A kind of preparation method of azo oxide and azo stilbene dye
A technology of azo oxide and stilbene, which is applied in the field of dyes, can solve the problems of non-separation, inconvenient dyes, and unusability, and achieve good cellulose affinity, simple process steps, and strong operability
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Embodiment 1
[0036] The preparation method of dye Direct Yellow 11 is as follows:
[0037] Slowly add 11.9 parts of 4-nitrotoluene-2-sulfonic acid to 44 parts of 25% tetramethylammonium hydroxide aqueous solution (40°C), and stir to form a blue-purple solution. At 70°C, the reaction was stirred for 5h. After the reaction, a reddish-brown transparent solution was formed, and 4.7 parts of 30% hydrochloric acid was added to the solution to adjust the pH to 8 to obtain a yellow solution with a maximum absorption wavelength of 414 nm.
[0038] Dye structural formula I, as shown in the figure below:
[0039] (I)
[0040] Among them, X represents the group N ⊕ (CH 3 ) 4 .
Embodiment 2
[0042] The preparation method of dye Direct Yellow 11 is as follows:
[0043] Slowly add 4-nitrotoluene-2-sulfonic acid to 15% tetramethylammonium hydroxide aqueous solution, the molar ratio of 4-nitrotoluene-2-sulfonic acid to tetramethylammonium hydroxide is 1:2, Stir to form a blue-violet solution. At 65°C, the reaction was stirred for 8h. After the reaction, a reddish-brown transparent solution was formed, and hydrochloric acid was added to the solution to adjust the pH to 7 to obtain a yellow solution with a maximum absorption wavelength of 410 nm.
[0044] Structure is with embodiment 1.
Embodiment 3
[0046] The preparation method of dye Direct Yellow 11 is as follows:
[0047]Slowly add 4-nitrotoluene-2-sulfonic acid to 30% tetramethylammonium hydroxide aqueous solution (40°C), the molar ratio of 4-nitrotoluene-2-sulfonic acid to tetramethylammonium hydroxide 1:5, stirring to form a blue-purple solution. The reaction was stirred at 85 °C for 4 h. After the reaction, a reddish-brown transparent solution was formed, and hydrochloric acid was added to the solution to adjust the pH to 9 to obtain a yellow solution with a maximum absorption wavelength of 416 nm.
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