Low-temperature automobile expansion adhesive and preparation method thereof

An automotive and low-temperature technology, which is applied in the field of low-temperature automotive expansion rubber and its preparation, can solve the problems of low foaming ratio, poor storage stability, short storage period and the like of the expansion rubber, and achieves good high-temperature baking stability and storage stability. , The effect of stable product quality

Active Publication Date: 2020-01-14
浙江杰上杰新材料股份有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] (1) The expansion ratio of traditional expansion rubber is low, the product density is high, and it cannot fill large cavities;
[0005] (2) The bonding strength between the expansion rubber and the aluminum sheet and the ABS skeleton is too low, and the problem of sagging and peeling is prone to occur under the process conditions;
[0006] (3) The high-temperature baking stability is poor, and the expansion rubber after foaming is prone to c

Method used

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  • Low-temperature automobile expansion adhesive and preparation method thereof
  • Low-temperature automobile expansion adhesive and preparation method thereof
  • Low-temperature automobile expansion adhesive and preparation method thereof

Examples

Experimental program
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Effect test

Embodiment 1

[0065] A kind of low-temperature automobile expansion rubber, described low-temperature automobile expansion rubber is made of each raw material comprising following weight parts:

[0066] 100 parts of high molecular polymer, 3-5 parts of peroxide vulcanizing agent, 0.5-3 parts of vulcanization aid (also known as auxiliary cross-linking agent), 5-15 parts of foaming agent, 0.5-8 parts of foaming activator, 1-10 parts of filler, 2-15 parts of tackifier, 0.5-3 parts of lubricant, 0-2 parts of antioxidant, 0-10 parts of flame retardant.

[0067] Wherein, the high molecular polymer is ethylene-vinyl acetate copolymer (EVA resin) with VA content of 26-28, ethylene-vinyl acetate copolymer (EVA resin) with VA content of 40, low-density polyethylene (LDPE), ethylene Methyl methacrylate copolymer (EMA), ethylene-ethyl acrylate copolymer (EEA), ethylene-butyl acrylate copolymer (EBA), butadiene rubber (BR), ethylene-propylene-diene rubber (EPDM) any one or a mixture of several.

[006...

Embodiment 2 to 7

[0094] All adopt the preparation method of following a kind of described low-temperature automobile expansion glue, comprise the following steps:

[0095] (1) Add high molecular polymer in internal mixer and carry out pre-mixing;

[0096] (2) Add lubricant, foaming agent, antioxidant, filler, tackifier, flame retardant to the internal mixer in turn, and enter the next step after the materials are mixed into blocks;

[0097] (3) Continue mixing after adding vulcanizing agent, vulcanizing aid, and foaming activator; turn over the material during mixing and clean the material at the feeding port for more than 3 times;

[0098] (4) After mixing evenly, under the condition that the temperature of the material does not exceed 90°C, unload the material and enter the extruder for granulation;

[0099] (5) Packaging granular expansion rubber, which is the low-temperature automobile expansion rubber.

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PUM

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Abstract

The invention discloses a low-temperature automobile expansion adhesive. The low-temperature automobile expansion adhesive is made of the following raw materials in parts by weight: 100 parts of a polymer, 3-5 parts of a peroxide vulcanization agent, 0.5-3 parts of a vulcanization auxiliary agent, 5-15 parts of a foaming agent, 0.5-8 parts of a foaming activator, 1-10 parts of a filler, 2-15 partsof a tackifier, 0.5-3 parts of a lubricant, 0-2 parts of an antioxidant, and 0-10 parts of a flame retardant. According to the low-temperature automobile expansion adhesive, the raw material composition is carefully chosen, the content of each raw material is optimized, and the prepared low-temperature automobile expansion adhesive has high foaming ratio and small product density, and can fill large cavities. The expansion adhesive has high bonding strength with an ABS framework member. The expansion adhesive has good high-temperature baking stability. The expansion adhesive after foaming isnot easy to collapse and shrink. The low-temperature foaming performance and high-temperature foaming ratio are well balanced. The storage stability is good, the product quality is stable, and a storage period is relatively long.

Description

technical field [0001] The invention relates to the field of expansion rubber, in particular to a low-temperature automobile expansion rubber and a preparation method thereof. Background technique [0002] With the rapid development of the national economy, people's living standards have been greatly improved, and various high-end passenger cars have become family necessities. There is a large gap in engine technology between self-owned brands and foreign-funded brand cars, resulting in self-owned brands in the mid-to-high-end market. Frustrated one after another. Increasing investment in research and development, improving the ride comfort of automobiles, and controlling production costs have become top priorities. Among the many parameters of the car, NVH (Noise, Vibration, Harshness) has received great attention, because the bypass cavity of the car body will generate high-speed airflow when driving at high speed, resulting in strong noise and vibration. [0003] The cu...

Claims

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Application Information

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IPC IPC(8): C09J123/08C09J123/06C09J11/04C09J11/06C09J11/08
CPCC08K2003/2296C08K2003/265C08L2201/02C08L2203/14C08L2205/035C09J11/04C09J11/06C09J11/08C09J123/0853C08L23/06C08L23/0869C08L57/02C08K13/02C08K5/09C08K3/26C08K3/2279C08K5/1345C08K5/14C08K3/22
Inventor 罗李华
Owner 浙江杰上杰新材料股份有限公司
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