140 results about "Methine group" patented technology

A photoelectric conversion element is provided and includes: an electrically conductive thin layer; an organic photoelectric conversion layer; and a transparent electrically conductive thin layer. The organic photoelectric conversion layer contains: a compound represented by formula (I); and a fullerene or a fullerene derivative.

In the formula, Z₁ represents an atomic group necessary for forming a 5- or 6-membered ring, L₁, L₂ and L₃ each independently represents an unsubstituted methine group or a substituted methine group, D₁ represents an atomic group, and n represents an integer of 0 or more.

A curable composition containing a lake dye having an absorption maximum in the wavelength region of from 700 nm to 1100 nm and a thermosetting compound and/or a photo-setting compound; a solid imaging device installing therein a filter prepared using the curable composition; and a lake dye represented by the following formula (V):

wherein L¹ represents a methine chain composed of odd number(s) of methine group(s); A¹ and A² are each independently represents an alkyl group having a sulfo group; Y represents a cation necessary to balance a charge and selected from the group consisting of alkali earth metal ions (Mg²⁺, Ca²⁺, Ba²⁺, Sr²⁺), transition metal ions (Ag⁺, Fe⁺, Co²⁺, Ni²⁺, Cu²⁺, Zn²⁺) and (Al³⁺).

The invention relates to compounds of a general formula (I): wherein Ar<1>is an optionally-substituted aryl or heteroaromatic group; R<1 >is an optionally-substituted lower alkyl, lower alkenyl, lower alkynyl or cyclo-lower alkyl group, or is an aryl, aralkyl or heteroaromatic group optionally having a substituent; R<2>is a hydrogen atom, a lower alkyl group, a lower alkenyl group or a lower alkynyl group, or is an aryl, aralkyl or heteroaromatic group optionally having a substituent; R<3>is a hydrogen atom or a lower alkyl group; R<4>is a hydrogen atom, a halogen atom, a hydroxyl group, a lower alkyl group or a group of -N(R<1k>)R<1m>; T and U are a nitrogen atom or a methine group, etc. The compounds of the invention have excellent Weel kinase-inhibitory effect and are therefore useful in the field of medicines, especially treatment of various cancers.

A subject matter of the invention is cyanine derivatives of formula:

in which the dotted lines represent the atoms necessary for the formation of one or two fused aromatic rings, each ring comprising 5 or 6 carbon atoms;

• R₁, R₂, R₃ and R₄ represent, independently of one another: H; substituted or unsubstituted C₁-C₁₅ alkyl; C₁-C₆ alkoxy; (C₂-C₁₂)dialkylamino; C₁-C₆ alkoxycarbonyl; di(C₂-C₁₂)alkylamido; a substituted or unsubstituted aryl, arylalkyl or aryloxy group; a halogen atom; a nitro; an L1-W, L2-M, L2-A or L2-G group;
• R₅ and R₆ represent, independently of one another: substituted or unsubstituted C₁-C₁₅ alkyl; a substituted or unsubstituted aryl or arylalkyl group; an L1-W, L2-M, L2-A or L2-G group;
• X is chosen from: O, S or CR₇R₈; Y is chosen from: O, S or CR₉R₁₀;
• R₇, R₈, R₉ and R₁₀ independently represent: substituted or unsubstituted C₁-C₁₅ alkyl; substituted or unsubstituted aryl, arylalkyl or aryloxy; an L1-W, L2-M, L2-A or L2-G group;
• R₇ and R₈ and/or R₉ and R₁₀ can also together form a ring comprising 5 or 6 atoms or a heterocycle comprising 4 to 5 carbon atoms and an oxygen atom;
• B represents a polymethine bridge comprising 1 to 5 methine groups, said groups being in particular individually unsubstituted or substituted by a substituted or unsubstituted C₁-C₁₅ alkyl; a substituted or unsubstituted aryl, arylalkyl or aryloxy group; a nitro group; an L1-W, L2-M, L2-A or L2-G group;
• L1 and L2 are connecting arms; G is a reactive group; A is a coupling agent; M is a conjugated molecule, W is a phosphate or phosphonate ester (preferably diester), with the proviso that the cyanine derivative comprises at least one L1-W group and at least one L2-A, L2-G or L2-M group.

