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A kind of high-voltage flexible polyolefin wire material for new energy vehicles and preparation method thereof

A soft polyolefin and new energy vehicle technology, applied in the field of electric wire materials, can solve the problems of unresolved higher temperature resistance, poor mechanical and physical properties, high temperature aging instability, etc., and achieve low preparation cost, easy process, thermal Good stability and anti-aging effect

Active Publication Date: 2021-08-31
苏州铂玛新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The current wire and cable materials for ordinary fuel vehicles cannot meet the requirements of wire and cable materials for new energy vehicles. At present, elastomeric PVC and elastomeric polyethylene cable materials are mainly used to make new energy vehicle wires and cables on the market, but elastomeric rubber and Elastomer polyethylene materials have the following disadvantages: First, if the two materials achieve good flexibility, but poor mechanical and physical properties, if the mechanical and physical properties are good, their flexibility is average; second, high temperature aging is unstable, affecting service life
[0006] Chinese patent CN106380869A discloses a 125-degree radiation cross-linking elastomeric cable material for high-voltage lines of new energy vehicles and its preparation method. The problem of temperature resistance of TPE materials is solved by radiation cross-linking, but the temperature resistance level is only 125 ° C. For There is no solution for a higher temperature resistance level, and the investment in irradiation equipment is large, and the damage to the material is relatively large during the irradiation crosslinking process, and residual components are easily generated inside the material

Method used

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  • A kind of high-voltage flexible polyolefin wire material for new energy vehicles and preparation method thereof
  • A kind of high-voltage flexible polyolefin wire material for new energy vehicles and preparation method thereof
  • A kind of high-voltage flexible polyolefin wire material for new energy vehicles and preparation method thereof

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Experimental program
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preparation example Construction

[0030] The polyolefin wire material is prepared by irradiation crosslinking; the olefin copolymer is 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1, 3-adamantanediol monoacrylate and acrylonitrile are prepared by free radical copolymerization; the preparation method of the olefin copolymer comprises the following steps: 1,1,1-trifluoro-2-(trifluoromethyl )-4-pentan-2-ol, 1,3-adamantane diol monoacrylate, acrylonitrile, and initiator are added to the high boiling point solvent, and the reaction is stirred at 70-80°C under nitrogen or inert gas atmosphere 3- After 5 hours, it was precipitated in water, and dried to constant weight in a vacuum oven at 80-90°C to obtain an olefin copolymer.

[0031] Further, the 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1,3-adamantanediol monoacrylate, acrylonitrile, initiator, high The mass ratio of the boiling point solvent is 1:1:(2-3):(0.03-0.05):(15-24).

[0032] Further, the initiator is at least one of azobisisobutyronitril...

Embodiment 1

[0040] Embodiment 1 provides a kind of soft polyolefin wire stock for high-voltage lines of new energy vehicles, which comprises the following components by weight:

[0041]

[0042] The polyolefin wire material is prepared by irradiation cross-linking; the olefin copolymer is 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 3-adamantanediol monoacrylate and acrylonitrile are prepared by radical copolymerization; the preparation method of the olefin copolymer includes the following steps: 1,1,1-trifluoro-2-(trifluoromethyl) )-4-pentan-2-ol, 1,3-adamantanediol monoacrylate, acrylonitrile, and an initiator were added to a high-boiling solvent, stirred for 3 hours at 70°C in a nitrogen atmosphere, and then precipitated in water. out, and dried to constant weight in a vacuum drying oven at 80°C to obtain an olefin copolymer; the 1,1,1-trifluoro-2-(trifluoromethyl)-4-pentan-2-ol, 1,1, The mass ratio of 3-adamantanediol monoac...

Embodiment 2

[0049] Embodiment 2 provides a kind of soft polyolefin wire stock for high-voltage lines of new energy vehicles, and its formula and preparation method are basically the same as those of embodiment 1, and the difference is that it includes the following components by weight:

[0050]

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Abstract

The invention discloses a soft polyolefin wire material for high-voltage wires of new energy vehicles, which is characterized in that it comprises the following components in parts by weight: 15-25 parts of elastomer rubber; 15-25 parts of elastomer polyethylene; olefin 30-50 parts of copolymer; 15-25 parts of toughening agent; 7-12 parts of inorganic flame retardant; 5-10 parts of auxiliary agent; 5-10 parts of antioxidant; 5-10 parts of crosslinking agent; The olefin wire material is prepared by irradiation crosslinking; the olefin copolymer is 1,1,1-trifluoro-2-(trifluoromethyl)-4-penta-2-alcohol, 1,3-adamant Alkanediol monoacrylate and acrylonitrile are prepared by free radical copolymerization. The high-voltage flexible polyolefin wire material for new energy vehicles disclosed by the present invention retains the flexibility of these two materials, improves the mechanical properties, and adds some special fillers to make the olefin cable material meet the use characteristics of high-voltage wires. The preparation method above adopts The radiation cross-linking method improves the thermal stability, anti-aging performance and service life of the olefin wire material.

Description

technical field [0001] The invention relates to the technical field of wire materials, in particular to a high-voltage soft polyolefin wire material for new energy vehicles and a preparation method thereof. Background technique [0002] With the deepening of the global energy crisis, the depletion of oil resources and the increasing harm of air pollution and global temperature rise, governments and automobile companies generally recognize that energy saving and emission reduction are the main direction of future automobile technology development. It is in this situation that new energy vehicles emerge as the times require. Wires for new energy vehicles are crucial to the normal operation and service life of new energy vehicles. [0003] Since the kinetic energy system of new energy vehicles is different from that of ordinary fuel vehicles, the differences between the wires used in new energy vehicles and ordinary fuel vehicles are: the high-voltage cables of electric vehicl...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L33/20C08L23/06C08L75/04C08L33/04C08L83/08C08L13/00C08L23/34C08L9/02C08K13/06C08K9/06C08K3/22C08F220/44C08F220/20H01B3/44
CPCC08F220/44C08J3/246C08J3/28C08K2003/026C08K2003/2224C08L33/20C08L2201/02C08L2201/08C08L2203/202C08L2205/035C08L2312/06H01B3/447C08L23/06C08L75/04C08L33/04C08K13/06C08K9/06C08K3/2279C08F220/20C08L83/08C08L13/00C08K3/22C08L23/34C08L9/02C08K3/02
Inventor 王登辉詹芊芊
Owner 苏州铂玛新材料有限公司