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Lead-acid storage battery pole plate, lead-acid storage battery, preparation methods and application

A lead-acid battery and plate technology, which is applied in the direction of lead-acid battery electrodes, lead-acid batteries, lead-acid battery construction, etc., can solve problems such as increased internal resistance, inactivation of active materials, and low efficiency of electric energy utilization

Active Publication Date: 2019-11-19
NANYANG NORMAL UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

You must produce as much as you want and sell as much as you want, otherwise, you will have to charge and protect the lead battery from time to time, wasting power resources and reducing the sales price of the product
[0023] In summary, the irreversible degeneration of lead batteries caused by the special self-discharge and "float charge" of lead batteries is the result of the inactivation of active materials, increased internal resistance, low energy utilization efficiency, safety hazards and end-of-life of traditional lead batteries. root cause, and its course cannot be changed by "fair use"

Method used

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  • Lead-acid storage battery pole plate, lead-acid storage battery, preparation methods and application
  • Lead-acid storage battery pole plate, lead-acid storage battery, preparation methods and application
  • Lead-acid storage battery pole plate, lead-acid storage battery, preparation methods and application

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0092] Example 1 (the metal barium plate accounts for 10wt.% in the composite plate C, and the lead-barium alloy plate containing 0.5wt.% barium accounts for 90wt.%; the barium element accounts for 10.45wt.% in the pole plate)

[0093] (1) Melt and cast the analytically pure barium particles to obtain a barium bar with a specification of 20mm×4mm×40mm and a barium content of 99.95wt.%. 4mm × 40mm, barium-containing 0.5wt.% lead-barium alloy strip; under nitrogen atmosphere, use boron glass material pressure roller to roll the barium strip containing barium 99.95wt.% into a 0.1mm thick metal barium plate, get A Plate, the barium-containing 0.5wt.% lead-barium alloy bar is rolled into a lead-barium alloy plate with a thickness of 0.2mm, the same width as plate A, and twice the area to obtain plate B (alloy phase composition is BaPb 3 and αBaPb ​​crystallite); according to the "B-A-B" way to stack A and B boards, use the same material with double-rollers with shallow concave-conv...

Embodiment 2

[0097] Example 2 (the metal barium plate accounts for 5wt.% in the composite plate C, and the lead-barium alloy plate containing barium 1wt.% accounts for 95wt.%; the barium element accounts for 5.95wt.% in the pole plate)

[0098] (1) Melt and cast the analytically pure barium particles to obtain a barium bar with a specification of 20mm×4mm×40mm and a barium content of 99.95wt.%. 4mm×40mm, lead-barium alloy strip containing 1wt.% barium; under a nitrogen atmosphere, roll the barium strip containing 99.95wt.% barium into a 0.1mm thick metal barium plate with a boron glass material pressure roller to obtain a plate A , the barium-containing 1wt.% lead-barium alloy bar is rolled into a lead-barium alloy plate with a thickness of 0.3mm, the same width as plate A, and twice the area to obtain plate B (alloy phase composition is BaPb 3 and αBaPb ​​crystallite); according to the "B-A-B" way to stack A and B boards, use the same material with double-rollers with shallow concave-conv...

Embodiment 3

[0102] Example 3 (the metal barium plate accounts for 3wt.% in the composite plate C, and the lead-barium alloy plate containing barium 2wt.% accounts for 97wt.%; the barium element accounts for 4.94wt.% in the pole plate)

[0103] (1) Melt and cast the analytically pure barium particles to obtain a barium bar with a specification of 20mm×4mm×40mm and a barium content of 99.95wt.%. 4mm×40mm, lead-barium alloy strip containing 2wt.% barium; under a nitrogen atmosphere, roll the barium strip containing 99.95wt.% barium into a 0.2mm thick metal barium plate with a boron glass material pressure roller to obtain a plate A , the barium-containing 2wt.% lead-barium alloy bar is rolled into a lead-barium alloy plate with a thickness of 0.4mm, the same width as plate A, and twice the area to obtain plate B (alloy phase composition is BaPb 3 and αBaPb ​​crystallite); according to the "B-A-B" way to stack A and B boards, use the same material with double-rollers with shallow concave-conv...

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Abstract

The invention belongs to the field of electric energy storage and relates to a lead-acid storage battery pole plate, a lead-acid storage battery, a preparation method of the lead-acid storage batterypole plate, a preparation method of the lead-acid storage battery and the application of the lead-acid storage battery pole plate to the preparation of the lead-acid storage battery. According to thelead-acid storage battery pole plate, the lead-acid storage battery, the preparation method of the lead-acid storage battery pole plate, the preparation method of the lead-acid storage battery and theapplication of the lead-acid storage battery pole plate to the preparation of the lead-acid storage battery of the invention, inert material metals, namely, barium and a lead-barium alloy, and a sulfuric acid solution, are used as raw materials; after lead sulfate is generated, the lead sulfate is squeezed into a barium metal plate by means of rolling, so that the lead sulfate is separated, andmeanwhile, the metal barium forms a stable and reliable conductive network; and a boron trioxide-silicon dioxide gel layer which is applied later can further seal and isolate the lead sulfate particles without impeding the transmission of sulfate ions and hydrogen ions, so that the lead-acid storage battery pole plate is obtained. With the lead-acid storage battery pole plate, the lead-acid storage battery, the preparation methods and the application of the lead-acid storage battery pole plate to the preparation of the lead-acid storage battery of the invention adopted, the irreversibility ofa traditional lead-acid storage battery in a use process is effectively avoided; the conductive network of the pole plate can keep stable for a long time; active substances are separated and arrangedin the microgrids of the conductive network and almost can repeatedly participate in charging and discharging circulation; and therefore, the lead-acid storage battery can have a long service life.

Description

technical field [0001] The invention belongs to the field of electric energy storage, and in particular relates to a lead-acid storage battery plate, a lead-acid storage battery and a preparation method and application thereof. Background technique [0002] In the secondary power supply, lead-acid batteries (hereinafter referred to as lead batteries), compared with lithium batteries, although their weight specific energy is lower, but it has abundant raw materials, relatively safe, easy maintenance and regeneration, and can be discharged with a large current. and other advantages. After research, it is found that there are five major disadvantages in current maintenance-free lead batteries, making them facing the fate of being eliminated. If you can find out the shortcomings of its structure, give full play to its advantages, greatly improve its performance, especially if it can achieve long life, then it is still very useful in areas where weight is not a concern. The fiv...

Claims

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Application Information

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IPC IPC(8): H01M4/16H01M4/20H01M4/21H01M10/12
CPCH01M4/16H01M4/20H01M4/21H01M10/12Y02E60/10Y02P70/50
Inventor 王利亚杜冰李波李森兰
Owner NANYANG NORMAL UNIV
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