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Wastewater degradation process based on photoelectric synergy

A technology for wastewater degradation and photoelectric degradation, which is applied in the fields of light water/sewage treatment, water pollutants, water/sewage treatment, etc. Transfer effect, improve photocatalytic performance, improve the effect of water treatment

Inactive Publication Date: 2020-06-26
边永根
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, from the perspective of photocatalytic technology, photogenerated electrons and holes are generated simultaneously during the catalytic process, and the two are easily recombined, which seriously affects the efficiency of photocatalytic degradation of organic matter, which also limits the in-depth application of photocatalytic technology in the field of environmental protection.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Add 5L of methylene blue solution with a concentration of 0.01mmol / L into the liquid storage tank, and process it according to the above method, wherein the flow rate is 100mL / min, and the photoelectric drop device adopts anode plate and cathode plate with a porous structure, and the porous structure The porosity is 100ppi, the surface of the cathode plate and the anode plate is provided with a photocatalytic film, and the anode plate and the cathode plate are made of the same material, and a stepped alternating voltage is provided between the anode plate and the cathode plate, so The spacing between the anode plate and the cathode plate is 40mm, and the surfaces of the anode plate and the cathode plate are all irradiated with ultraviolet lamps; the voltage of the gradient alternating voltage adopts 20V, and the frequency is 10Hz, and the intensity of ultraviolet rays on the surface of the titanium dioxide film is 3mW / cm 2 , the loading amount of titanium dioxide in the ...

Embodiment 2

[0033] Add 8L of ethyl acetate waste liquid with a COD of 108000mg / L into the liquid storage tank, and process it according to the above method, wherein the flow rate is 400mL / min. The photoelectric drop device adopts anode plate and cathode plate with porous structure, and the porous The porosity of the structure is 200ppi, the surface of the cathode plate and the anode plate are provided with a photocatalytic film, and the anode plate and the cathode plate are made of the same material, and a stepped alternating voltage is set between the anode plate and the cathode plate, The distance between the anode plate and the cathode plate is 50mm, the surfaces of the anode plate and the cathode plate are all irradiated with ultraviolet lamps, the voltage of the gradient alternating voltage is 30V, the frequency is 50Hz, and the intensity of ultraviolet on the surface of the titanium dioxide film is 5mW / cm 2 , the loading amount of titanium dioxide in the titanium dioxide film is 4g...

Embodiment 3

[0036] Add 10L of biological waste liquid with a COD of 87000mg / L into the liquid storage tank, and process it according to the above method, wherein the flow rate is 300mL / min. The photoelectric drop device adopts anode plate and cathode plate with porous structure, and the The porosity is 150ppi, the surface of the cathode plate and the anode plate are provided with a photocatalytic film, and the anode plate and the cathode plate are made of the same material, and a stepped alternating voltage is set between the anode plate and the cathode plate, the The distance between the anode plate and the cathode plate is 45mm, and the surfaces of the anode plate and the cathode plate are all irradiated with ultraviolet lamps, the voltage of the gradient alternating voltage is 25V, the frequency is 40Hz, and the intensity of ultraviolet rays on the surface of the titanium dioxide film is 4mW / cm 2 , the loading amount of titanium dioxide in the titanium dioxide film is 3g / cm 2 . After ...

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Abstract

The invention discloses a wastewater degradation process based on photoelectric synergy. The process comprises the following steps: 1, adding organic wastewater into a liquid storage tank, filtering,and removing particles in the organic wastewater by using a physical filtration mode; 2, introducing the filtered wastewater into a photoelectric degradation device through a circulating pump, and carrying out degradation treatment; 3, discharging the wastewater subjected to photoelectric degradation into a liquid storage tank, filtering, taking the flow as a cycle, re-discharging the wastewater finally discharged into the liquid storage tank into a photoelectric degradation device, and carrying out continuous circular treatment until COD and BOD reach the discharge standard; and 4, introducing the wastewater subjected to circular treatment into a membrane filtration assembly, and removing salt generated by degradation, so that the comprehensive water quality of the treated water finally reaches the sewage discharge standard. According to the invention, photocatalysis is used as a technical core, and the characteristics of a voltage and capacitance system are supplemented, so that rapid transfer of hole electrons is formed, the effect of rapid degradation is achieved, and the effect of water treatment is improved.

Description

technical field [0001] The invention belongs to the field of environmental protection and also belongs to the field of photocatalysis, and specifically relates to a wastewater degradation process based on photoelectric synergy. Background technique [0002] The continuous deepening of the industrialization process has caused a huge waste of resources and energy, water pollution, energy crisis and other issues have become prominent. The development of effective wastewater treatment processes has always been the focus of environmental protection. In terms of the composition of wastewater, wastewater can generally be divided into inorganic wastewater and organic wastewater. Inorganic wastewater mainly contains heavy metals, heavy metal complexes, acids and bases, cyanides, sulfides, halogen ions and other inorganic ions. Organic wastewater contains commonly used organic solvents, organic acids, ethers, polychlorinated biphenyls, organophosphorus compounds, petroleum, oils, phe...

Claims

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Application Information

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IPC IPC(8): C02F1/32C02F1/461C02F9/08C02F101/30C02F101/10C02F101/20
CPCC02F1/32C02F1/46104C02F1/46109C02F9/00C02F2001/46142C02F2101/10C02F2101/20C02F2101/30
Inventor 边永根
Owner 边永根