The invention provides an ultra-wear-resistant alumina ceramic ball. The ultra-wear-resistant alumina ceramic ball comprises the following chemical components: 90-95% by weight of Al2O3, 5-8% by weight of SiO2, 0.3-0.5% by weight of CaO, 0.5-0.9% by weight of MgO, 1-2% by weight of ZrO and 0.1-0.5% by weight of La2O3/Y2O3, wherein the equivalent wear loss is less than 72 per mil. A provided preparation method comprises the following process steps of: adopting alumina powder and other mineral raw materials for burdening, refining mud, drying, calcining, synthesizing, ball-milling, granulating, forming and firing to obtain a product. According to the invention, the wear resistance of the product can achieve the standard of the alumina ceramic ball; and furthermore, the ultra-wear-resistant alumina ceramic ball has the advantages of lower cost of the raw materials, better grinding performance and high performance-price ratio of the product, is more suitable for being applied in production, and can reduce the production cost of an enterprise and improve the production efficiency of the enterprise.