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Treatment method of acidic chromium-containing electroplating wastewater

A treatment method, chromium electroplating technology, is applied in the field of treatment of acidic chromium-containing electroplating wastewater, which can solve the problems of large dosage of chemicals, incomplete copper and nickel treatment, etc., achieve low operating cost, realize safe reuse, and high operability and the effect of applying the value

Inactive Publication Date: 2019-11-01
HENAN UNIVERSITY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0005] In order to solve the problems in the prior art that the dosage of medicaments is large and the copper and nickel in wastewater are not completely treated when treating chromium-containing wastewater, the present invention provides a treatment method for acidic chromium-containing electroplating wastewater

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0021] Take 10mL of hydrazine hydrate and mix and dilute with 50mL of water for use; Weigh 8g of ferrous sulfate and 2g of polyferric sulfate to mix, and then dissolve the mixture in 100mL of water to form a composite iron salt solution for use; Weigh 0.1 g Solid polyacrylamide is dissolved in 100 mL of water and prepared into a polyacrylamide solution with a concentration of 0.1% for use.

[0022] Take 10 mL of acidic chromium-containing electroplating wastewater, add 0.6 mL of hydrazine hydrate diluent to adjust the pH of the solution to 8.8, stir well for 20 minutes, then add 0.8 mL of composite iron salt solution, mix well for 5 minutes, then add 0.02 mL of polyacrylamide solution, and mix Let it homogenize for 5 minutes and filter with filter paper. The acidic chromium-containing electroplating wastewater before and after treatment was tested, and the results are shown in Table 1.

[0023] Table 1. Test results of acidic chromium-containing electroplating wastewater before an...

Embodiment 2

[0027] Take 10mL of hydrazine hydrate and mix and dilute with 40mL of water for use; Weigh 8g of ferrous sulfate and 2g of polyferric sulfate to mix, and then dissolve the mixture in 100mL of water to form a composite iron salt solution for use; Weigh 0.1 g Solid polyacrylamide is dissolved in 100 mL of water and prepared into a polyacrylamide solution with a concentration of 0.1% for use.

[0028] Take 10 mL of acidic chromium-containing electroplating wastewater, add 0.6 mL of hydrazine hydrate diluent to adjust the pH of the solution to 8.8, stir well for 20 minutes, then add 0.6 mL of composite iron salt solution, mix well for 5 minutes, then add 0.03 mL of polyacrylamide solution, and stir 2min, filter paper filter. The acidic chromium-containing electroplating wastewater before and after treatment was tested, and the results are shown in Table 2.

[0029] Table 2. Test results of acidic chromium-containing electroplating wastewater before and after treatment in Example 2

[0...

Embodiment 3

[0033] Take 10mL of hydrazine hydrate and mix and dilute with 30mL of water for use; Weigh 8g of ferrous sulfate and 2g of polyferric sulfate to mix, then dissolve the mixture in 110mL of water to form a composite iron salt solution for use; Weigh 0.3 g Solid polyacrylamide is dissolved in 100 mL of water and prepared into a polyacrylamide solution with a concentration of 0.3% for use.

[0034] Take 10 mL of acidic chromium-containing electroplating wastewater, add 0.5 mL of hydrazine hydrate diluent to adjust the pH of the solution to 8.5, stir well for 10 minutes, then add 0.6 mL of composite iron salt solution, mix well for 5 minutes, then add 0.01 mL of polyacrylamide solution, and stir 3min, filter paper filter. The acidic chromium-containing electroplating wastewater before and after treatment was tested, and the results are shown in Table 3.

[0035] Table 3. Test results of acidic chromium-containing electroplating wastewater before and after treatment in Example 3

[0036]...

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Abstract

The invention belongs to the field of electroplating wastewater treatment and in particular relates to a treatment method of acidic chromium-containing electroplating wastewater. The treatment methodcomprises the following specific treatment steps: dropping a hydrazine hydrate diluted liquid into acidic chromium-containing electroplating wastewater, adjusting the pH value of the wastewater to 7.9-8.8, and performing continuous stirring so as to obtain a mixed solution; dropping a composite iron salt solution into the mixed solution, and performing continuous stirring; further adding a polyacrylamide solution into the mixed solution to implement flocculation precipitation, performing continuous stirring, performing solid-liquid separation, and recycling a liquid after treatment. By adopting the method, the amounts of lime and iron salts can be reduced, the cost can be lowered, in addition, cobalt, copper and nickel in the solution can be efficiently and synchronously removed, and efficient purification of the acidic chromium-containing electroplating wastewater can be achieved.

Description

Technical field [0001] The invention belongs to the field of electroplating wastewater treatment, and specifically relates to a method for treating acidic chromium-containing electroplating wastewater. Background technique [0002] The rapid development of the electroplating industry is accompanied by the discharge of a large amount of electroplating wastewater, which has caused irreversible and serious harm to environmental pollution, and at the same time also poses a serious threat to human health. Electroplating wastewater often contains a large number of various heavy metal ions (chromium, copper, nickel, etc.). These metal ions will eventually enter the human body along with drinking water sources or aquatic foods and affect human health. Therefore, external control must be strictly controlled. The heavy metal content in the discharge of electroplating wastewater, especially the more toxic chromium discharge should be controlled. [0003] The usual treatment methods for elect...

Claims

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Application Information

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IPC IPC(8): C02F9/04C02F101/20C02F101/22C02F103/16
CPCC02F1/5236C02F1/56C02F1/66C02F1/70C02F9/00C02F2101/20C02F2101/22C02F2103/16
Inventor 王洋洋张改素刘祎丹
Owner HENAN UNIVERSITY