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Vitrification method for industrial waste salt

A technology of industrial waste salt and vitrification, applied in chemical instruments and methods, solid waste removal, transportation and packaging, etc., can solve the problem of inability to effectively deal with industrial waste salt and coal gangue, and avoid toxic dioxin gas. The effect of producing, stable structure and high safety

Active Publication Date: 2020-05-01
GO HIGHER ENVIRONMENT GRP CO LTD +2
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0006] Therefore, the technical problem to be solved by the present invention is to overcome the defects in the prior art that cannot effectively process industrial waste salt and coal gangue, thereby providing a vitrification method for industrial waste salt

Method used

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  • Vitrification method for industrial waste salt
  • Vitrification method for industrial waste salt

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Weigh industrial waste salt, coal gangue (SiO 2 The content is 50%) and additives (the mixture of calcium carbonate and sodium oxide with a mass ratio of 4:1), mixed evenly by a mixer, and the particle size of industrial waste salt and coal gangue is 1-3mm; The cracking furnace is cracked for 1.5 hours, and the temperature of the cracking furnace is controlled to 550 ° C; the mixed material after cracking is sent to the melting furnace for melting for 1 hour, and the temperature of the melting furnace is controlled to 1200 ° C; The gas produced by the final melting furnace is disposed of by the tail gas treatment system and then discharged up to the standard. The molten slag liquid is discharged from the furnace bottom, and the glass body is obtained after natural cooling.

Embodiment 2

[0032] Weigh industrial waste salt and coal gangue (SiO 2 content of 60%), mixed evenly by the mixer, and the particle size of industrial waste salt and coal gangue is 1-3mm; the mixture is sent to the cracking furnace for cracking for 1 hour, and the temperature of the cracking furnace is controlled to 600 ℃; the cracked mixture is sent to After melting in the melting furnace for 1.5 hours, the temperature of the melting furnace is controlled to 1150 °C; the waste gas generated by the cracking furnace is discharged into the melting furnace for further treatment to avoid the generation of toxic gases such as dioxins. Finally, the gas generated by the melting furnace is disposed of by the exhaust gas treatment system and discharged up to the standard. The molten slag liquid is discharged from the furnace bottom, and the glass body is obtained after natural cooling.

Embodiment 3

[0034] Weigh industrial waste salt, coal gangue (SiO 2 content is 70%) and sodium sulfate, and mix them evenly through a mixer, and the particle size of industrial waste salt and coal gangue is 1-3mm; the mixture is sent to a cracking furnace for cracking for 3 hours, and the temperature of the cracking furnace is controlled to 450 ° C; The mixture is sent to the melting furnace to be melted for 3 hours, and the temperature of the melting furnace is controlled to 1250 °C; the waste gas generated by the cracking furnace is discharged into the melting furnace for further treatment to avoid the generation of toxic gases such as dioxins. Finally, the gas generated by the melting furnace is disposed of by the exhaust gas treatment system. . The molten slag liquid is discharged from the furnace bottom, and the glass body is obtained after natural cooling.

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Abstract

The invention relates to a vitrification method for industrial waste salt. The vitrification method comprises the following steps that S1, the industrial waste salt and coal gangue are mixed evenly toobtain a mixture; S3, the mixture is cracked; and S3, matter obtained after cracking is smelted, and glassy smelting slag is obtained. According to the method, treatment of wastes with processes of wastes against one another can be achieved, the industrial waste salt and the coal gangue are converted into stable vitreous bodies, the coal gangue includes a certain quantity of combustibles, the heating value ranges from 4.18 Mj / kg to 12.56 Mj / kg, the coal gangue can provide heat generated by spontaneous combustion in the smelting process of a smelting furnace, and therefore the supply needs forexternal heat energy are reduced; and potassium oxide, sodium oxide and calcium oxide are included in the coal gangue and all can achieve the functions of fluxing agents, and the actual temperature of the smelting furnace needed in the glass slagging process can be reduced.

Description

technical field [0001] The invention relates to the technical field of hazardous waste disposal, in particular to a vitrification method of industrial waste salt. Background technique [0002] Industrial waste salt mainly refers to the by-product crystalline salts produced in industrial production. The main components are solid hazardous wastes of one or more inorganic salts such as sodium chloride, sodium sulfate, sodium sulfide, calcium chloride, etc. A large amount of organic matter is entrained, making it have a strong pungent odor, and it may also entrain elements such as heavy metal ions and heteroatoms. It was included in the 2016 edition of the National Hazardous Waste List. [0003] At present, the most commonly used method for the disposal of industrial waste salt is landfill treatment. Existing waste salt and other soluble hazardous wastes are directly landfilled after curing and curing with cement. For flexible landfills, waste salt is highly soluble and has a h...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): B09B3/00B09B5/00
CPCB09B5/00B09B3/29
Inventor 陈福泰马建波刘兴甜刘海宁
Owner GO HIGHER ENVIRONMENT GRP CO LTD