Provided is an organic electroluminescent device (organic EL device), in which the luminous efficiency of the device is improved, driving stability is sufficiently ensured, and the construction of the device is simple. This organic EL device is an organic electroluminescent device, including a light-emitting layer between an anode and a cathode laminated on a substrate, in which the light-emitting layer contains a phosphorescent light-emitting dopant and an indolocarbazole compound as a host material. Examples of the indolocarbazole compound include a compound represented by the following formula (1). It should be noted that in the formulae: a ring A and a ring B are represented by the formulae (1a) and (1b), respectively; Ar's each represent an aromatic hydrocarbon group or an aromatic heterocyclic group; R's each represent a hydrogen atom, an alkyl group, or a cycloalkyl group; X represents a methine group or a nitrogen atom; A represents an aromatic hydrocarbon group, an alkyl group, a cycloalkyl group, or a group represented by the formula (1c); and n represents 0 or 1.

Disclosed is a photosensitive composition for volume hologram recording which shows excellent interference fringe record and a volume hologram recording medium having lighter weight and excellent storage stability. The invention is directed to a volume hologram recording photosensitive composition comprising: (a) a compound having at least one active methylene group in one molecule or a compound having at least two active methine groups in one molecule; (b) a compound containing in one molecule two or more groups which are nucleophilicly added by a carbanion generating from an active methylene group or an active methine group; (c) a Michael-reaction catalyst; (d) a photopolymerizable compound; and (e) a photopolymerization initiator composition.

A composition having excellent transparency, flexibility, rubber elasticity, thermal resistance, impact resistance, abrasion resistance and the like, a composition having excellent rigidity and impact resistance as well as excellently balanced in whitening resistance, abrasion resistance and heat sealability, and a composition having excellent rubbery properties, thermal resistance, abrasion resistance and flexibility are provided.

A composition comprising a specific propylene•α-olefin copolymer for which, in a signal chart measured by ¹³C-NMR and predetermined such that the peak present at the highest magnetic field among the signals originating from CH (methine) of the constituent unit derived from an α-olefin having 4 to 20 carbon atoms is to be at 34.4 ppm, an absorption intensity A at about 22.0 to 20.9 ppm and an absorption intensity B at about 19.0 to 20.6 ppm satisfy the following relational expressions (i) and (ii) with respect to an absorption intensity C at about 19.0 to 22.0 ppm, which is assignable to propylene methyl:

(A/C)×100≦8  (i), and

(B/C)×100≧60  (ii),

a molded product thereof, and the α-olefin-based copolymer are provided.

An RMA crosslinkable composition having at least one crosslinkable component including reactive components A and B each including at least 2 reactive groups, the at least 2 reactive groups of component A being acidic protons (C—H) in activated methylene or methine groups and the at least 2 reactive groups of component B are activated unsaturated groups (C═C) and a base catalyst (C) which reactive components A and B crosslink by Real Michael Addition (RMA) reaction under action of the base catalyst, characterised in that the at least one crosslinkable component including reactive components A and B in the composition have a total hydroxy number of less than 60, preferably less than 40 and more preferably less than 20 mg KOH/g solids. Further, specific resins A and B having a low hydroxy number for use in RMA cross-linkable compositions and a process for the manufacture thereof.

A near-infrared absorptive image-forming composition, which contains a dye of formula (I):

wherein L₁ is a methine chain composed of 7 methine groups, and L₁ may have a substituent but the substituent is not an amino group; R¹, R² and A each independently are an alkyl or cycloalkyl group, which may be substituted; B is a group of atoms necessary for forming an aromatic hydrocarbon ring or aromatic heteroring, and the ring formed with B may be substituted; Y is a cation necessary for keeping the charge balance in the molecule, but Y may not be present when Y is unnecessary for the charge balance; and R¹ and R² may bond to each other, to form a ring; an ink and an electrophotographic toner, each containing the composition; and an inkjet-recording method, an electrophotographic-recording method, and a near-infrared-ray-reading method.

