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Lithium-ion battery negative electrode material and preparation method thereof, negative electrode and lithium-ion battery

A lithium-ion battery and negative electrode material technology, applied in the field of applied chemistry, can solve the problems of low lithium-ion battery capacity, poor rate performance and cycle performance, and achieve high mechanical strength, improved cycle stability, and excellent electrochemical performance.

Active Publication Date: 2021-06-18
SHENZHEN BYD LITHIUM BATTERY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0004] The purpose of the present disclosure is to solve the problems of low capacity, poor rate performance and cycle performance of existing lithium-ion batteries, provide a lithium-ion battery negative electrode material and its preparation method, lithium-ion battery negative electrode and lithium-ion battery

Method used

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  • Lithium-ion battery negative electrode material and preparation method thereof, negative electrode and lithium-ion battery

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preparation example Construction

[0045] The method for preparing the negative electrode of the lithium ion battery of the present disclosure may include the following steps: uniformly mixing the negative electrode material, the conductive agent and the first binder in the first solvent to obtain the negative electrode slurry; coating the negative electrode slurry on the negative electrode current collector Above, the lithium battery negative electrode A containing the negative electrode material of the present disclosure is obtained after drying at 50-150° C. and tableting treatment at 0.5-3 MPa.

[0046] A fifth aspect of the present disclosure provides a lithium ion battery including a positive electrode, a negative electrode and an electrolyte. The structure of the lithium battery is not particularly required, and may be one of an all-solid-state battery, a quasi-solid-state battery and a liquid lithium battery, preferably a liquid lithium battery, for example, may include a positive electrode, a negative e...

Embodiment 1

[0057] (1) Preparation of positive electrode C of lithium battery

[0058] 930g of LiCoO 2 Anode material (93%), 30g binder PVDF (3%), 20g acetylene black (2%), 20g conductive agent carbon fiber (2%) join in the 800g solvent NMP (nitrogen methyl pyrrolidone), and in vacuum mixer Stir in medium to form a stable and uniform positive electrode slurry. The positive electrode slurry is evenly and intermittently coated on both sides of aluminum foil (aluminum foil size: width 160mm, thickness 16μm), then dried at 393K, pressed by a roller press with a pressure of 1.5MPa, and cut into size It is a lithium battery positive electrode C of 480mm (length) × 45mm (width).

[0059] (2) Preparation of lithium battery negative electrode A

[0060] Production of negative electrode materials with core-shell structure: 1020g of TiO 2 , 11g of lithium ethoxide was added to 100mL of ethanol, stirring was started, and then the cloudy liquid was evaporated to dryness, wherein, TiO 2 The averag...

Embodiment 2

[0066] (1) Preparation of positive electrode C of lithium battery

[0067] 930g of LiCoO 2 Anode material (93%), 30g binder PVDF (3%), 20g acetylene black (2%), 20g conductive agent carbon fiber (2%) join in the 800g solvent NMP (nitrogen methyl pyrrolidone), and in vacuum mixer Stir in medium to form a stable and uniform positive electrode slurry. The positive electrode slurry is evenly and intermittently coated on both sides of aluminum foil (aluminum foil size: width 160mm, thickness 16μm), then dried at 393K, pressed by a roller press with a pressure of 1.5MPa, and cut into size It is a lithium battery positive electrode C of 480mm (length) × 45mm (width).

[0068] (2) Preparation of lithium battery negative electrode A

[0069] Production of negative electrode materials with core-shell structure: 1000g of TiO 2 , 5g Ti(BH 4 ) 2 , 3.1g of lithium ethoxide was added to 25mL of octadecene, stirring was started, and then the cloudy liquid was evaporated to dryness, wher...

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Abstract

The present disclosure relates to a lithium-ion battery negative electrode material. The particles of the negative electrode material have a core-shell structure. The particles of the negative electrode material have a core-shell structure. The core-shell structure includes an inner core, an intermediate shell layer and an outer shell layer. TiO 2 , the intermediate shell contains Li 4 Ti 5 o 12 , the outer shell layer contains TiOF 2 . Applying the lithium-ion battery anode material provided by the present disclosure to a lithium-ion battery can significantly improve the rate performance, cycle performance and battery capacity of the lithium-ion battery.

Description

technical field [0001] The disclosure relates to the field of applied chemistry, in particular, to a lithium-ion battery negative electrode material and a preparation method thereof, a lithium-ion battery negative electrode and a lithium-ion battery. Background technique [0002] Lithium-ion battery anode materials have an important impact on the performance of lithium-ion batteries, and coating and modifying lithium-ion battery anode materials is an effective means to improve their electrochemical performance. [0003] TiO2 is used in the patent application CN102208612A 2 Coated Li 4 Ti 5 o 12 Lithium battery anode composite materials were prepared by the method, although the rate performance and cycle stability of lithium batteries prepared by this method have been improved to a certain extent, but the lithium ion battery anode materials prepared by this method have limited improvement in the capacity of lithium ion batteries; patent Application CN104425808A discloses ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01M4/36H01M4/48H01M4/485H01M4/62H01M4/131H01M10/0525
CPCH01M4/131H01M4/366H01M4/48H01M4/485H01M4/624H01M10/0525Y02E60/10
Inventor 历彪郭姿珠易观贵
Owner SHENZHEN BYD LITHIUM BATTERY
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