A kind of high-voltage flexible polyolefin wire material for new energy vehicles and preparation method thereof
A soft polyolefin and new energy vehicle technology, applied in the field of electric wire materials, can solve the problems of unresolved higher temperature resistance, poor mechanical and physical properties, high temperature aging instability, etc., and achieve low preparation cost, easy process, thermal Good stability and anti-aging effect
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[0030] The polyolefin wire material is prepared by irradiation crosslinking; the olefin copolymer is 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1, 3-adamantanediol monoacrylate and acrylonitrile are prepared by free radical copolymerization; the preparation method of the olefin copolymer comprises the following steps: 1,1,1-trifluoro-2-(trifluoromethyl )-4-pentan-2-ol, 1,3-adamantane diol monoacrylate, acrylonitrile, and initiator are added to the high boiling point solvent, and the reaction is stirred at 70-80°C under nitrogen or inert gas atmosphere 3- After 5 hours, it was precipitated in water, and dried to constant weight in a vacuum oven at 80-90°C to obtain an olefin copolymer.
[0031] Further, the 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1,3-adamantanediol monoacrylate, acrylonitrile, initiator, high The mass ratio of the boiling point solvent is 1:1:(2-3):(0.03-0.05):(15-24).
[0032] Further, the initiator is at least one of azobisisobutyronitril...
Embodiment 1
[0040] Embodiment 1 provides a kind of soft polyolefin wire stock for high-voltage lines of new energy vehicles, which comprises the following components by weight:
[0041]
[0042] The polyolefin wire material is prepared by irradiation cross-linking; the olefin copolymer is 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 3-adamantanediol monoacrylate and acrylonitrile are prepared by radical copolymerization; the preparation method of the olefin copolymer includes the following steps: 1,1,1-trifluoro-2-(trifluoromethyl) )-4-pentan-2-ol, 1,3-adamantanediol monoacrylate, acrylonitrile, and an initiator were added to a high-boiling solvent, stirred for 3 hours at 70°C in a nitrogen atmosphere, and then precipitated in water. out, and dried to constant weight in a vacuum drying oven at 80°C to obtain an olefin copolymer; the 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1,1, The mass ratio of 3-adamantanediol monoac...
Embodiment 2
[0049] Embodiment 2 provides a kind of soft polyolefin wire stock for high-voltage lines of new energy vehicles, and its formula and preparation method are basically the same as those of embodiment 1, and the difference is that it includes the following components by weight:
[0050]
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