The invention discloses a preparation method of a tin carbon composite material for negative electrode of lithium ion batteries. The preparation method comprises the following steps: the method that a medium is adopted to block discharge plasma for assisting high-energy ball milling is adopted to ball mill the mixed powder of tin and graphite for 2.5h to 20h, thus obtaining the tin carbon composite powder; and then the tin carbon composite powder is made into an lithium ion electrode plate which is then assembled into batteries, wherein the mass of a graphite raw material accounts 30 to 70 percent of the total mass of the mixed powder; during the ball milling process, the mass ratio of the grinding balls to the ball powder of the tin and graphite mixed powder is 30:1 to 70:1; and the medium adopts an inert gas which is not reacted with Sn, such as helium, neon, argon, krypton, xenon or nitrogen. The preparation method can effectively improve ball-milling efficiency, keep lamellar integrity of graphite, improve first reversible capacity and cycle life, and refine Sn particles to enable the relative volume change of a working electrode in the charging and discharging process to be reduced and improve the cycle performance of the lithium batteries.