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A kind of titanium alloy surface nitriding process

A titanium alloy and nitriding technology, which is applied in metal material coating process, coating, solid-state diffusion coating, etc., can solve the problems of slow nitriding speed, brittle treatment time of the permeated layer, thin permeated layer, etc., and achieve smooth surface , hardness and wear resistance are improved, and the effect of no cracks on the surface

Active Publication Date: 2021-11-16
HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] In view of the problems in the prior art that nitriding is generally carried out at low temperature, and there are disadvantages such as slow nitriding speed, thin nitriding layer, brittle nitriding layer and long treatment time, the present invention provides a titanium alloy surface nitriding process

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  • A kind of titanium alloy surface nitriding process
  • A kind of titanium alloy surface nitriding process
  • A kind of titanium alloy surface nitriding process

Examples

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Embodiment 1

[0041] A titanium alloy surface nitriding process, comprising the following steps:

[0042] Step 1. Pretreatment of the surface of the titanium alloy substrate: Cut the Ti-6Al-4V titanium alloy material into 15mm×80mm×10mm, grind it successively with 100 mesh, 200 mesh, and 500 mesh water abrasive paper, and then use ultrasonic waves at a frequency of 40Hz Wash it for 25 minutes under the condition, and dry it with the cold air mode of the hair dryer;

[0043] Step 2. Put the titanium alloy substrate into the nitriding device of SK-1600°C series vacuum / atmosphere tube electric furnace, seal the device, and evacuate the nitriding device to below 0.1Pa through a vacuum pump;

[0044] Step 3: Set the heating rate of the nitriding device to 5°C / min, raise the temperature to a nitriding temperature of 600°C, and maintain a vacuum environment in the furnace;

[0045] Step 4: Feed high-purity nitrogen gas into the nitriding device at a flow rate of 3 L / min, nitriding for 10 hours, a...

Embodiment 2

[0047] A titanium alloy surface nitriding process, comprising the following steps:

[0048] Step 1. Pretreatment of the surface of the titanium alloy substrate: Cut the TB6 titanium alloy material into 15mm×80mm×10mm, polish it successively with 100 mesh, 200 mesh, and 500 mesh water abrasive paper, and then clean it with ultrasonic waves for 30 minutes at a frequency of 35Hz , and blow dry with a hair dryer in cold mode;

[0049] Step 2. Put the titanium alloy substrate into the nitriding device of SK-1600°C series vacuum / atmosphere tube electric furnace, seal the device, and evacuate the nitriding device to below 0.1Pa through a vacuum pump;

[0050] Step 3. Set the heating rate of the nitriding device to 8°C / min, raise the temperature to a nitriding temperature of 950°C, and maintain a vacuum environment in the furnace;

[0051] Step 4: Feed a mixed gas of nitrogen and argon with a volume ratio of 1:2 into the nitriding device at a flow rate of 5 L / min, perform nitriding for...

Embodiment 3

[0053] A titanium alloy surface nitriding process, comprising the following steps:

[0054] Step 1. Pretreatment of the surface of the titanium alloy substrate: Cut the TA15 titanium alloy material into 15mm×80mm×10mm, grind it successively with 100 mesh, 200 mesh, and 500 mesh water abrasive paper, and then clean it with ultrasonic waves at a frequency of 45Hz for 20 minutes , and blow dry with a hair dryer in cold mode;

[0055] Step 2. Put the titanium alloy substrate into the nitriding device of SK-1600°C series vacuum / atmosphere tube electric furnace, seal the device, and evacuate the nitriding device to below 0.1Pa through a vacuum pump;

[0056] Step 3: Set the heating rate of the nitriding device to 10°C / min, raise the temperature to a nitriding temperature of 1200°C, and maintain a vacuum environment in the furnace;

[0057] Step 4: Feed a mixed gas of nitrogen and argon with a volume ratio of 1:5 into the nitriding device at a flow rate of 8 L / min, perform nitriding...

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Abstract

The invention specifically discloses a titanium alloy surface nitriding process. The method includes: putting the titanium alloy substrate whose surface has been pretreated into a vacuum nitriding device, vacuuming, and raising the temperature of the vacuum nitriding device to the nitriding temperature; the nitriding temperature is 400-1300°C; Pass into nitriding gas in the vacuum nitriding device, nitriding 0.1-15h, pass into inert gas, cool to room temperature, can form titanium nitride layer on titanium alloy surface; Described nitriding gas is that volume ratio is 1: 0‑5 nitrogen and argon. The titanium alloy surface nitriding process provided by the present invention can prepare modified titanium alloys with different properties at low temperature and high temperature according to the specific requirements of titanium alloy service, wherein the thickness of the titanium nitride layer can reach 20‑200 μm, the hardness Up to 2100HV 0.5 , the average wear loss is 1.67‑3.14g, which is obviously improved compared with the matrix hardness and wear resistance.

Description

technical field [0001] The invention relates to the technical field of titanium alloy surface modification, in particular to a titanium alloy surface nitriding process. Background technique [0002] Compared with other metal materials, titanium alloy has the advantages of low density, high specific strength, corrosion resistance, low temperature resistance and high temperature resistance. Therefore, it is widely used in military industry, nuclear industry, chemical industry and automobile industry. However, the surface hardness of titanium alloy is low, its wear resistance is poor, and it is very sensitive to adhesive wear and fretting wear, so its application range is greatly limited. How to improve the hardness and wear resistance of titanium alloy has become one of the hot spots in the field of titanium alloy research. [0003] Titanium nitride has the advantages of high melting point, high hardness, and excellent wear resistance and high temperature stability. Preparat...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C23C8/24
CPCC23C8/24
Inventor 冯志浩孙信阳秦雪明孟致安胡希磊韩鹏彪
Owner HEBEI UNIVERSITY OF SCIENCE AND TECHNOLOGY