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A kind of preparation method of environment-friendly and antibacterial nanocellulose composite soybean oil-based polymer foam

A nanocellulose, soybean oil-based technology, applied in the field of preparation of environmentally friendly antibacterial nanocellulose composite soybean oil-based polymer foam, can solve the problem of incomplete and inevitable decomposition of blowing agents, difficult control, and residual foam form of chemical additives And other issues

Active Publication Date: 2021-09-14
GUANGXI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the molding process of traditional nanocellulose polymer composite foam still needs the help of chemical blowing agent, and the decomposition of blowing agent is not completely unavoidable, resulting in the residue of chemical additives and the difficulty of controlling the foam shape.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0020] A preparation method of an environment-friendly and antibacterial nanocellulose composite soybean oil-based polymer foam, comprising the following steps:

[0021] (1) Preparation of antibacterial microgel emulsifier: the consumption of the following raw materials is in parts by weight, first take by weighing 40 parts of TEMPO oxidized nano-cellulose colloid, place it in a polytetrafluoroethylene mould, and then take by weighing 20 parts of mass concentration Nisin solution of 2% was added dropwise to the surface layer of TEMPO oxidized nanocellulose colloid along the mold wall with a peristaltic syringe pump at a speed of 1mL / min, and then stood at 4°C for 24h to form a hydrogel, and then added 40 parts of deionized water was treated with a high-pressure homogenizer at a pressure of 30,000 PSI for 5 minutes to obtain an antibacterial microgel emulsifier.

[0022] Among them, the preparation method of TEMPO oxidized nano-cellulose colloid is: adopt TEMPO oxidation method...

Embodiment 2

[0028] A preparation method of an environment-friendly and antibacterial nanocellulose composite soybean oil-based polymer foam, comprising the following steps:

[0029] (1) Preparation of antibacterial microgel emulsifier: the consumption of the following raw materials is in parts by weight, first take by weighing 40 parts of TEMPO oxidized nano-cellulose colloid, place it in a polytetrafluoroethylene mould, and then take by weighing 20 parts of mass concentration Nisin solution of 2% was added dropwise to the surface layer of TEMPO oxidized nanocellulose colloid along the mold wall with a peristaltic syringe pump at a speed of 1mL / min, and then stood at 4°C for 24h to form a hydrogel, and then added 40 parts of deionized water was treated with a high-speed disperser at 15,000 rpm for 5 minutes to obtain an antibacterial microgel emulsifier.

[0030] Among them, the preparation method of TEMPO oxidized nano-cellulose colloid is: pretreating the bleached bagasse fibers after m...

Embodiment 3

[0036] A preparation method of an environment-friendly and antibacterial nanocellulose composite soybean oil-based polymer foam, comprising the following steps:

[0037](1) Preparation of antibacterial microgel emulsifier: the consumption of the following raw materials is in parts by weight, first take by weighing 40 parts of TEMPO oxidized nano-cellulose colloid, place it in a polytetrafluoroethylene mould, and then take by weighing 20 parts of mass concentration Nisin solution of 2% was added dropwise to the surface layer of TEMPO oxidized nanocellulose colloid along the mold wall with a peristaltic syringe pump at a speed of 1mL / min, and then stood at 4°C for 24h to form a hydrogel, and then added 40 parts of deionized water was treated with an ultrasonic cell pulverizer at a power of 1000W for 5 minutes to obtain an antibacterial microgel emulsifier.

[0038] Among them, the preparation method of TEMPO oxidized nano-cellulose colloid is: adopt TEMPO oxidation method to pre...

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Abstract

The invention discloses a method for preparing an environment-friendly and antibacterial nano-cellulose composite soybean oil-based polymer foam. The method comprises the following steps: (1) placing TEMPO oxidized nano-cellulose colloid in a polytetrafluoroethylene mould, and then placing Add nisin solution dropwise to its surface layer, form a hydrogel after standing at 4°C for 24h, then add deionized water to disperse for 5min to obtain an antibacterial microgel emulsifier; (2) add benzoyl peroxide , acetone and epoxy soybean oil acrylate are mixed uniformly at room temperature, then add antimicrobial microgel emulsifier, and emulsify at a high speed for 5min at 15000r / min to prepare soybean oil-based foaming liquid; (3) soybean oil-based The foaming solution was poured into a polytetrafluoroethylene mold and heated at 120°C for 180 minutes to foam and solidify to form an environmentally friendly and antibacterial nanocellulose composite soybean oil-based polymer foam. The process of the invention is simple, the raw material is environmentally friendly, and the product foam has high strength and good antibacterial performance, and can be used as an antibacterial buffer material.

Description

technical field [0001] The invention belongs to the technical field of preparation of functional foam materials and antibacterial packaging materials, and in particular relates to a preparation method of an environment-friendly and antibacterial nanocellulose composite soybean oil-based polymer foam. Background technique [0002] Foam material has the characteristics of light weight, heat insulation, sound absorption, shock absorption, etc., and is a kind of cushioning material widely used in modern times. At present, the commonly used foam materials mainly include expanded polystyrene, polyurethane foam, etc. Although these foam materials have many advantages, due to the problems of non-renewable raw materials, poor biocompatibility and non-degradability, etc. It will inevitably have a certain impact on the natural environment. In addition, foam materials are widely used in food packaging, medical materials, purification and filtration, etc., but bacterial contamination is...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L91/00C08L1/04C08L89/00C08J9/30C08B15/02
CPCC08B15/02C08J9/0061C08J9/30C08J2391/00C08J2401/04C08J2489/00
Inventor 鲁鹏田旭旺吴敏刘杨黄崇杏
Owner GUANGXI UNIV