Antimony-based tailing adsorbing material, preparation method and applications thereof

An adsorption material, antimony tailings technology, applied in chemical instruments and methods, adsorbed water/sewage treatment, other chemical processes, etc., can solve the problems of complex production process, cumbersome preparation process, secondary pollution, etc., and improve the pore structure. , the preparation method is simple, the effect of strong adsorption performance

Active Publication Date: 2020-04-17
KUNMING UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the production process of this material is relatively complicated, and may cause secondary pollution
[0005] At present, there are many kinds of adsorption materials, the most common ones are activated carbon, zeolite, carbon molecular sieve, resin, etc., which are involved in various fields, but the preparation process is relatively cumbersome.

Method used

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  • Antimony-based tailing adsorbing material, preparation method and applications thereof
  • Antimony-based tailing adsorbing material, preparation method and applications thereof
  • Antimony-based tailing adsorbing material, preparation method and applications thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0028] Example 1: Antimony tailings adsorption materials prepared with different ratios of antimony tailings and viscous agents (commercially purchased ultrafine kaolin) are effective against heavy metals Pt, As, Mn and high-concentration organic emulsified wastewater (serum protein simulates high-concentration organic emulsified wastewater) Adsorption detection of

[0029] 1. The preparation process of antimony tailings adsorption material is as follows:

[0030] (1) Wash the antimony tailings with water until the pH of the washing solution is 6.5, dry and pulverize them, and then take the following percentages of powdered antimony tailings: 30%, 40%, 50%, 60%, 70%, 80%, 90% % and kaolin 70%, 60%, 50%, 40%, 30%, 20%, 10%, mix evenly;

[0031] (2) Add deionized water, stir until viscous, use a particle forming mold to form the viscous mixture into balls, and make 1 part for each ratio;

[0032] (3) Each portion is fired at 1000°C for 12 hours;

[0033] (4) After taking out ...

Embodiment 2

[0038] Embodiment 2: 90% of antimony tailings and 10% of ultra-fine kaolin; the antimony tailings adsorption material fired for 12h under different firing temperatures is effective for metal Pt, As, Mn and high-concentration organic emulsified wastewater (serum protein simulates high Concentration organic emulsified wastewater) adsorption performance test, the content is as follows

[0039] (1) Wash the antimony tailings with water until the pH of the washing solution is 7, dry and pulverize, take the antimony tailings powder and superfine kaolin and mix them thoroughly;

[0040] (2) Add deionized water, stir until viscous, use a particle forming mold to form the viscous mixture into a ball, and make a total of 9 parts;

[0041](3) The firing temperatures are 400°C, 500°C, 600°C, 700°C, 800°C, 900°C, 1000°C, 1100°C, 1200°C, and calcined for 12 hours;

[0042] (4) Take it out and cool it, wash it with deionized water for 3-5 times, dry it, and then fire it into antimony tailin...

Embodiment 3

[0048] Example 3: 90% of antimony tailings and 10% of ultra-fine kaolin; the antimony tailings adsorption material fired for different times at a firing temperature of 1000°C is effective for metal Pt, As, Mn and high-concentration organic emulsified wastewater (serum Protein simulates the adsorption performance of high-concentration organic emulsified wastewater), the content is as follows:

[0049] (1) Wash the antimony tailings with water until the pH of the washing solution is 7, dry and pulverize, take the antimony tailings powder and superfine kaolin and mix them thoroughly;

[0050] (2) Add deionized water, stir until viscous, use a particle forming mold to form the viscous mixture into a ball, and make a total of 9 parts;

[0051] (3) Fire at 1000°C for 8h, 10h, 12h, 14h, 16h, 18h, 20h, 22h, 24h;

[0052] (4) Take it out and cool it, wash it with deionized water for 5 times, dry it, and then fire it into antimony tailings adsorption materials with different firing tim...

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Abstract

The invention discloses an adsorbing material based on antimony tailings, a preparation method and applications thereof, wherein the adsorbing material is prepared from the following components in percentage by mass: 50-90% of antimony tailings and 50-10% of an adhesive. According to the present invention, the adsorption performance detection results show that the material has high adsorption performance on high-concentration organic emulsification wastewater and heavy metal-containing wastewater, has characteristics of stable chemical property, developed pores, high mechanical strength, high-temperature resistance and the like, and has broad prospects in the fields of waste resource utilization and adsorption materials.

Description

technical field [0001] The invention belongs to the field of environmental functional materials, and in particular relates to a preparation method and application of an antimony tailings-based adsorption material. Background technique [0002] my country's antimony reserves and production are the first in the world. In recent years, my country's antimony production accounts for about 90% of the world's total. Due to the large-scale development of antimony mines, a large number of antimony pollution accidents and relatively serious antimony pollution problems have been caused, especially In Guangxi, Hunan, Yunnan, Guizhou and other southern provinces where antimony mines are relatively concentrated, there is a large amount of antimony tailings accumulation, so the whereabouts of antimony tailings has become one of the hottest topics in tailings treatment today. [0003] In 2016, CN201610031832.9 disclosed a kind of antimony tailings slag aerated concrete block and its preparat...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B01J20/10B01J20/30C02F1/28C02F101/20C02F101/30
CPCB01J20/103B01J20/08B01J20/06C02F1/281C02F2101/20C02F2101/30C02F2101/206
Inventor 瞿广飞吴丰辉李江松李军燕
Owner KUNMING UNIV OF SCI & TECH
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