A kind of inorganic nano antibacterial hard PVC and preparation method thereof

A kind of inorganic nano and nano technology, applied in the field of antibacterial plastics, can solve the problems of small effective specific surface area, poor antibacterial performance, easy migration, etc., and achieve the guarantee of bactericidal and antibacterial ability, significant bactericidal and antibacterial effect, and easy operation of the preparation process Effect

Active Publication Date: 2021-09-21
SOUTH CHINA UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Although the patent uses organic antibacterial agents and inorganic antibacterial agents in combination to improve the antibacterial effect of materials, most organic antibacterial agents have toxicity, poor safety, and easy migration (resulting in short antibacterial life). Decomposition fails during processing, and the decomposed substances are even toxic, resulting in safety problems and short antibacterial life of the PVC antibacterial plastic
[0006] Chinese invention patent application CN106009396A discloses an antibacterial plastic. Polyvinyl chloride and nano-zinc oxide are directly blended to obtain a composite material. The composite material obtained by this method will release nano-zinc oxide into the environment, resulting in a short antibacterial life of the composite material. and environmental pollution
Chinese invention patent application CN103951910B discloses a polyvinyl chloride composite plastic and its preparation method. This material has poor antibacterial properties and also has the problem of migration of nano-zinc oxide.
In addition, the nano-zinc oxide in the polyvinyl chloride / nano-zinc oxide antibacterial material disclosed in the above patents is easy to agglomerate, and the effective specific surface area is small, resulting in a low sterilization rate of the material, which limits its application range

Method used

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  • A kind of inorganic nano antibacterial hard PVC and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0032] In parts by mass, the raw material formula of the inorganic nano antibacterial hard PVC of the present embodiment is as follows:

[0033] Rigid polyvinyl chloride (brand: UE508, Dongguan Feihua Plastic Co., Ltd.) 55 parts;

[0034] Inorganic non-metallic nanofillers (nano-SiO 2 , Brand: VK-SP30, Xuancheng Jingrui New Material Co., Ltd., particle size: 30nm) 15 parts;

[0035] Heat stabilizer (rare earth stabilizer, brand: 85795, Jinan Baijin Chemical Technology Co., Ltd.) 5 parts;

[0036] Coupling agent (silane coupling agent, brand: GF95, Shenzhen Huicheng Plastic Auxiliary Chemical Co., Ltd.) 13 parts;

[0037] Antioxidant (brand: 1076, Dongguan Kangjin New Material Technology Co., Ltd.) 7 parts;

[0038] UV absorber (brand: RQT-X-1, Henan Ruiqite Chemical Co., Ltd.) 5 parts;

[0039] During preparation, hard polyvinyl chloride, nano-SiO 2 Fillers, heat stabilizers, silane coupling agents, antioxidants, and ultraviolet absorbers are weighed according to the mass...

Embodiment 2

[0041] The difference from Example 1 is that in the raw material formula of this example, nano-ZnO is used as the inorganic non-metallic nano-filler, and other types of coupling agents and different proportions are selected.

[0042] In parts by mass, the raw material formula of inorganic nano antibacterial hard PVC is as follows:

[0043] Rigid polyvinyl chloride (brand: UE508, Dongguan Feihua Plastic Co., Ltd.) 60 parts;

[0044] Inorganic non-metallic nano-filler (nano-ZnO filler, Xuancheng Jingrui New Material Co., Ltd., particle size: 50nm) 10 parts;

[0045] Heat stabilizer (rare earth stabilizer, brand: 85795, Jinan Baijin Chemical Technology Co., Ltd.) 6 parts;

[0046] Coupling agent (aluminate coupling agent, brand: DL-411, Fuzhou Yuanke New Fine Materials Co., Ltd.) 10 parts;

[0047] Antioxidant (brand: 1076, Dongguan Kangjin New Material Technology Co., Ltd.) 8 parts;

[0048] UV absorber (brand: RQT-X-1, Henan Ruiqite Chemical Co., Ltd.) 6 parts;

[0049] Dur...

Embodiment 3

[0051] The difference with Example 1 is: adopt nano-TiO in the raw material formula of this example 2 As an inorganic non-metallic nano-filler, other types of coupling agents and different proportions are selected.

[0052] In parts by mass, the raw material formula of inorganic nano antibacterial hard PVC is as follows:

[0053] Rigid polyvinyl chloride (brand: UE508, Dongguan Feihua Plastic Co., Ltd.) 65 parts;

[0054] Inorganic non-metallic nanofillers (nano TiO 2 Filler, grade: 5484WJ, Nanjing Hongde Nano Material Co., Ltd., particle size: 20-50nm) 5 parts;

[0055] Heat stabilizer (rare earth stabilizer, brand: 85795, Jinan Baijin Chemical Technology Co., Ltd.) 8 parts;

[0056] Coupling agent (titanate coupling agent, brand: 201, Dongguan Shanyi Plastic Chemical Co., Ltd.) 5 parts;

[0057] Antioxidant (brand: 1076, Dongguan Kangjin New Material Technology Co., Ltd.) 9 parts;

[0058] 8 parts of ultraviolet absorber (brand: RQT-X-1, Henan Ruiqite Chemical Co., Ltd....

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Abstract

The invention belongs to the field of antibacterial plastics, and discloses an inorganic nano antibacterial hard PVC and a preparation method thereof. Add inorganic non-metallic nano fillers into water to make slurry, then add coupling agent, heat and stir for reaction, filter the reacted slurry, dry, pulverize, sieve, and then use high-energy ball mill to obtain inorganic nano Antibacterial agent: mix hard polyvinyl chloride, inorganic nano antibacterial agent and additives, and extrude to obtain inorganic nano antibacterial hard PVC. The present invention adopts inorganic non-metallic nanometer filler to make antibacterial agent through special treatment process, so that its antibacterial and antibacterial ability can be improved and its nanometer scale can be kept evenly dispersed in PVC. It is easy to use, has long-term effectiveness, and improves the impact resistance of rigid PVC.

Description

technical field [0001] The invention belongs to the field of antibacterial plastics, and in particular relates to an inorganic nano antibacterial hard PVC and a preparation method thereof. Background technique [0002] At present, polyvinyl chloride (PVC) is one of the five general-purpose plastics, and its annual output is second only to polyethylene. It is widely used, easy to process and produce, easy to market, and has excellent physical properties, such as low density, high strength, and oil resistance. Good performance, chemical resistance, high transparency, excellent flame retardancy, high insulation, and low price, it is widely used in various industries and fields, and has become the second largest general-purpose plastic. And from the perspective of my country's plastic production situation, the output of rigid polyvinyl chloride accounts for about 60% of its total output. However, because polyvinyl chloride does not have antibacterial properties, its surface wil...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L27/06C08K13/06C08K9/06C08K9/04C08K9/00C08K3/36C08K3/22
CPCC08K3/22C08K3/36C08K9/00C08K9/04C08K9/06C08K13/06C08K2003/2241C08K2003/2296C08K2201/003C08K2201/011C08L27/06
Inventor 牟文杰黄佳美赵良知
Owner SOUTH CHINA UNIV OF TECH
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