Lithium-ion battery negative electrode material and preparation method thereof, negative electrode and lithium-ion battery
A lithium-ion battery and negative electrode material technology, applied in the field of applied chemistry, can solve the problems of low lithium-ion battery capacity, poor rate performance and cycle performance, and achieve high mechanical strength, improved cycle stability, and excellent electrochemical performance.
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[0045] The method for preparing the negative electrode of the lithium ion battery of the present disclosure may include the following steps: uniformly mixing the negative electrode material, the conductive agent and the first binder in the first solvent to obtain the negative electrode slurry; coating the negative electrode slurry on the negative electrode current collector Above, the lithium battery negative electrode A containing the negative electrode material of the present disclosure is obtained after drying at 50-150° C. and tableting treatment at 0.5-3 MPa.
[0046] A fifth aspect of the present disclosure provides a lithium ion battery including a positive electrode, a negative electrode and an electrolyte. The structure of the lithium battery is not particularly required, and may be one of an all-solid-state battery, a quasi-solid-state battery and a liquid lithium battery, preferably a liquid lithium battery, for example, may include a positive electrode, a negative e...
Embodiment 1
[0057] (1) Preparation of positive electrode C of lithium battery
[0058] 930g of LiCoO 2 Anode material (93%), 30g binder PVDF (3%), 20g acetylene black (2%), 20g conductive agent carbon fiber (2%) join in the 800g solvent NMP (nitrogen methyl pyrrolidone), and in vacuum mixer Stir in medium to form a stable and uniform positive electrode slurry. The positive electrode slurry is evenly and intermittently coated on both sides of aluminum foil (aluminum foil size: width 160mm, thickness 16μm), then dried at 393K, pressed by a roller press with a pressure of 1.5MPa, and cut into size It is a lithium battery positive electrode C of 480mm (length) × 45mm (width).
[0059] (2) Preparation of lithium battery negative electrode A
[0060] Production of negative electrode materials with core-shell structure: 1020g of TiO 2 , 11g of lithium ethoxide was added to 100mL of ethanol, stirring was started, and then the cloudy liquid was evaporated to dryness, wherein, TiO 2 The averag...
Embodiment 2
[0066] (1) Preparation of positive electrode C of lithium battery
[0067] 930g of LiCoO 2 Anode material (93%), 30g binder PVDF (3%), 20g acetylene black (2%), 20g conductive agent carbon fiber (2%) join in the 800g solvent NMP (nitrogen methyl pyrrolidone), and in vacuum mixer Stir in medium to form a stable and uniform positive electrode slurry. The positive electrode slurry is evenly and intermittently coated on both sides of aluminum foil (aluminum foil size: width 160mm, thickness 16μm), then dried at 393K, pressed by a roller press with a pressure of 1.5MPa, and cut into size It is a lithium battery positive electrode C of 480mm (length) × 45mm (width).
[0068] (2) Preparation of lithium battery negative electrode A
[0069] Production of negative electrode materials with core-shell structure: 1000g of TiO 2 , 5g Ti(BH 4 ) 2 , 3.1g of lithium ethoxide was added to 25mL of octadecene, stirring was started, and then the cloudy liquid was evaporated to dryness, wher...
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Abstract
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