaterial performance, the method comprises the following steps: uniformly mixing a polyolefin elastomer and an organic solvent, and standing to swell the polyolefin elastomer; mixing carbon nano tubes with the swollen polyolefin elastomer, and then drying to removethe solvent to obtain a carbon nano tube / polyolefin elastomer composite material; uniformly stirring a conductive silver adhesive and the carbon nanotube / polyolefin elastomer composite material, and then curing and molding to obtain the composite material with the negative dielectric constant and negative permeability metamaterial performance. Compared with the prior art, the metamaterial with thenegative dielectric constant and negative permeability performance is prepared for the first time by using an insulating polymer-the polyolefin elastomer as a matrix, the application range of the metamaterial is greatly expanded, and the metamaterial can be applied in the fields of stealth, miniature antennas, electronic components and the like.

Description

technical field [0001] The invention relates to the field of materials, in particular to a method for preparing a carbon nanotube / polyolefin elastomer composite material with double negative metamaterial properties. Background technique [0002] There are two ways to generate double-negative metamaterial properties with negative permittivity and negative permeability, respectively. First of all, there are two types of negative permittivity, the Drude model and the Lorentz model. There are also two completely different mechanisms for the generation of negative magnetic permeability. One case is the phenomenon that the composite material whose filler is magnetic particles will produce negative magnetic permeability. The frequency dependence of permeability can be represented by two types of magnetic resonance: domain wall motion and gyromagnetic spin motion. Another situation is that a large number of conductive loops are formed in the system, which will generate an induced...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L23/08C08L101/00C08K3/04C08K3/08C08J3/21
CPCC08J3/212C08K2003/0806C08L23/0815C08L101/00C08K3/041C08K3/08
Inventor 邱军骆红春
Owner TONGJI UNIV
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