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A kind of nanometer zero-valent metal porous functional material prepared based on meteorite, its preparation method and application

A nano-zero-valent, metal porous technology, applied in chemical instruments and methods, biological water/sewage treatment, sustainable biological treatment, etc., can solve the problems of easy clogging, low adsorption capacity, poor removal of pollutants, etc. Strong capacity, low production cost, and the effect of recycling waste

Active Publication Date: 2022-01-28
HEFEI UNIV
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] The problem to be solved by the invention is that existing artificial wetland fillers and sponge city substrates have defects such as easy clogging, low adsorption capacity, and poor pollutant removal effect.

Method used

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  • A kind of nanometer zero-valent metal porous functional material prepared based on meteorite, its preparation method and application
  • A kind of nanometer zero-valent metal porous functional material prepared based on meteorite, its preparation method and application
  • A kind of nanometer zero-valent metal porous functional material prepared based on meteorite, its preparation method and application

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Experimental program
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preparation example Construction

[0050] During the preparation of the composite porous material, the aluminum powder can produce hydrogen in the alkaline solution, and generate a porous structured material, and the active group provides an alkalinity in the active group, and provides an alkaline environment for the aluminum powder production. On the other hand, its main component calcium oxide and water reactively releases a large amount of heat, so that the temperature of the embryo is increased. In order to prevent heat produced by the calcium oxide and the water reaction to oxidize the nano-zero-priced metal composite material obtained in step S1, in step S3 of the present invention, the composite porous material is cooled, and the surface of the prepared composite porous material is evenly applied. The zero-priced metal composite material is prepared, and the nano-zero-covalent metal porous functional material is obtained. The nano-zero-priced metal composites fall into the open pores in the open pores of the...

Embodiment 1

[0061] The preparation method of the nano-zero-priced metal porous functional material in this embodiment includes the following steps:

[0062] The meteorite was broken to 0.0374 mm or less, and the dried meteorite powder was calcined under a hydrogen atmosphere with alcohol.

[0063] At the same time, according to the mass percentage zeolite: 55-60%, ordinary silicate cement: 25-35%, raw lime: 5-10%, aluminum powder: 1-1.5%, gypsum: 2-4%, mix, cast, hair Bubble, and stirred at a high temperature at 150 ° C for 6 hours to prepare a composite porous material;

[0064] Finally, sprinkle the nano-zero-covalent metal composite material on the surface of the composite porous material, wherein the weight ratio of the nano-zero-coated metal composite and the composite porous material is 2:98, watering for 10 days, and obtains nano-zero-priced metal composite porous. Functional Materials.

[0065] The present embodiment performs performance test of the obtained nano-zero-covalent metal c...

Embodiment 2

[0069] The preparation method of the nano-zero-priced metal porous functional material in this embodiment includes the following steps:

[0070] The meteorite was broken to 0.0374 mm or less. After mixing alcohol was mixed, the dried meteorite powder was calcined under a hydrogen atmosphere, the calcination temperature was 900 ° C, the time was 2 h, and the nano-zero-covalent metal composite material was produced.

[0071] At the same time, according to the quality percentage zeolite: 60-63%, ordinary silicate cement: 30-35%, raw lime: 6-9%, aluminum powder: 1-1.7%, gypsum: 3-4%, mix, cast, hair Bubble, and evaporate 8 hours at high temperature at 180 ° C to prepare a composite porous material;

[0072] Finally, the nano-zero-covalent metal composite material is sprinkled on the surface of the composite porous material, wherein the weight of the nano-zero-covalent metal composite and the composite porous material is 5: 100, watering for 15 days, and obtains nano-zero-priced metal ...

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Abstract

The invention provides a nanometer zero-valent metal porous functional material prepared based on meteorite, its preparation method and application, and belongs to the technical field of composite materials. The method for preparing nanometer zero-valent metal porous functional material based on meteorite comprises the following steps: step S1, using meteorite powder as raw material to prepare nanometer zero-valent metal composite material through reduction and calcination; and zeolite, cement, quicklime, aluminum powder, gypsum and Surfactant mixed ingredients, pouring, foaming, cutting, autoclaving and curing to obtain a composite porous material; Step S2, evenly spreading the nano-zero-valent metal composite material on the surface of the composite porous material, after natural curing, The nanometer zero-valent metal porous functional material is prepared. The nano-zero-valent metal composite porous functional material of the present invention has multi-level pores, high porosity and large specific surface area, which provides space for microorganisms to enter the material to attach and grow, and is used as a constructed wetland matrix and a sponge city matrix to treat wastewater and pollutants High removal rate.

Description

Technical field [0001] The present invention relates to the technical field of composite materials, and in particular, there is a meteorite-based nano-zero-priced metal porous functional material, and the preparation method thereof is used. Background technique [0002] With the acceleration of urbanization, the problems such as urban flood, water resource shortage and weighing of runoff pollution are highlighted. According to the National EPA information, the rainwater runoff has been listed as a third largest contamination source that causes water pollution. Since the release of the "Sponge City Construction Technology Guide" The essence of sponge city construction is through the combination of manual facilities and natural pathways, realizing rainwater naturally accumulating, natural penetration and natural purification, and can "release" rain water during water, form a good natural circulation, promote rainwater resources and ecosystems Environmental protection. The occurrenc...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C02F3/10C02F3/32C02F3/34C02F3/28C02F101/10C02F101/16
CPCC02F3/107C02F1/288C02F1/42C02F3/2806C02F3/34C02F3/347C02F3/325C02F3/327C02F1/58C02F2101/16C02F2001/425C02F2101/105Y02W10/10
Inventor 鲍腾卫新来金杰吴克王晓飞
Owner HEFEI UNIV