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Polybutene resin composition for packaging film and preparation method thereof

A technology of polybutene resin and composition, applied in the field of polyolefin composition, can solve the problem of not finding patents related to polybutene film, etc.

Active Publication Date: 2022-03-01
PETROCHINA CO LTD
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] At present, no related patents have been found for polybutene film

Method used

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  • Polybutene resin composition for packaging film and preparation method thereof
  • Polybutene resin composition for packaging film and preparation method thereof

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0064] Polybutene (melt flow rate is 0.62 g / 10 min, density is 0.9105 g / cm 3 ) And antioxidants, processing stabilizers, nucleating agents and open agents, wherein the main antioxidant is four [β- (3,5-di-tert-butyl-4-hydroxyphenyl) propionic acid] pentaerythritol ester, The addition amount is 1600 ppm; the complementary oxygen is three (2,4-di-tert-butylphenyl) phosphite, the addition amount is 3200 ppm; the processing stabilizer is calcium stearate, the amount of 500 ppm is added; the nucleating agent is 3790, the amount of addition is 900 ppm; the opening agent is an oleic acid amide, the amount is 1000 ppm (the above is based on the polybutenylene per gram). The above composition was added to the kneading machine, the cylinder temperature was 190 ° C, the screw rotational speed 40R / min. After the mixer extruded granulation, it was produced into a film product, and the product performance was shown in Table 1.

Embodiment 2

[0066] Polybutene (melt flow rate is 0.62 g / 10 min, density is 0.9105 g / cm 3 ) And antioxidants, processing stabilizers, nucleating agents and open their auxiliaries, wherein the main antioxidant is β- (3,5 di-tert-butyl-4-hydroxybenzene) propionate octadol ester, add The amount is 2400 ppm; the complementary oxygen is three (2,4-di-tert-butylphenyl) phosphite, the amount of addition is 2400 ppm; the processing stabilizer is zinc stearate, the addition is 400 ppm; the nucleating agent is 20e The amount of addition is 800 ppm; the opening agent is a mustard amide, the amount is 500 ppm (the above is based on polybutene per gram). The above composition was added to the mixer, the cylinder temperature was 195 ° C, and the screw speed was 50 R / min. After the mixer extruded granulation, it was produced into a film product, and the product performance was shown in Table 1.

Embodiment 3

[0068] Polybutene (melt flow rate is 0.62 g / 10 min, density is 0.9105 g / cm 3 ) And antioxidants, processing stabilizers, nucleating agents, and an open agents, wherein the main antioxidant is 1,3,5-three (3,5-di-tert-butyl-4-hydroxybenzo) isocanuric acid. The amount of addition is 2000 ppm; the complementary oxygen is three (2,4-di-tert-butylphenyl) phosphite, the addition is 2000 ppm; the processing stabilizer is a talc powder, the addition is 600 ppm; nucleating agent is Na -45, the amount of added is 1000 ppm; the anodulation agent is an oleic acid amide, the amount is 500 ppm (the above is based on the polybutenethylene per gram). The above composition was added to the mixer, the cylinder temperature was 195 ° C, the screw rotational speed of 45 R / min. After the mixer extruded granulation, it was produced into a film product, and the product performance was shown in Table 1.

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Abstract

The invention relates to a polybutene resin composition for packaging film and a preparation method thereof, which is prepared by mixing polybutene (PB) and additives, the additives are antioxidant, processing stabilizer, nucleating agent and opening It is compounded with additives, and the addition amounts are (based on each gram of polybutene): 1000-5000ppm for antioxidant, 100-2000ppm for processing stabilizer, 100-2000ppm for nucleating agent, and 100-2000ppm for anti-blocking agent. 100-2000ppm. The packaging film prepared by adopting the composition can not only increase the tensile strength, impact performance and tear resistance performance of the film, but also increase the nucleation speed of the product and have excellent processing performance.

Description

Technical field [0001] The present invention relates to a polyolefin composition, specifically a polybutene resin composition and a preparation method for packaging film. Background technique [0002] Polybutene-1 (PB) resin has good temperature resistance, pressure resistance, creep resistance, durability, chemical stability, and plasticity, called "gold in plastic", is currently the world One of the most cutting chemical materials. The industrialization of polybutene-1 resin in my country is still in the early stages of development. China's petroleum butne-1 production capacity reached 850,000 tons / year or so, more than 75% as a fuel, the resources were wasted, how to increase the added value of butene-1 products was a big problem for China's oil to solve. Develop high value-added PB products, can reasonably use butene-1 resources, enrich China's petroleum high value-added polyolefin product varieties, bring huge economic benefits for Chinese oil [0003] At present, polybute...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08L23/20C08K13/02C08K5/134C08K5/526C08K5/09C08K5/20C08K5/3492C08K3/34C08K5/13
CPCC08K13/02C08K5/1345C08K5/526C08K5/09C08K5/20C08K5/34924C08K3/34C08K5/13C08L2203/16C08L23/20
Inventor 杨琦和树立张瑞高宇新宋磊任鹤孙彬彬王华杨国兴赵兴龙王立娟王文燕李冬霞郭峰姜进宪国海峰
Owner PETROCHINA CO LTD