A near infrared fluorescent contrast agent which is excellent in permeability in a living tissue and enables specific imaging of tumor and/or blood vessel, comprising a compound represented by formula (I) or a pharmaceutically acceptable salt thereof, wherein R¹, R², R⁷, and R⁸ represent a C₁-C₁₀ alkyl group or the like; R³, R⁴, R⁵, R⁶, R⁹, R¹⁰, R¹¹, and R¹² represent a hydrogen atom, a C₁-C₆ alkyl group, an aryl group or the like; X¹ and X² represent a C₁-C₁₅ alkyl group or an aryl group and X¹ and X² in total have 0 to 4 carboxyl groups; m¹, m², and m³ represents 0 or 1; L¹ to L⁷ independently represent a methine group; M represents a hydrogen atom, a metal, or a quaternary ammonium salt; and n represents an integer of 1 to 7 necessary for neutralizing charge.

The present invention relates to a compound that has URAT1 inhibitory action, and a URAT1 inhibitor, a blood uric acid level-reducing agent and a pharmaceutical composition comprising the compound. More specifically, the present invention relates to a compound represented by Formula (I) below.

[in the formula,

• • R¹ is -Q¹-A¹ and the like; is a double bond or a single bond; when is a double bond, W¹ is a nitrogen atom or a group represented by the general formula: ═C(R^a)—, and W² is a nitrogen atom or a group represented by the general formula: ═C(R^b)—; when is a single bond, W¹ is a group represented by the general formula: —C(R^aa)(R^ab)— or a group represented by the general formula: —(C═O)—, and W² is a group represented by the general formula: —C(R^ba)(R^bb)—, a group represented by the general formula: —(C═O)— or a group represented by the general formula: —N(R^bc)—; W³, W⁴ and W⁵ are each independently a nitrogen atom or a methine group and the like that may have a substituent; X is a single bond, an oxygen atom and the like; Y is a single bond or (CR^YiR^Yi′)_n; and Z is a hydroxyl group or COOR² and the like.

The emulsion composition of the present invention contains

• • (A) 0.001 to 10 wt. % of an organic compound having two or more hydroxyl groups, an inorganic value of 220 to 450, and an organic value of 300 to 1,000;
  • (B) 0.001 to 10 wt. % of an organic compound having one hydroxyl group, an inorganic value of 100 to 200, and an organic value of 280 to 700;
  • (C) 0.001 to 10 wt. % of a compound represented by formula (2):

wherein R¹ is a C4 to C30 hydrocarbon group; Z is a methylene group, a methine group, or an oxygen atom; X¹, X², X³ is a hydrogen atom, a hydroxyl group, or an acetoxy group; X⁴ is a hydrogen atom, an acetyl group, or a glyceryl group; each of R² and R³ a hydrogen atom, a hydroxyl group, a hydroxymethyl group, or an acetoxymethyl group; R⁴ is a C5 to C60 hydrocarbon group; and R⁵ is a hydrogen atom or a hydrocarbon group containing 1 to 30 carbon atoms in total;

(D) 0.00012 to 10 wt. % of at least one compound selected from the group consisting of a nonionic surfactant having a polyoxyethylene group and an HLB of 10 or higher, an ionic surfactant, and a sphingosine salt;

(E) 0.003 to 15 wt. % of at least one compound selected from the group consisting of a sugar alcohol selected from the group consisting of erythritol, threitol, xylitol, and mannitol, a disaccharide, and a trisaccharide; and

(F) water.

A photoelectric conversion device is provided and includes a photoelectric conversion layer containing a compound represented by the following formula (1). Formula (1):

In the formula, Z₁ represents an atomic group for forming a 5- or 6-membered nitrogen-containing heterocyclic ring; Za represents an atomic group for forming a 5- or 6 membered ring; R₁ represents a hydrogen atom, an alkyl group, an alkenyl group, an aryl group or a heterocyclic group; L₁₁ to L₁₄ each represents a methine group which may have a substituent or may form a ring with another methine group; p1 represents 0 or 1; n1 represents an integer of 0 to 4 and when n1 is an integer of 2 or more, each L₁₃ or L₁₄ may be the same as or different from every other L₁₃ or L₁₄; M1 represents an ion for neutralizing the electric charge; and m1 represents a number necessary for neutralization of the electric charge; provided that a compound where Z₁ is an atomic group forming a thiazoline nucleus or a thiazole nucleus is excluded.

