4results about "Styryl-azo dyes" patented technology

The present invention discloses a preparation method of yellow azoxy and azo stilbene dyes. Using 4-nitrotoluene-2-sulfonic acid as a raw material and water as a reaction solvent, in the presence of choline hydroxide, dye yellow 11 is obtained through a condensation reaction. The molecular structure of choline hydroxide contains a quaternary ammonium salt group and a hydroxyl group. The hydroxyl group provides additional hydrophilicity, which helps to improve the solubility and dispersibility of the dye in an aqueous medium and enhance the affinity between the dye and the fiber. Choline hydroxide can effectively provide the alkaline environment required for the reaction, promote the synthesis reaction of the dye, and better control the selectivity and yield of the reaction. Since the choline hydroxide molecule contains a hydroxyl group, it can form hydrogen bonds with the sulfonic acid groups in the dye molecule, enhance the stability between dye molecules, and improve the light fastness and acid and alkali resistance of the dye. Using choline hydroxide not only optimizes the reaction conditions, improves the purity and yield of the dye, but also significantly improves the performance of dye yellow 11.

Provided is a preparation method for a yellow oxidized azo and azo-stilbene dye, including the following steps: taking 4-nitrotoluene-2-sulfonic acid as a starting material, and taking water as a reaction solvent to obtain Direct Yellow 11 through a condensation reaction in the presence of choline hydroxide. A molecular structure of choline hydroxide contains both a quaternary ammonium group and a hydroxyl group. The hydroxyl group provides additional hydrophilicity, which is conducive to improving the solubility and dispersibility of the dye in aqueous media, thereby enhancing affinity of the dye with fibers. Choline hydroxide can effectively provide the alkaline environment required for the reaction, promoting the progress of dye synthesis, and controlling the selectivity and yield of the reaction better. The choline hydroxide can form hydrogen bonds with the sulfonic acid groups in the dye molecules, thereby enhancing intermolecular stability and improving light fastness and acid / alkali resistance of Direct Yellow 11.

The application provides a preparation method of quaternary ammonium base and application thereof in dye synthesis. Propylene oxide is added into trimethylamine, nucleophilic ring-opening addition reaction of trimethylamine to the epoxy group of propylene oxide is carried out, hydroxypropyltrimethylammonium hydroxide is obtained, then the hydroxypropyltrimethylammonium hydroxide is used to replace sodium hydroxide in the dye synthesis process, inorganic salt is not introduced into the reaction system, and after the reaction is completed, multiple water washing and salt removal are not needed, so that the wastewater amount and salt load can be obviously reduced.

Disclosed in the present invention is a method for preparing yellow azo oxide and azo distyrylbenzene dyes, which method comprises: taking 4-nitrotoluene-2-sulfonic acid as a raw material and water as a reaction solvent, and performing a condensation reaction in the presence of choline hydroxide to obtain dye yellow 11. The molecular structure of choline hydroxide contains a quaternary ammonium salt group and a hydroxyl, wherein the hydroxyl provides additional hydrophilicity, and facilitates improving the solubility and dispersity of the dyes in an aqueous medium and enhancing the affinity between the dyes and fibers. The choline hydroxide can effectively provide an alkaline environment required by the reaction, promote the synthetic reaction of the dyes, and better control the selectivity and yield of the reaction. The choline hydroxide molecule contains a hydroxyl, which can form a hydrogen bond with a sulfonic acid group in dye molecules, such that the stability between the dye molecules is enhanced, and the light resistance and acid-base resistance of the dyes are improved. Using choline hydroxide not only optimizes reaction conditions, and increases the purity and the yield of the dyes, but also significantly improves the performance of dye yellow 11.