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High-heat-conductivity polypropylene composite material and preparation method thereof

A composite material and polypropylene technology, applied in the field of high thermal conductivity polypropylene composite material and its preparation, can solve problems such as poor mechanical properties and poor flow properties, achieve good compatibility, improve thermal conductivity, improve fluidity and strength Effect

Active Publication Date: 2019-12-13
CHANGZHOU UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0007] In order to solve the problems of poor mechanical properties and poor fluidity of high thermal conductivity polypropylene materials (filler powder content is more than 70%), the present invention provides a high thermal conductivity polypropylene composite material and its preparation method, using high strength, high flow Performance and polar modified polypropylene are coordinated with each other according to different proportions, so that the highly filled polypropylene thermal conductivity material can be prepared to obtain high thermal conductivity, high mechanical properties and good processing properties

Method used

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  • High-heat-conductivity polypropylene composite material and preparation method thereof
  • High-heat-conductivity polypropylene composite material and preparation method thereof
  • High-heat-conductivity polypropylene composite material and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0036] The high thermal conductivity polypropylene composite material, by weight, consists of raw materials:

[0037]

[0038] (1) carry out coupling agent surface treatment to graphite powder and graphite sheet, obtain modified graphite powder and graphite sheet;

[0039] (2) The modified graphite powder and the modified graphite sheet are mixed with maleic anhydride grafted polypropylene, 0.5 part of flow agent, and 5 parts of high fluidity polypropylene at high speed to obtain compound 1;

[0040] (3) High-strength polypropylene, chopped carbon fiber, 2 parts of high-fluidity polypropylene, 0.5 part of flow agent, and antioxidant are mixed at high speed to obtain a mixture 2;

[0041] (4) Second-stage continuous extrusion compound granulation: fully knead and plasticize the compound 1 in the first-stage twin-screw extruder, control the temperature of the melt at 180-250°C, and enter the second-stage twin-screw extruder after mixing. Out of the feeding port of the machin...

Embodiment 2

[0043]

[0044] Second-stage continuous extrusion compound granulation was adopted, and the preparation process was the same as in Example 1 to obtain a high thermal conductivity polypropylene composite material.

Embodiment 3

[0046]

[0047]

[0048] Second-stage continuous extrusion compound granulation was adopted, and the preparation process was the same as in Example 1 to obtain a high thermal conductivity polypropylene composite material.

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Abstract

The invention belongs to the field of high-heat-conductivity materials, and especially relates to a high-heat-conductivity polypropylene composite material and a preparation method thereof. The high-heat-conductivity polypropylene composite material comprises, by weight, 80-100 parts of a heat conducting filler, 0-5 parts of a chopped carbon fiber, 6-15 parts of modified polypropylene, 8-20 partsof high-strength polypropylene, 2-7 parts of high-fluidity polypropylene and assistants. High-strength, high-fluidity and polarity-modified polypropylenes are adopted at different proportions, a powder containing 70-85% by mass of graphite and graphite flakes is added, and a two-stage continuous extrusion composite granulation process is carried out to obtain the heat conducting composite materialwith the high heat conductivity, high mechanical properties and good processability; and the heat conducting coefficient of the polypropylene composite material is 4-26 W / m.k, the tensile strength is15-30 MPa, the elongation at break is 3-5%, and the flow shear rate is 1-6.

Description

technical field [0001] The invention belongs to the field of thermally conductive materials, in particular to a high thermally conductive polypropylene composite material and a preparation method thereof. Background technique [0002] Polypropylene is one of the substrates of commonly used high thermal conductivity materials, and its thermal conductivity is generally around 0.12W / (m·K). The production process of high thermal conductivity polypropylene composite materials is to add some thermal conductivity fillers to the polypropylene matrix, such as (graphite, graphene, chopped carbon fiber, carbon black, etc.), metal materials (copper, aluminum, etc.) or metal oxide materials ( Aluminum hydroxide, magnesium hydroxide, etc.), granulated by mixing and single-stage extrusion. A heat conduction material with a heat conduction coefficient of 2-4W / (m·K) is obtained, which meets the heat conduction requirements of heat conduction polypropylene products. [0003] In the above-me...

Claims

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Application Information

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IPC IPC(8): C08L23/12C08L51/06C08K13/06C08K9/06C08K3/04C08K7/06C09K5/14
CPCC08L23/12C09K5/14C08L2205/025C08L2205/03C08L51/06C08K13/06C08K9/06C08K3/04C08K7/06C08K7/00
Inventor 陶国良郑康夏艳平
Owner CHANGZHOU UNIV
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