Provided is an azole derivative which can be contained as an active ingredient in an agricultural or horticultural chemical agent having an excellent disease control effect. This azole derivative is represented by general formula (I). (In formula (I), R1 represents a C1-C6 alkyl group which may be substituted; R2 represents a functional group containing a carbonyl group, wherein a carbon atom in the carbonyl group is bonded to both a carbon atom substituted by R1 in the cyclopentane ring and any one selected from a hydrogen atom, a hydroxyl group, R3, OR3 and NR3R4; R3 and R4 independently represent a C1-C6 alkyl group, a C2-C6 alkenyl group or a C2-C6 alkynyl group; Y represents a halogen atom, a C1-C4 alkyl group, a C1-C4 haloalkyl group, a C1-C4 alkoxy group, a C1-C4 haloalkoxy group, a phenyl group, a cyano group or a nitro group; m represents 0-5; and A represents a nitrogen atom or a methine group.).

The present invention is to provide a curable coating composition having much less of a volatile organic component, and being excellent in coating film performance such as durability and scratch resistance, and a coating film forming method using the above curable coating composition capable of suppressing generation of sagging and so on. The present invention is a curable coating composition which comprises (a) a component having an active methylene group and/or an active methine group, (b) a component having a methacrylate group and/or an acrylate group, (c) a Michael reaction catalyst and (d) a photo-polymerization initiator. The present invention also provides a coating film forming method which comprises a step (1) of applying a curable coating on a substrate to be coated and a step (2) including a stage of irradiating with ultraviolet ray and a stage of heating, said curable coating comprising the above curable coating composition.

The invention discloses an MOF loaded corrosion inhibitor filler, a self-repairing anticorrosive coating and a preparation method thereof. The filler takes a metal organic framework compound hmt-MOF as a capsule shell and an encapsulated corrosion inhibitor as a capsule core, and an hmt-MOF compound is formed by assembling two organic polydentate ligands including hexamethylenetetramine and terephthalic acid; amino nitrogen atoms in hexamethylenetetramine and carboxyl oxygen atoms in terephthalic acid can react with functional groups in resin, compatibility is good, dispersion is easy, high storage stability is achieved, and the compound can react with a metal substrate to generate -N/O coordination bonds, hydrogen bonds and the like; and the adhesive force and the corrosion resistance ofthe coating and the substrate are enhanced, and a high self-repairing function can be kept for a long time in an acid-base environment. The raw materials are easy to obtain and low in toxicity, the production technological process is simple, preparation is easy, the trend of green and environment-friendly development is met, large-scale industrial production can be achieved, and good application prospects are achieved.

The photosensitive resin composition contains a binder resin (A), a photopolymerizable compound (B), a photopolymerization initiator (C) and a solvent (D), wherein the binder resin (A) comprises a polymer (AA) containing a structural unit (A1) derived from at least one kind of compound selected from a group consisting of unsaturated carboxylic acids and unsaturated carboxylic acid anhydrides, a structural unit (A2) derived from an unsaturated compound having at least one kind of group selected from a group consisting of active methylene groups and active methine groups, and a structural unit (A3) derived from a monomer copolymerizable with the structural unit (A1) and the structural unit (A2), however, (A3) excluding the structural unit (A1) and the structural unit (A2).

In the presence of an imide compound (e.g., N-hydroxyphthalimide) shown by the following formula (1):wherein R1 and R2 represent a hydrogen atom, a halogen atom, an alkyl group, an aryl group and a cycloalkyl group, and R1 and R2 may bond together to form a double bond, or an aromatic or non-aromatic ring, and Y is an O or OH, and n denotes 1 to 3;a substrate is allowed to contact with at least one reactant selected from (i) a nitrogen oxide and (ii) a mixture of carbon monoxide and oxygen to be introduced with at least one functional group selected from a nitro group and a carboxyl group. The nitrogen oxide includes, for example, a compound represented by the formula NxOy (e.g., N2O3, NO2). The substrate includes, for example, a compound having a methine carbon atom (e.g., adamantane), a compound having a methyl group or a methylene group at an adjacent moiety of an aromatic ring. According to such reaction, the substrate can be efficiently nitrated or carboxylated even in a mild or moderate condition.