A superlubricious catheter material
A super-lubricating, catheter-based technology, applied in the field of medical materials, can solve problems such as easy blockage of blood vessel thrombosis, cardiovascular and cerebrovascular diseases, foreign body sensation in patients, etc., achieve excellent antibacterial performance and self-healing, high puncture success rate, and reduce foreign body sensation Effect
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[0080] In a preferred embodiment, the preparation method of the polyethylene glycol modified chitosan comprises the following steps:
[0081] Step a: Stir and mix 5-6 parts of chitosan, 1-2 parts of acetic acid, and 30-40 parts of distilled water in parts by weight to obtain a mixed solution;
[0082] Step b: In parts by weight, add 2 to 3 parts of polyethylene glycol into 30 to 40 parts of tetrahydrofuran under stirring conditions, and after stirring and mixing evenly, add 0.5 to 1 part of terephthalic acid and 0.1 to 0.3 parts of paraphthalic acid After dimethylaminopyridine, continue to add 1 to 2 parts of methyltetraylbicyclohexylamine, mix evenly, filter, and dry the filtrate to obtain a powder material;
[0083] Step c: adding 20-30 parts of the powder material obtained in step b to 9-16 parts of the mixed solution obtained in step a in parts by weight to obtain polyethylene glycol-modified chitosan.
[0084] In a more preferred embodiment, the preparation method of des...
Embodiment 1
[0109] Embodiment 1 of the present invention provides a super-lubricating catheter material, including the following raw materials in parts by weight: 22 parts of isocyanate, 45 parts of polyol, 18 parts of cross-linking agent, 10 parts of chain extender, and 12 parts of antibacterial agent.
[0110] Described isocyanate is the mixture of trimethyl hexamethylene diisocyanate and 1,4-cyclohexane dimethyl diisocyanate; Described trimethyl hexamethylene diisocyanate and 1,4-cyclohexane dimethyl diisocyanate The molar ratio of base diisocyanate is 3:7. The polyol is a mixture of polyethylene glycol and polyethylene adipate; the weight ratio of the polyethylene glycol and polyethylene adipate is 2:1; the Polyethylene glycol is the polyethylene glycol (PEG-2000) that relative molecular weight is 2000; Described polyethylene adipate is the polyethylene adipate that relative molecular weight is 2000 (PDA-2000). The cross-linking agent is 1,4-butanediol; the chain extender is hydroqu...
Embodiment 2
[0121] Embodiment 2 of the present invention provides a super-lubricating catheter material, including the following raw materials in parts by weight: 15 parts of isocyanate, 40 parts of polyol, 14 parts of cross-linking agent, 5 parts of chain extender, and 8 parts of antibacterial agent.
[0122] Described isocyanate is the mixture of trimethyl hexamethylene diisocyanate and 1,4-cyclohexane dimethyl diisocyanate; Described trimethyl hexamethylene diisocyanate and 1,4-cyclohexane dimethyl diisocyanate The molar ratio of base diisocyanate is 3:7. The polyol is a mixture of polyethylene glycol and polyethylene adipate; the weight ratio of the polyethylene glycol and polyethylene adipate is 2:1; the Polyethylene glycol is the polyethylene glycol (PEG-2000) that relative molecular weight is 2000; Described polyethylene adipate is the polyethylene adipate that relative molecular weight is 2000 (PDA-2000). The cross-linking agent is 1,4-butanediol; the chain extender is hydroquin...
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Abstract
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